• Title/Summary/Keyword: Partial IR

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Metabolic comparison between standard medicinal parts and their adventitious roots of Cynanchum wilfordii (Maxim.) Hemsl. using FT-IR spectroscopy after IBA and elicitor treatment (IBA 및 elicitor 처리에 따른 백수오 기내 생산 부정근 및 표준품의 FT-IR 스펙트럼 기반 대사체 비교 분석)

  • Ahn, Myung Suk;So, Eun Jin;Jie, Eun Yee;Choi, So Yeon;Park, Sang Un;Moon, Byeong Cheol;Kang, Young Min;Min, Sung Ran;Kim, Suk Weon
    • Journal of Plant Biotechnology
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    • v.45 no.3
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    • pp.250-256
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    • 2018
  • To determine whether metabolite fingerprinting for whole cell extracts based on Fourier transform infrared spectroscopy (FT-IR) can be used to discriminate and compare metabolic equivalence, standard medicinal parts of Cynanchum wilfordii (Maxim.) Hemsl. and their adventitious roots were subjected to FT-IR. The principal component analysis (PCA) and partial least square discriminant analysis (PLS-DA) from FT-IR spectral data showed that whole metabolic pattern from the adventitious root of Cynanchum wilfordii was highly similar to its standard medicinal parts. These results clearly showed that mass proliferation of adventitious roots could be applied for the novel supply of standard medicinal parts of medicinal plants. Furthermore, FT-IR spectroscopy combined with multivariate analysis established in this study could be applied as an alternative tool for discriminating of whole metabolic equivalence from standard medicinal parts. Thus, it is proposed that these metabolic discrimination systems from the adventitious root of Cynanchum wilfordii could be applied for metabolic standardization of in vitro grown Cynanchum wilfordii.

Spectral Infrared Signature Analysis of the Aircraft Exhaust Plume (항공기 배기 플룸의 파장별 IR 신호 해석)

  • Gu, Bonchan;Baek, Seung Wook;Yi, Kyung Joo;Kim, Man Young;Kim, Won Cheol
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.42 no.8
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    • pp.640-647
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    • 2014
  • Infrared signature of aircraft exhaust plume is the critical factor for aircraft survivability. To improve the military aircraft survivability, the accurate prediction of infrared signature for the propulsion system is needed. The numerical analysis of thermal fluid field for nozzle inflow, free stream flow, and plume region is conducted by using the in-house code. Weighted Sum of Gray Gases Model based on Narrow Band with regrouping is adopted to calculate the spectral infrared signature emitted from aircraft exhaust plume. The accuracy and reliability of the developed code are validated in the one-dimensional band model. It is found that the infrared radiant intensity is relatively more strong in the plume through the analysis, the results show the different characteristic of the spectral infrared signature along the temperature, the partial pressure, and the species distribution. The continuous spectral radiant intensity is shown near the nozzle exit due to the emission from the nozzle wall.

Deterioration of Polyethylene Films Induced by Partial Discharge and Variations Observed in Mechanical Properties (Polyethylene film의 부분방전열화와 역학적 특성)

  • ;Shigeru Yamamot
    • Journal of the Korean Society of Safety
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    • v.4 no.1
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    • pp.5-14
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    • 1989
  • Deterioration induced by partial discharge was investigated for low-density polyethylene samples. Under an electrical field, a cold-drawn PE film was stretched perpendicularly to the direction of the original drawing. The starting voltage of the discharge shows a minimum at the draw ratio of 1.2 to 1.8. Around the same draw ratio, the elastic modulus and mechanical loss factor (tan S) of the sample exhibit a minimum and a maximum, respectively. According to the X-ray analysis, the size itf microcrystals decreases with increasing draw ratios. Reorientation of the ru01ecular chains was observed above a draw ratio of 1.5 by the IR method.

