• 제목/요약/키워드: Packing Group

검색결과 138건 처리시간 0.03초

BENTAZONE, $C_{10}H_{12}N_2O_3S$의 결정 및 분자구조 (The Crystal and Molecular Structure of BENTAZONE, $C_{10}H_{12}N_2O_3S$)

  • 박권일;조성일
    • 한국결정학회지
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    • 제8권2호
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    • pp.144-148
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    • 1997
  • 단결정 X-ray 회절법을 이용하여 Bentazone, C10H12N2O3S의 결정 및 부자구조를 규명하였다. 공간군은 P21/c이며 a=9.7818(9)Å, b=9.6095(9)Å, c=13.5737(9)Å, β=97.269(1)', Z=4, V=1136.1(6) Å. 직접법으로 개략적인 분자모델을 설정하고, 1396(Fo2>4σFo2)개의 독립 회절반점에 완전행력 최소자승법으로 정밀화하여 최종신뢰도값, R=0.045인 최종적인 분자모형을 구하였다. 분자내의 Thiocarbazin ring과 Isopropyl작용기는 staggered conformation을 이루고 있으며, 수소결합에 의하여 결합된 분자들은 c-축 방향으로 교차 하면서 packing 되어 있다.

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당의 종류 및 첨가량을 달리한 깨다식의 품질특성 (Quality Characteristics of Sesame Dasiks According to amount and the kind of Sweetener)

  • 김진숙;한영실;유선미;김행란;전혜경
    • 한국식품조리과학회지
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    • 제19권3호
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    • pp.280-285
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    • 2003
  • 깨다식의 감미 및 물성 등의 개선을 위해 꿀보다 높은 점도와 hardness를 가지는 쌀엿과 조청 등을 첨가 혼합하여 품질을 조사한 결과를 요약하면 다음과 같다. 깨다식의 적정 재료 배합비는 깨가루 100 기준시, 꿀과 쌀엿의 동량 혼합액 50%(w/w)였으며, 이를 기준으로 제조한 깨다식의 이화학적 특성은 당도 17.44 brix$^{\circ}$, 수분 12.16, 환원당 15.44, 단백질 12.88, 지방 32.02, 조회분 2.82 %이었고, 기계적 특성 중 TPA의 chewiness는 0.28~0.30, hardness는 27.22~27.44 g/$\textrm{cm}^2$이고, 색도의 L값은 41.67, a값 4.58, 그리고 b값은 16.99였다.

후면전극형 실리콘 태양전지 제조기술 개발 (Development of Manufacturing Processes of Crystalline Silicon Back Contact Solar Cells)

  • 김대원;이건영;조은철;박상욱;문인식;이규열;유재희
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2005년도 춘계학술대회
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    • pp.89-93
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    • 2005
  • A rear contact solar cell has a potential merit of efficiency improvement by a low shading loss in front surface. a simplified module assembly. and a higher packing density. Among the rear contact solar cells. MWT. metallizationl wrap through MWT solar cells that have the bus bars on the back side and the front side metallization is connected to the back through metal filled laser fired holes in the silicon wafer. This approach has the advantages of a much more uniform appearance. The first fabrication of MWT using a multicrystalline silicon modules in our group showed $12.28\%$ on $125mm{\times}125mm$ active area.

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항공운송용 위험물과 화물실 등급에 대한 연구 (The Study on the CAO Dangerous Goods and the Cargo Compartment Classification)

  • 신대원;구성관;김웅이
    • 한국항공운항학회지
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    • 제23권2호
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    • pp.84-88
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    • 2015
  • In this study, we surveyed the CAO Dangerous Goods, the Cargo Compartment Classification, IATA DGR(Dangerous Goods Regulations), ICAO Doc. 9284 and the regulation for the Air Transport of Dangerous Goods by Ministry of land Infrastructure and Transport of Korea. We found that the differences between these regulations. Applied according to the type of dangerous goods cargo compartment Class is determined. These regulations have caused confusion was due to the difference, because of the need for revision and amendment regulations were analyzed.

