• Title/Summary/Keyword: Paints

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Development of Durable Reliability Assessment Methods for Heavy Duty Coatings

  • Kim, Seung-Jin;Jung, Ho;Yang, In-Mo;Tanaka, Takeyuki
    • Corrosion Science and Technology
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    • v.4 no.4
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    • pp.155-163
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    • 2005
  • Heavy duty coating are required to have minimum durable period of 15 years under average usage environment because these paints are coated with purpose of anti-corrosion, antifouling, plastering etc. Onto steel structures constructed upon land and sea and other ferrous structures of electric power generation plants, electricity transmission towers, large structures of various plants, etc. Therefore we tried to estimate heavy duty coating longevity through reliability evaluation method and used combined cyclic anti-conrrosion test method composed of drying, moisturizing and salt spray as for accelerated life test to estimate longevity. Accelerated life test hours to heavy duty coating of first grade (with longevity not less than 15 years) specification may be obtained from troubleless test hours $t_n=\frac{B_p}{n^{1/\beta}}\left[\frac{1n(1-CL)}{1n(1-p)} \right]^{1/\beta}=19.671$ (yr) where shape parameter $\beta=1.1$, confidence level CL=80 %, warranty life $B_{10}=15$ yr and sampling size n=10 (2 sets). Because acceleration factor {AF} found by accelerated test is 41.7, accelerated life test hours required may be represented about 4,132 hr so that if this amount of hours is converted to number of cycles(6 hr/cycle) of complex cycle corrosion resistance test then the amount is tantamount about 690 cycles. That means if there does not occur trouble failure (with defect factor sum not more than 20) during when there is performed 690 cycles of combined cyclic anti-corrosion test to heavy duty coating specimen then it signifies that there can be warranted longevity $B_{10}$ of 15 yr under condition of confidence level CL=80 %.

A Study of Costume on Gustav Klimt's Paintings (구스타프 클림트 회화에 표현된 의상에 관한 연구)

  • Jang, Sung-Eun
    • Journal of the Korean Society of Clothing and Textiles
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    • v.31 no.2 s.161
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    • pp.280-291
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    • 2007
  • The purpose of this study is to research characteristics of costume which is expressed in Gustav Klimt's Paintings. In the end of 19th century and the beginning of 20century Vienna, considered to be the fashion Mecca after Paris, the creativity of such artists allowed the 'Anti-Fashion Movement' to set itself up against the frippery of the costume of the time. The Secession Movement received the effect of Art Nouveau and Symbolism and Klimt led of this movement as a forerunner in Vienna. Many women appealed in Klimt's Painting with unique costume which contrast to traditional fashion that period time. The characteristics of costume in his paintings are as follows. Firstly, Klimt drew in the women's costume which made by designers of Vienna Workshops, at one of motive of his work of art. Costume got a opportunity became a new art field, because there was no conceptual thinking of a fashion designer at that time. Secondly, the costume of Klimt' paintings had both anti-fashion design and elements of fashion, so he gained considerable support from leaders of high fashion who was the upper classes. Thirdly, both anti-fashion and fashion appeared in his painting at first period. Costume which made at the Vienne Workshop appealed portraits of Klimt paints at the second period. Klimt interested in Naturalism, Japonism, Orientalism and Greece style and expressed his characteristic techniques at the last period. Lastly, Klimt liberated the woman from a physical and spirit restriction through his various artistic presentations.

Pervaporation of Fluoroethanol/Water Mixtures through Commercial Poly(vinyl alcohol) Membranes (상용화된 폴리비닐알콜막을 이용한 불화에탄올/물의 투과증발 특성연구)

  • Lee Soo-Bok;Ahn Sang-Man;Choi Seung-Hak;Kim Jeong-Hoon;Lee Yong-Taek
    • Membrane Journal
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    • v.14 no.3
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    • pp.258-262
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    • 2004
  • Trifluoroethyl methacrylate (TFEMA) is used in the preparation of water-repellant paints and optical fiber clading materials, and is manufactured by esterification reaction of trifluoroethanol (TFEA) and methacrylic acid (MA). To estimate the applicability of a pervaporation membrane for the esterification TFEMA esterification, the basic pervaporation properties for TFEA/water mixture were determined using a commercial poly(vinyl alcohol) membrane (GFT Membrane $Pervap^{\circledR}1005$). The effect of TFEA concentration in feed solution and operating temperature on the pervaporation properties was determined. The total permeation flux decreased with increasing TFEA concentration from 90 to 99 wt%, but the separation factor of TFEA/water showed maximum values at 95 wt% TFEA concentration. With increasing feed temperatures from 50 to 8$0^{\circ}C$, the permeation flux and separation factor increased. Higher separation factors and permeation fluxes were observed at 8$0^{\circ}C$ of feed temperature. This pervaporation performance confirmed that the commercial pervaporation membrane could be successfully applied to esterification of TFEMA.