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Simultaneous estimation of fatty acids contents from soybean seeds using fourier transform infrared spectroscopy and gas chromatography by multivariate analysis (적외선 분광스펙트럼 및 기체크로마토그라피 분석 데이터의 다변량 통계분석을 이용한 대두 종자 지방산 함량예측)

  • Ahn, Myung Suk;Ji, Eun Yee;Song, Seung Yeob;Ahn, Joon Woo;Jeong, Won Joong;Min, Sung Ran;Kim, Suk Weon
    • Journal of Plant Biotechnology
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    • v.42 no.1
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    • pp.60-70
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    • 2015
  • The aim of this study was to investigate whether fourier transform infrared (FT-IR) spectroscopy can be applied to simultaneous determination of fatty acids contents in different soybean cultivars. Total 153 lines of soybean (Glycine max Merrill) were examined by FT-IR spectroscopy. Quantification of fatty acids from the soybean lines was confirmed by quantitative gas chromatography (GC) analysis. The quantitative spectral variation among different soybean lines was observed in the amide bond region ($1,700{\sim}1,500cm^{-1}$), phosphodiester groups ($1,500{\sim}1,300cm^{-1}$) and sugar region ($1,200{\sim}1,000cm^{-1}$) of FT-IR spectra. The quantitative prediction modeling of 5 individual fatty acids contents (palmitic acid, stearic acid, oleic acid, linoleic acid, linolenic acid) from soybean lines were established using partial least square regression algorithm from FT-IR spectra. In cross validation, there were high correlations ($R^2{\geq}0.97$) between predicted content of 5 individual fatty acids by PLS regression modeling from FT-IR spectra and measured content by GC. In external validation, palmitic acid ($R^2=0.8002$), oleic acid ($R^2=0.8909$) and linoleic acid ($R^2=0.815$) were predicted with good accuracy, while prediction for stearic acid ($R^2=0.4598$), linolenic acid ($R^2=0.6868$) had relatively lower accuracy. These results clearly show that FT-IR spectra combined with multivariate analysis can be used to accurately predict fatty acids contents in soybean lines. Therefore, we suggest that the PLS prediction system for fatty acid contents using FT-IR analysis could be applied as a rapid and high throughput screening tool for the breeding for modified Fatty acid composition in soybean and contribute to accelerating the conventional breeding.

Efficient Linear Path Query Processing using Information Retrieval Techniques for Large-Scale Heterogeneous XML Documents (정보 검색 기술을 이용한 대규모 이질적인 XML 문서에 대한 효율적인 선형 경로 질의 처리)

  • 박영호;한욱신;황규영
    • Journal of KIISE:Databases
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    • v.31 no.5
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    • pp.540-552
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    • 2004
  • We propose XIR-Linear, a novel method for processing partial match queries on large-scale heterogeneous XML documents using information retrieval (IR) techniques. XPath queries are written in path expressions on a tree structure representing an XML document. An XPath query in its major form is a partial match query. The objective of XIR-Linear is to efficiently support this type of queries for large-scale documents of heterogeneous schemas. XIR-Linear has its basis on the schema-level methods using relational tables and drastically improves their efficiency and scalability using an inverted index technique. The method indexes the labels in label paths as key words in texts, and allows for finding the label paths that match the queries far more efficiently than string match used in conventional methods. We demonstrate the efficiency and scalability of XIR-Linear by comparing it with XRel and XParent using XML documents crawled from the Internet. The results show that XIR-Linear is more efficient than both XRel and XParent by several orders of magnitude for linear path expressions as the number of XML documents increases.

Implementation of Agricultural Multi-UAV System with Distributed Swarm Control Algorithm into a Simulator (분산군집제어 알고리즘 기반 농업용 멀티 UAV 시스템의 시뮬레이터 구현)

