• 제목/요약/키워드: Paramagnetic

검색결과 360건 처리시간 0.026초

Optical Properties of Two Different Metallic NaxCoO2:x=0.35 and 0.75

  • Hwang, J.;Yang, J.;Timusk T.;Chou, F.C
    • Journal of Magnetics
    • /
    • 제10권3호
    • /
    • pp.128-132
    • /
    • 2005
  • We report optical ab-plane properties of the layered sodium cobaltate, $Na_xCoO_2$ for x = 0.35 and 0.75. Two samples show metallic behaviors according to dc resistivity transport. Overall temperature dependent optical conductivities of both samples are very similar to those of the high temperature superconducting underdoped cuprates. We found that the optical scattering rate of x = 0.75 sample, which is in a Curie-Weiss metallic phase, varies linearly (non-Fermi liquid) with frequency and temperature while that of x = 0.35 sample, which is in a paramagnetic metallic phase, varies quadratically (Fermi liquid) with frequency and temperature. Both x = 0.35 and 0.75 samples have an onset of scattering around $600\;cm^{-1}$ which can be attributed to the interaction of charge carriers with a bosonic collective mode in a system.

Field-Induced Translation of Single Ferromagnetic and Ferrimagnetic Grain as Observed in the Chamber-type μG System

  • Kuwada, Kento;Uyeda, Chiaki;Hisayoshi, Keiji;Nagai, Hideaki;Mamiya, Mikito
    • Journal of Magnetics
    • /
    • 제18권3호
    • /
    • pp.308-310
    • /
    • 2013
  • Translation induced by the field-gradient force is being observed for a single ferromagnetic iron grain and a ferrimagnetic grain of a ferrite sample ($CuFe_2O_4$). From measurements on the translation, precise saturated magnetization of $M_S$ is possible for a single grain. The method is based on the energy conservation rule assumed for the grain during its translation and the grain is translated through a diffuse area under microgravity conditions. The results of the two materials indicate that a field-induced translation of grain bearing spontaneous moment is generally determined by a field-induced potential $-mM_SH(x)$ where m denotes the mass of sample. According to the above translations, the detection of $M_S$ is not interfered by any signals from the sample holder. The $M_S$ measurement does not require m value. By observing translations resulting from fieldinduced volume forces, the magnetization of a single grain is measurable irrespective of its size; the principle is also applicable to measuring susceptibility of diamagnetic and paramagnetic materials.

B20 결정구조와 MnGe와 MnSi의 전자구조 및 자기적 특성 (B20 Crystal Structure and Electromagnetic Property of MnGe and MnSi)

  • 정태성
    • 한국재료학회지
    • /
    • 제29권8호
    • /
    • pp.477-482
    • /
    • 2019
  • The magnetic properties and electronic structures of the B20 crystal structure MnGe and MnSi were investigated using the density functional theory with local density approximation. The low symmetry of the B20 crystal structure plays a very important role to make electromagnetic characteristics of these materials. The important result of the calculations is that it can be observed the appearance of a pair of gaps in the density of states near the Fermi level in both compounds. These features are results from d-band splitting by the low symmetry of the crystal field from B20 crystal structure. It can be seen that there is half-metallic characteristics from the density of states in both compounds. The calculation shows that the value of magnetic moment of MnGe is 5 times bigger than that of MnSi even though they have same crystal structure. The electronic structures of paramagnetic case have a very narrow indirect gap just above the Fermi level in both compounds. These gaps acquire some significance in establishing the stability of the ferromagnetic states within the local density approximation. Calculation shows that the Mn 3d character dominates the density of states near the Fermi level in both materials.

Feasible waste liquid treatment from electroless nickel-plating by intense magnetic field of HTS bulk magnets

  • Oka, T.;Furusawa, M.;Sudo, K.;Dadiel, L.;Sakai, N.;Seki, H.;Miryala, M.;Murakami, M.;Nakano, T.;Ooizumi, M.;Yokoyama, K.;Tsujimura, M.
    • 한국초전도ㆍ저온공학회논문지
    • /
    • 제23권3호
    • /
    • pp.37-40
    • /
    • 2021
  • Nickel (Ni) is a kind of the rare earth resources. Since Ni-containing waste is drained after several plating operations in the factories, the effective recycling technique has been expected to be introduced. An actual magnetic separation technique using HTS bulk magnet generating the strong magnetic field has succeeded in collecting the paramagnetic slurry containing Ni-sulphate coarse crystals which were fabricated from the Ni-plating waste. The Ni compound in the collected slurry was identified as NiSO4/6H2O, showing slight differences in the particle size and magnetic susceptibility between the samples attracted and not-attract to the magnetic pole. This preferential extraction suggests us a novel recycling method of Ni resource because the compound is capable of recycling back to the plating processes as a raw material.

