• 제목/요약/키워드: Paramagnetic

검색결과 360건 처리시간 0.022초

Nano-sized Effect on the Magnetic Properties of Ag Clusters

  • Jo, Y.;Jung, M.H.;Kyum, M.C.;Park, K.H.;Kim, Y.N.
    • Journal of Magnetics
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    • 제11권4호
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    • pp.160-163
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    • 2006
  • We have prepared crystalline Ag nanoparticles with an average size of 4 nm in diameter by using an inductively coupled plasma reactor equipped with the liquid nitrogen cooling system. Our magnetic data show that the nano-sized effect of Ag nanoparticles on the magnetic properties is ferromagnetic, instead of a diamagnetic component of the Ag bulk and a superparamagnetic component of magnetic nanoparticles. We have also studied the magnetic properties of Ag-Cu nanocomposites with an opposite concentration profile between surface and core. These comparisons indicate that the ferromagnetic component strongly depends on the surface of Ag nanoparticles, while the paramagnetic component is strongly affected by the outer oxide layer, with the background of a diamagnetic component from the core of Ag.

Investigation of a New Red-Emitting, Eu3+-Activated MgAl2O4 Phosphor

  • Singh, Vijay;Haque, Masuqul;Kim, Dong-Kuk
    • Bulletin of the Korean Chemical Society
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    • 제28권12호
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    • pp.2477-2480
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    • 2007
  • MgAl2O4:Eu3+ red-light emitting powder phosphor was prepared at temperature as low as 500 oC within a few minutes by using the combustion route. The prepared powder was characterized by X-ray diffraction, scanning electron microscopy and Fourier-transform infrared spectrometry. The luminescence of Eu3+-activated MgAl2O4 shows a strong red emission dominant peak around 611 nm, which can be attributed to the 5D0-7F2 transition of Eu3+ ions from the synthesized phosphor particles under excitation (394 nm). Electron paramagnetic resonance (EPR) measurements at the X-band showed that no signal could be attributed to Eu2+ ions in MgAl2O4.

요업콘덴사 제조에 있어서의 과전체와 전기물질간의 반응검사 (Study of the Reaction between the Dielectric and the Electrode during the Manufacturing of the Ceramic Capaciitor)

  • 김기호
    • 한국세라믹학회지
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    • 제21권1호
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    • pp.60-66
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    • 1984
  • During the metallization in the manufacturing of the ceramic capacitor at the boundary layer between Pd or Pt electrode and $BaTiO_3$-dielectric reactions were analysed. For the study of the reaction Electron Spin Resonance (ESR) Method was used. With the aid of ESR an increased of the concentration of the paramagnetic $Ti^{3+}$-Centers on the metallizing process could be seen. It meaned a reduction effect although the metallization was accomplished under oxidation atmosphere. Therefore it could be regarded as a reaction at the boundary layer. In order to investigate the reaction ad double octahedral model was compared and the increase of the $Ti^{3+}$-concentration was studied.

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화재에서의 열발생율 측정 (Measurement of Heat Release Rate in Fires)

  • 한용식;김명배;최준석
    • 연구논문집
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    • 통권29호
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    • pp.49-55
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    • 1999
  • Heat release rate used to characterize the fire is an important factor for determining the fire size, the fire growth and the time for suppression and evacuation. The purpose of present work is to review theoretical backgrounds and to introduce equations for estimation of heat release rate with oxygen consumption method in fires. Our work also shows the experimental results of applications for liquid fuels. The oxygen concentration is measured by the analyzer of paramagnetic type. The analyzers of Infra-Red type are used to measure the concentrations of $CO_2$ and CO gas. Time delays of analyzers are ignored.

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Polarized Infrared Emission from Polycyclic Aromatic Hydrocarbons and Implications

  • Hoang, Thiem
    • 천문학회보
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    • 제42권2호
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    • pp.81.2-81.2
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    • 2017
  • Polarized mid-infrared emission from polycyclic aromatic hydrocarbons (PAHs) can provide a crucial test of basic physics of alignment of nanoparticles and opens a potential new window into studying magnetic fields. In this talk, I will present a new model of polarized PAH emission that takes into account the effect of PAH alignment with the magnetic field due to resonance paramagnetic relaxation. I will then present our predictions for the polarization level of the strong PAH emission features from the interstellar medium. I will present the first detection of polarization of PAH emission at 11.3micron which is consistent with our theoretical prediction. Finally, I will discuss important implications of this work for tracing magnetic fields via mid-IR PAH features and for constraining the polarization of anomalous microwave emission that is useful for the quest of CMB B-modes.