  • Ju, Chanyoung;Park, Sungjun;Son, Hyoung Il
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2017.04a
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    • pp.37-38
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    • 2017
  • 최근 방제 및 예찰과 같은 농작업에 단일 UAV(Unmanned Aerial Vehicle)시스템이 적용되고 있지만, 가반하중과 체공시간 등 기존시스템의 문제가 점차 대두되면서 작업 시간을 보다 단축시키고 작업 효율을 극대화 할 수 있는 농업용 멀티 UAV시스템의 필요성이 증대되고 있다. 본 논문에서는 작업자가 다수의 농업용 UAV를 효과적으로 제어할 수 있는 분산군집제어 알고리즘을 제안하며 알고리즘 검증 및 평가를 위한 시뮬레이터를 소개한다. 분산군집제어는 UAV 제어 계층, VP(Virtual Point) 제어 계층, 원격제어 계층으로 이루어진 3계층 제어구조를 가진다. UAV 제어 계층에서 각 UAV는 point mass로 모델링 되는 VP의 이상적인 경로를 추종하도록 제어한다. VP 제어 계층에서 각 VP는 입력 $p_i(t)=u^c_i+u^o_i+u^{co}_i+u^h_i$-(1)을 받아 제어되는데 여기서, $u^c_i{\in}{\mathbb{R}}^3$는 VP 사이의 충돌방지제어, $u^o_i{\in}{\mathbb{R}}^3$는 장애물과의 충돌방지제어, $u^{co}_i{\in}{\mathbb{R}}^3$는 UAV 상호간의 협조제어, $u^h_i{\in}{\mathbb{R}}^3$는 작업자로부터의 원격제어명령이다. (1)의 제어입력에서 충돌방지제어는 각 $u^i_c:=-{\sum\limits_{j{\in}{\eta}_i}}{\frac {{\partial}{\phi}_{ij}^c({\parallel}p_i-p_j{\parallel})^T}{{\partial}p_i}}$-(2), $u^o_c:=-{\sum\limits_{r{\in}O_i}}{\frac {{\partial}{\phi}_{ir}^o({\parallel}p_i-p^o_r{\parallel})^T}{{\partial}p_i}}$-(3)로 정의되면 ${\phi}^c_{ij}$${\phi}^o_{ir}$는 포텐셜 함수를 나타낸다. 원격제어 계층에서 작업자는 햅틱 인터페이스를 통해 VP의 속도를 제어하게 된다. 이때 스케일변수 ${\lambda}$에 대하여 VP의 원격제어명령은 $u^t_i(t)={\lambda}q(t)$로 정의한다. UAV 시뮬레이터는 리눅스 환경에서 ROS(Robot Operating Systems)를 기반한 3차원 시뮬레이터인 Gazebo상에 구축하였으며, 마스터와 슬레이브 간의 제어 명령은 TCPROS를 통해 서로 주고받는다. UAV는 PX4 기반의 3DR Solo 모델을 사용하였으며 MAVROS를 통해 MAVLink 통신 프로토콜에 접속하여 UAV의 고도, 속도 및 가속도 등의 상태정보를 받을 수 있다. 현재 멀티 드론 시스템을 Gazebo 환경에 구축하였으며, 추후 시뮬레이터 상에 분산군집제어 알고리즘을 구현하여 검증 및 평가를 진행하고자 한다.

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BLYP and mPW1PW91 Calculated Structures and IR Spectra of the Stereoisomers of Tetra-O-methylsulfinylcalix[4]arene

  • Choe, Jong-In
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3247-3251
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    • 2010
  • Molecular structures of the various conformers for the four stereoisomers of tetra-t-butyl-tetra-O-methylsulfinylcalix[4]arene (1) were optimized using DFT BLYP and mPW1PW91/6-31G(d,p) (hybrid HF-DF) calculation methods. We have analyzed the total electronic and Gibbs free energies and normal vibrational frequencies of 16 different structures from four major conformations (cone (CONE), partial cone (PC), 1,2-alternate (1,2-A), 1,3-alternate (1,3-A)) of the four stereoisomers [1(rccc), 1(rcct), 1(rctt), 1(rtct)]. The mPW1PW91/6-31G(d,p) calculations suggested that the $1(rccc)_{CONE}$, $1(rcct)_{PC}$, $1(rctt)_{PC}$, and $1(rtct)_{1,3-A}$ were the most stable conformations of the respective stereoisomers. These outcomes are in accordance with the experimental structures obtained from X-ray crystallography. The electrostatic repulsion between the sulfinyl and methoxy groups is a primary factor for the relative stabilities of the four different conformations. The IR spectra of the most stable conformers [$1(rccc)_{CONE}$, $1(rcct)_{PC}$, $1(rctt)_{PC}$, $1(rtct)_{1,3-A}$] of each stereoisomer were compared to each other.