Safty of Alternatives for Endocirne Disrupting Substances (내분비계장애물질 대체소재의 안전성)

  • Park, Chan Jin;Kim, Woong;Gye, Myung Chan
    • Korean Journal of Environmental Biology
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    • v.33 no.4
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    • pp.361-374
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    • 2015
  • Endocirne disruptors (EDs) can cause fertility decrease, developmental disorder, and even cancer in animals. Until 90's, EDs were used in various synthetic products including paints, coatings, detergents, plastics, and plasticizers. Currently, in several countries, the production, trade and use of EDs or EDs-suspected chemicals have been regulated while activity to screen the alternatives for EDs including bisphenol-A, phthalate and nonylphenol is active. Although various toxicity test method was developed and applied for screening of alternatives, however, the safety of alternatives has been not fully demonstrated. Some alternatives have high structural similarity with existing EDs, raising the possible risk of endocrine disruption by alternatives. In an effort to develop the safe alternatives, we reviewed the effects of EDs such as bisphenol-A, phthalates, nonylphenol and their substituents. In addition, in-silico analysis for endocrine disrupting activities of some alternatives was presented.

Tubular Jacquard Knit Wear Design through the Application of Keith Haring's Works (키스 해링[Keith Haring]의 작품을 응용한 니트웨어 디자인 - 튜블러 자카드 조직을 활용하여 -)

  • Lee, Ha-Jung;Lee, Youn-Hee
    • Journal of the Korean Society of Costume
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    • v.61 no.1
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    • pp.69-83
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    • 2011
  • This study applied cartoon-like simple and implicit symbol of Keith Haring works to tubular jacquard knit, designed woman casual knit wear with fun, explicit and activities using fluorescent yarns with explicit features. This study aimed to propose the directions for new market pioneering that meets the emotional requirements of modern people by raising the level of utilization and expression area of knit fashion, and to present the constructive directions for high value-added knit wear by designing highly effective knit wear. Methods of this study examined the lifetime and artistic background of Keith Haring and collected his works through searching of internet, scholastic publications or thesis. Formative types and colors of works collected were analyzed and classified according to characteristic standards of Haring and characteristic formativeness and color of works were extracted. The result of this study is as shown below: First, the feature of his works can be summarized into motif that has symbolic and implicit cartoon-like lines including narratives as well as enormous number of works. Such feature is very suitable for variation and recombination in realization of design and has unlimited potentials for development. Second, image colors can be extracted such as black and white, original color and fluorescent paints, which reflects the intention of artist who put focus on communication with the public. Such color feature is very suitable for design motif that has explicitness of reflecting the intention of artist through use of special fluorescent yarn. Third, I made it as reversible wear that has effects of increasing or decreasing the explicitness according to color area ratio using the feature of textures allowing use of both sides as well as form stability of tubular jacquard. Fourth, by adjusting the thickness of fabric with controlling of ply in fabric using poly yarn and wool union yarn, I could obtain good results of study in terms of technique that can express various materials with embossed dynamic effects of unevenness on flat surface.

Operation Characteristics of the HVAC System Installed in Ancient Tomb (고분내부에 설치된 공조시스템의 운전특성)

  • Jun, Yong-Du;Lee, Kum-Bae;Jun, Hee-Ho;Ko, Seok-Bo;Park, Jin-Yang;Youn, Young-Muk
    • Journal of Energy Engineering
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    • v.15 no.3 s.47
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    • pp.202-208
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    • 2006
  • Although the importance of good conservation of historic sites including ancient royal tombs is well aware, still not much attention has been paid for the facilities and systems to preserve those historic sites, which includes precious artifacts as wall paints and carved works, etc. Even the general understanding about the environment of the underground space or tombs is not satisfactory. In the present study, vibration levels due to the operation of an HVAC system to maintain the desired indoor temperature and humidity are investigated experimentally. According to the measured data, the level of vibration inside the present model tomb with the indoor unit inside, showed order of magnitude less values than the Swiss Standards, but still higher than the value suggested by German standards, which is, zero. Further study will be pursued for cases including different ways of installation, because the vibration level depends not only on the system design, but also on the installation methods.

Surface Modification of Flake-Shaped Inorganic Mica and Their Cool Paint Performances (판상형 무기소재인 Mica의 표면개질 및 차열페인트의 특성 평가)

  • Park, Jeong Min;Kim, Hee Jung;Yoo, Jung Whan
    • Applied Chemistry for Engineering
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    • v.27 no.1
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    • pp.35-38
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    • 2016
  • In this study, the mica used as a thermal-insulation material was modified with a silane coupling agent, octyltriethoxysilane (OTES), to improve its hydrophobicity. The modified mica was characterized using FT-IR spectrometer, water wettability test, and water contact angle measurement. The analysis exhibits that OTES for the modified mica sample was well bonded chemically and drastically enhanced the hydrophobicity. The reflectance observed as 73.9% (mica) and 86.4% (OTES/mica), respectively, for OTES/mica was improved about 12.5% before any modifications. Also the modified mica sample showed $7.2^{\circ}C$ decrease in the thermal-insulation performance of cool paints compared to that of using unmodified mica, indicating that the modification of mica with silane coupling agents could be effective in enhancing the thermal-insulation performance of the cool paint.