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혈액 세포의 고유자성을 이용한 마이크로 자기영동 세포분리기 (Magnetophoretic Microseparators for Separating Blood Cells Based on Their Native Magnetic Properties)

  • 정진희;한기호
    • 대한기계학회논문집B
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    • 제32권11호
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    • pp.856-862
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    • 2008
  • This paper presents the characterization of a continuous magnetophoretic microseparator for separating white and red blood cells from peripheral whole blood cells based on their native magnetic properties. The magnetophoretic microseparator separated the blood cells using a high gradient magnetic separation (HGMS) method without the use of additives such as magnetic beads or probing materials. Experimental results show that the paramagnetic capture mode microseparator can continuously separate out 93.5% of red blood cells and 97.4% of white blood cells from diluted whole blood, and the diamagnetic capture mode microseparator can continuously separate out 89.7% of red blood cells and 72.7 % of white blood cells by using applying an external magnetic flux of 0.2 T using a permanent magnet.

Electron Spin Transition Line-width of Mn-doped Wurtzite GaN Film for the Quantum Limit

  • Park, Jung-Il;Lee, Hyeong-Rag;Lee, Su-Ho;Hyun, Dong-Geul
    • Journal of Magnetics
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    • 제17권1호
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    • pp.13-18
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    • 2012
  • Starting with Kubo's formula and using the projection operator technique introduced by Kawabata, EPR lineprofile function for a $Mn^{2+}$-doped wurtzite structure GaN semiconductor was derived as a function of temperature at a frequency of 9.49 GHz (X-band) in the presence of external electromagnetic field. The line-width is barely affected in the low-temperature region because there is no correlation between the resonance fields and the distribution function. At higher temperature the line-width increases with increasing temperature due to the interaction of electrons with acoustic phonons. Thus, the present technique is considered to be more convenient to explain the resonant system as in the case of other optical transition systems.

Spectroscopy of Intracellularly Located $%{133}Cs$ Has Been Used to Monitor the Uptake of the Isolated Rat Liver

  • Park Byung-Rae
    • 대한의생명과학회지
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    • 제11권3호
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    • pp.301-305
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    • 2005
  • MR spectroscopy of intracellularly located $^{133}Cs$ has been used to monitor the uptake of Gd-EOB-DTPA by the isolated rat liver. As shown by ${31}P$ spectroscopy, accumulation of $^{133}Cs$ ions in hepatocytes does not produce detectable effects on the metabolism. The hepatic internalization of Gd-EOB-DTPA was followed by the paramagnetic relaxation enhancement of the intracellular $^{133}Cs$ ions, and confirmed by parallel quantitations of Gd and Cs run by inductively coupled plasma analysis of liver samples and aliquots of perfusate. Two peaks are observed at -22.0 and -23.5 ppm, with respect to the line of the external reference arbitarily set to 0 ppm. Upon rinsing of the extracellular compartment with regular K-H free of CsCl, the high-field resonance disappears within 20min. The intracellular concentration was confirmed by ICP, which gives a $Cs^+$ content of $22.0\pm3.5mM$. The relaxation data significantly underestimate the Gd content, suggesting a potential compartmentation of $Cs^+$ and the contrast agent.

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$La_{0.7}Sr_{0.3}FeO_{3}$ 세라믹스의 전기전도 특성 (Electrical Transport Properties of $La_{0.7}Sr_{0.3}FeO_{3}$)

  • 정우환
    • 한국전기전자재료학회논문지
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    • 제14권5호
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    • pp.376-382
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    • 2001
  • Magnetic and transport properties in the ceramic specimen of L $a_{0.7}$S $r_{0.3}$Fe $O_3$ with orthohombic structure has been investigated. Weak ferromagnetism has been observed in a ceramic sample of L $a_{0.7}$S $r_{0.3}$Fe $O_3$. Large dielectric relaxation of Debye type is observed in paramagnetic states within the temperature range of 130K~200K. From the temperature dependence of the characteristic frequency, we concluded that the elementary process of the dispersion is related to holes hopping between F $e^{3+}$ and F $e^{4+}$ ions. The temperature dependencies of thermoelectric power and Dc conductivity suggest that the charge carrier responsible for the conduction are strongly localized. These experimental results have been interpreted in terms of a hopping process involving small polaron.n.laron.n.

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PZT 박막의 나노 마멸특성에 관한 연구

  • 이용하;정구현;김대은;유진규;홍승범
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2004년도 춘계학술대회 논문요약집
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    • pp.135-135
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    • 2004
  • 21세기 정보화시대에 미디어의 발전은 고저장밀도를 요구하는 정보저장 장치의 개발을 필요로 하게 되었고, 현재 정보저장 장치의 주류를 이루는 magnetic recording 방식에 의한 HDD는 향후 5년 이내에 초자성한계 (super paramagnetic limit)라는 물리적 현상에 직면하여 더 이상 발전이 어려울 깃이다 따라서 이러한 한계를 극복하기 위한 여러 기술 증 Scanning Probe Microscope (SPM)을 이용한 차세대 탐침형 정보저장 기술은 미세한 끝단 반경을 가지는 탐침과 표면의 상호작용을 이용하여 정보를 기록/재생하는 기술로써 수십 nm 크기의 bit를 형성하여 Tbit/in$^2$ 이상의 높은 저장밀도를 가질 수 있으므로 현재 가장 상용화될 가능성이 높다.(중략)

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