Kinetics and Mechanisms of the Oxidation of Carbon Monoxide on $Eu_{1-x}Sr_xCoO_{3-y}$ Perovskite Catalysts

  • Dong Hoon Lee;Joon Ho Jang;Hong Seok Kim;Yoo Young Kim;Jae Shi Choi;Keu Hong Kim
    • Bulletin of the Korean Chemical Society
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    • v.13 no.5
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    • pp.511-516
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    • 1992
  • The catalytic oxidation of CO on perovskite $Eu_{1-x}Sr_xCoO_{3-y}$, has been investigated at reaction temperatures from 100 to $250^{\circ}C$ under stoichiometric CO and $O_2$ partial pressures. The microstructure and Sr-substitution site of the catalyst were studied by means of infrared spectroscopy. The reaction rates were found to be correlated with 1.5-and 1.0-order kinetics with and without a $CO_2$ trap, respectively; first-and 0.5-order with respect to CO and 0.5-order to $O_2$ with the activation energy of 0.37 eV $mol^{-1}$. It was found from IR, ${\sigma}$ and kinetic data that $O_2$ adsorbs as an ionic species on the oxygen vacancies, while CO adsorbs on the lattice oxygens. The oxidation reaction mechanism is suggested from the agreement between IR, ${\sigma}$ and kinetic data.

Development of UV Corona Camera for the Detecting of Discharge on Power Facility using UV Transmittance Improvement Filter (UV 투과율 향상 필터 기술을 이용한 전력설비 방전 검출용 자외선 코로나 카메라 개발)

  • Kim, Young-Seok;Choi, Myeong-Il;Kim, Chong-Min;Bang, Sun-Bae;Shong, Kil-Mok
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.11
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    • pp.1656-1661
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    • 2012
  • UV inspection technology is being used for predictive maintenance of power facility together with IR-thermography and ultrasonic devices. In this paper, the UV corona camera design, fabrication, and perform a simple test to be take advantage of the diagnostic equipment. The UV corona camera developed a $6.4^{\circ}{\times}4.8^{\circ}$ of the field of view as a conventional camera to diagnose a wide range of slightly enlarged, and power equipment to measure the distance between the camera and the distance meter has been attached. The transmission between 250 to 280nm was 11% ($12.5%{\times}88%{\times}98%$) by combing the transmission on absorption film, window and other filter(UG 5, nickel sulphate and so on). In a distance of 5m with the UV corona camera it is possible to detect partial discharge with a PD level of 2.5pC and a RIV level of $3.6dB{\mu}V$.

Kinetics and Oxygen Vacancy Mechanism of the Oxidation of Carbon Monoxide on Perovskite$Nd_{1-x}Sr_xCoO_{3-y}$ Solutions as a Catalyst

  • Dong Hoon Lee;Keu Hong Kim
    • Bulletin of the Korean Chemical Society
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    • v.15 no.8
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    • pp.616-622
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    • 1994
  • The oxidation of carbon monoxide by gaseous oxygen in the presence of a powdered $Nd_{1-x}Sr_xCoO_{3-y}$ solid solution as a catalyst has been investigated in the temperature range from 150$^{\circ}$C to 300$^{\circ}$C under various CO and $O_2$ partial pressures. The site of Sr substitution, nonstoichiometry, structure, and microstructure were studied by means of powder X-ray diffraction and infrared spectroscopy. The electrical conductivity of the solid solution has been measured at 300$^{\circ}$C under various CO and $O_2$ partial pressures. The oxidation rates have been correlated with 1.5-and 1.2-order kinetics with and without a $CO_2$ trap, respectively; first-and 0.7 order with respect to CO and 0.5-order to $O_2$. For the above reaction temperature range, the activation energy is in the range from 0.25 to 0.35 eV/mol. From the infrared spectroscopic, conductivity and kinetic data, CO appears essentially to be adsorbed on the lattice oxygens of the catalyst, while $O_2$ adsorbs as ions on the oxygen vacancies formed by Sr substitution. The oxygen vacancy mechanism of the CO oxidation and the main defect of $Nd_{1-x}Sr_xCoO_{3-y}$ solid solution are supported and suggested from the agreement between IR data, conductivities, and kinetic data.