A Study on the Synthesis of Acrylic Phenol Resins and Their Properties as a Paint (아크릴계 페놀수지 합성과 이를 이용한 도료의 물성연구)

  • Hwang, Sue In;Kim, Young Jin;Kim, Dong Kwon
    • Applied Chemistry for Engineering
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    • v.24 no.2
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    • pp.171-176
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    • 2013
  • The need of volatile organic compound (VOC) free coating material has been increased to solve environmental problems such as the global warming. Nowadays, about 70~80% of coating materials used in the worldwide are a liquid type. Therefore, the development of non-solvent coating material that can minimize VOCs emissions is necessary to solve the global warming problem. In this study, acrylic monomers were added to develop non-solvent paints in order to improve disadvantages of the poor adhesion of a conventional phenolic resin caused by acidification. As a result, the blend resins of 2.818 Mpa phenol- formaldehyde resin/poly methyl methacrylate (PE/PMMA) has the best properties and performances for the adhesives.

Subacute Inhalation Toxicity of Cyclohexanone in B6C3F1 Mice

  • Lee, Yong-Hoon;Chung, Yong Hyun;Kim, Hyeon-Yeong;Shin, Seo Ho;Lee, Sang Bae
    • Toxicological Research
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    • v.34 no.1
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    • pp.49-53
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    • 2018
  • Cyclohexanone ($C_6H_{10}O$, CAS No. 108-94-1) is a colorless oily liquid obtained through the oxidation of cyclohexane or dehydrogenation of phenol. It is used in the manufacture of adhesives, sealant chemicals, agricultural chemicals, paint and coating additives, solvent, electrical and electronic products, paints and coatings, photographic supplies, film, photochemicals, and as an intermediate in nylon production. Owing to the lack of information on repeated inhalation toxicity of cyclohexaone, in this study, we aimed to characterize the subacute inhalation toxicity. B6C3F1 mice were exposed to 0, 50, 150, and 250 ppm of cyclohexanone for 6 hr/day, 5 days/week for 4 weeks via whole-body inhalation in accordance with the OECD Test Guideline 412 (subacute inhalation toxicity: 28-day study). Mortality, clinical signs, body weights, food consumption, hematology, serum biochemistry, organ weights, as well as gross and histopathological findings were evaluated between the control and exposure groups. No mortality or remarkable clinical signs were observed during the study. No adverse effects on body weight, food consumption, hematology, serum biochemistry, and organ weights, gross or histopathological lesions were observed in any male or female mice in any of the exposure groups, although some statistically significant changes were observed in organ weights. We concluded that no observable adverse effect level (NOAEL) is above 250 ppm in mice exposed to cyclohexanone for 6 hr/day for 5 days/week.

Functional Gene Analysis to Identify Potential Markers Induced by Benzene in Two Different Cell Lines, HepG2 and HL-60

  • Kim, Youn-Jung;Song, Mi-Kyung;Sarma, Sailendra Nath;Choi, Han-Saem;Ryu, Jae-Chun
    • Molecular & Cellular Toxicology
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    • v.4 no.3
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    • pp.183-191
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    • 2008
  • Volatile organic compounds (VOCs) are common constituents of cleaning and degreasing agents, paints, pesticides, personal care products, gasoline and solvents. And VOCs are evaporated at room temperature and most of them exhibit acute and chronic toxicity to human. Benzene is the most widely used prototypical VOC and the toxic mechanisms of them are still unclear. The multi-step process of toxic mechanism can be more fully understood by characterizing gene expression changes induced in cells by toxicants. In this study, DNA microarray was used to monitor the expression levels of genes in HepG2 cells and HL-60 cells exposed to the benzene on IC20 and IC50 dose respectively. In the clustering analysis of gene expression profiles, although clusters of HepG2 and HL-60 cells by benzene were divided differently, expression pattern of many genes observed similarly. We identified 916 up-regulated genes and 1,144 down-regulated genes in HepG2 cells and also 1,002 up-regulated genes and 919 down-regulated genes in HL-60 cells. The gene ontology analysis on genes expressed by benzene in HepG2 and HL-60 cells, respectively, was performed. Thus, we found some principal pathways, such as, focal adhesion, gap junction and signaling pathway in HepG2 cells and toll-like receptor signaling pathway, MAPK signaling pathway, p53 signaling pathway and neuroactive ligand-receptor interaction in HL-60 cells. And we also found 16 up-regulated and 14 down-regulated commonly expressed total 30 genes that belong in the same biological process like inflammatory response, cell cycle arrest, cell migration, transmission of nerve impulse and cell motility in two cell lines. In conclusion, we suggest that this study is meaningful because these genes regarded as strong potential biomarkers of benzene independent of cell type.