Influence of crystallization treatment on structure, magnetic properties and magnetocaloric effect of Gd71Ni29 melt-spun ribbons

  • Zhong, X.C.;Yu, H.Y.;Liu, Z.W.;Ramanujan, R.V.
    • Current Applied Physics
    • /
    • 제18권11호
    • /
    • pp.1289-1293
    • /
    • 2018
  • The influence of crystallization treatment on the structure, magnetic properties and magnetocaloric effect of $Gd_{71}Ni_{29}$ melt-spun ribbons has been investigated in detail. Annealing of the melt-spun samples at 610 K for 30 min, a majority phase with a $Fe_3C$-type orthorhombic structure (space group, Pnma) and a minority phase with a CrB-type orthorhombic structure (space group, Cmcm) were obtained in the amorphous matrix. The amorphous melt-spun ribbons undergo a second-order ferromagnetic to paramagnetic phase transition at 122 K. For the annealed samples, two magnetic phase transitions caused by amorphous matrix and $Gd_3Ni$ phases occur at 82 and 100 K, respectively. The maximum magnetic entropy change $(-{\Delta}S_M)^{max}$ is $9.0J/(kg{\cdot}K)$ (5T) at 122 K for the melt-spun ribbons. The values of $(-{\Delta}S_M)^{max}$ in annealed ribbons are 1.0 and $5.7J/(kg{\cdot}K)$, corresponding to the two adjacent magnetic transitions.

The treatment of coolant wastewater of rolling plate process by High Gradient Magnetic Separation

  • Kim, Tae-Hyung;Ha, Dong-Woo;Kwon, Jun-Mo;Sohn, Myung-Hwan;Baik, Seung-Kyu;Oh, Sang-Soo;Ko, Rock-Kil;Kim, Ho-Sup;Kim, Young-Hun;Park, Seong-Kuk
    • 한국초전도ㆍ저온공학회논문지
    • /
    • 제11권4호
    • /
    • pp.8-11
    • /
    • 2009
  • This study introduced wastewater treatment method by High Gradient Magnetic Separation (HGMS). HGMS treatment was high efficient method for various industrial wastewaters. The system is currently research state, but we have surveyed commercialize the technology for industry. In rolling plate process, coolant wastewater was recycled by sedimentation and sand filter system. It needs several large reservoirs and long time to remove suspended solid (SS) like metal fines and iron oxide in hot rolling plate making process. If removing rate of suspended solid in rolling coolant wastewater is improved by using HGMS system, the productivity of working process can be increased and the area of reservoir can be reduced. We manufactured high temperature superconducting HGMS system that had a purpose to treatment of coolant wastewater in rolling plate process. We fabricated the prototypes of magnetic matrix filter consisting of stainless steel 430 mesh, which is a core component in the magnetic separation system, In our basic preliminary experiment using HGMS system, it has been clear that the fine paramagnetic particles in the coolant wastewater obtained from rolling plate process of POSCO can be separated with high efficiency.

SPIN POLARIZED PHOTOEMISSION AND MAGNETIC CIRCULAY DICHROISM STUDY OF FeAl THIN FILMS

  • Kim, K.W.;Kudryavtsev, Y.V.;Chang, G.S.;Whang, C.N.;Lee, Y.P.
    • 한국진공학회지
    • /
    • 제6권S1호
    • /
    • pp.53-58
    • /
    • 1997
  • It is well known that the equiatomic FeAl alloy crystallizes in a paramagnetic CsCl structure and is very stable in a wide temperature range owing to a significant charge transfer from Al to Fe. A presence of structural defects normally enhances the magnetic and magneto-optical properties of this alloy. In this study spin-resolved photoemission and magnetic circular dichroism (MCD) were carried out on both ordered and disordered $Fe_{0.52}Al_{0.48}$ alloy films. The disordered state in the alloy films was obtained by a vapor quenching deposition on cooled substrates. It is shown that the order-disorder transition in the Fe0.52Al0.48 alloy films leads to a significant change in the spin polarization. Form the MCD results the orbital and spin magnetic moments of the constituent atoms are obtained. According to the sum rule the spin and orbital magnetic moments of Fe in the disordered FeAl film are $\mu\frac{SR}{spin}=0.8\mu_B$ and $\mu\frac{SR}{orb}=0.14\mu_B$ respectively. The spin magnetic moment is also evaluated to be $\mu\frac{BR}{spin}=0.77\mu_B$ by the branching ration method employing a photon polarization of 90%.

  • PDF

Effect of Al on Structural and Magnetic Characteristics of CoCrFeNiMnAlx High Entropy Alloys

  • Majid Tavoosi;Ali Ghasemi;Gholam Reza Gordani;Mohammad Reza Loghman Estarki
    • 한국재료학회지
    • /
    • 제33권3호
    • /
    • pp.95-100
    • /
    • 2023
  • This research examines the effect of adding aluminum on the structural, phasic, and magnetic properties of CoCrFe NiMnAlx high-entropy alloys. To this aim, the arc-melt process was used under an argon atmosphere for preparing cast samples. The phasic, structural, and magnetic properties of the samples were characterized by x-ray diffraction (XRD), scanning electron microscopy (SEM), and vibrational magnetometry (VSM) analyses. Based on the results, the addition of aluminum to the compound caused changes in the crystalline structure, from FCC solid solution in the CoCrFeNiMn sample to CoCrFeNiMnAl BBC solid solution. It was associated with changes in the magnetic property of CoCrFeNiMnAlx high-entropy alloys, from paramagnetic to ferromagnetic. The maximum saturation magnetization for the CoCrFeNiMnAl casting sample was estimated to be around 79 emu/g. Despite the phase stability of the FCC solid solution with temperature, the solid solution phase formed in the CrCrFeNiMnAl high-entropy compound was not stable, and changed into FCC solid solution with temperature elevation, causing a reduction in saturation magnetization to about 7 emu/g.

Computed Tomographic and Magnetic Resonance Imaging Features of Oral Melanoma in a Dog

  • Arim Lee;Seokmin Lee;Hojung Choi;Youngwon Lee
    • 한국임상수의학회지
    • /
    • 제40권5호
    • /
    • pp.370-374
    • /
    • 2023
  • Oral melanoma is the most common type of oral tumor in dogs. In this report, computed tomography (CT) and magnetic resonance imaging (MRI) were performed to diagnose a right oral pigmented mass in an 8-year-old dog. The oral mass appeared as a homogeneous soft tissue density parenchyma on pre-contrast CT images, and with heterogeneous enhancement on post-contrast images. Bone destruction of the right mandibular body around the mass and mild enlargement of the right mandibular lymph node were also found. On MRI, the bulky oral mass showed mixed hyperintensity and isointensity compared to the adjacent muscle, where irregular hyperintensity on T1-weighted images corresponded to hypointensity on the T2-weighted images. Based on the physical examinations and imaging results, melanoma was suspected and confirmed via fine-needle aspiration. These unique MRI signals were due to the high paramagnetic melanin content in the tumor, therefore MRI examination could be useful for diagnosis of melanoma.

Radiologic-Pathologic Correlation of Unusual Lingual Masses: Part II: Benign and Malignant Tumors

  • Se Hyung Kim;Moon Hee Han;Sun Won Park;Kee-Hyun Chang
    • Korean Journal of Radiology
    • /
    • 제2권1호
    • /
    • pp.42-51
    • /
    • 2001
  • Because the tongue is superficially located and the initial manifestation of most diseases occurring there is mucosal change, lingual lesionscan be easily accessed and diagnosed without imaging analysis. Some lingual neoplasms, however, may manifest as a submucosal bulge and be located in a deep portion of the tongue, such as its base; their true characteristics and extent may be recognized only on cross-sectional images such as those obtained by CT or MRI. Some uncommon tongue neoplasms may have characteristic radiologic features, thus permitting quite specific radiologic diagnosis. Lipomas typically manifest at both CT and MR imaging as homogeneous nonenhancing lesions. Relative to subcutaneous fat they are isoattenuating on CT images, and all MR sequences show them as isointense. Due to the paramagnetic properties of melanin, metastases from melanotic melanoma usually demonstrate high signal intensity on T1-weighted MR images and low signal intensity on T2-weighted images. Although the radiologic findings for other submucosal neoplasms are nonspecific, CT and MR imaging can play an important role in the diagnostic work-up of these unusual tumors. Delineation of the extent of the tumor, and recognition and understanding of the spectrum of imaging and the pathologic features of these lesions, often help narrow the differential diagnosis.

  • PDF