Crystal Structure Analysis of 3-(4-ethylphenyl)-3H-chromeno[4,3-c]isoxazole-3a(4H)-carbonitrile

  • Malathy, P.;Ganapathy, Jagadeesan;Srinivasan, J.;Manickam, Bakthadoss
    • 통합자연과학논문집
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    • 제8권4호
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    • pp.250-257
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    • 2015
  • The crystal structure of the potential active 3-(4-ethylphenyl)-3H-chromeno[4,3-c]isoxazole-3a(4H)-carbonitrile ($C_{19}H_{16}N_2O_2$) has been determined from single crystal X-ray diffraction data. In the title compound crystallizes in the monoclinic space group $P2_1/c$ with unit cell dimension a=6.6869 (8) ${\AA}$, b=15.8326 (19) ${\AA}$ and c= 15.237 (2) ${\AA}$ [${\alpha}=90^{\circ}$, ${\beta}=100.663^{\circ}$ and ${\gamma}=90^{\circ}$]. In the structure chromene, isoxazole and carboxylate are almost coplanar each other. All geometrical parameters revelled that chromene ring of pyran ring adopt sofa conformation. The crystal packing is stabilized by intermolecular C-H...N and C-H...O hydrogen bond interaction.

Crystal Structure Analysis of Methyl-3-phenyl-3H-chromeno[4,3-c]isoxazole-3a(4H)-carboxylate

  • Ganapathy, Jagadeesan;Srinivasan, J.;Manickam, Bakthadoss
    • 통합자연과학논문집
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    • 제8권3호
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    • pp.184-191
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    • 2015
  • The crystal structure of the potential active methyl-3-phenyl-3H-chromeno[4,3-c]isoxazole-3a(4H)-carboxylate ($C_{18}H_{15}NO_4$) has been determined from single crystal X-ray diffraction data. In the title compound crystallizes in the orthorombic space group $P2_12_12_1$ with unit cell dimension $a=9.8320(17){\AA}$, $b=9.9890(18){\AA}$ and $c=15.588(3){\AA}$ [${\alpha}=90^{\circ}$, ${\beta}=90^{\circ}$ and ${\gamma}=90^{\circ}$]. In the structure chromene, isoxazole and carboxylate are almost coplanar each other. All geometrical parameters revelled that chromene ring of pyran ring adopt sofa conformation. The crystal packing is stabilized by intermolecular C-H...O and C-H...N hydrogen bond interaction.

RSA vs DEM in view of particle packing-related properties of cementitious materials

  • Li, Kai;Stroeven, Piet
    • Computers and Concrete
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    • 제22권1호
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    • pp.83-91
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    • 2018
  • Various systems for simulating particulate matter are developed and used in concrete technology for producing virtual cementitious materials on the different levels of the microstructure. Basically, the systems can be classified as two distinct families, namely random sequential addition systems (RSAs) and discrete element methods (DEMs). The first type is hardly being used for this purpose outside concrete technology, but became popular among concrete technologists. Hence, it is of utmost relevance to compare the two families in their capabilities, so that the reliability of produced data can be estimated. This paper pursues to do this on the basis of earlier published material of work performed by a succession of PhD students in the group of the second author. Limited references will be given to external sources.

Crystal Structure Analysis of N,N'-bis(3-chloro-2-methylsalicylidene)-1,4-butanediamine

  • Sharmila, P.;Rajesh, R.;Venkatesan, R.;Ganapathy, Jagadeesan;Aravindhan, S.
    • 통합자연과학논문집
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    • 제9권4호
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    • pp.255-260
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    • 2016
  • The crystal structure of the saliciline derivatives N,N'-bis(3-chloro-2-methylsalicylidene)-1,4-butanediamine ($C_{20}H_{22}Cl_2N_2O_2$) has been determined from single crystal X-ray diffraction data. In the title compound crystallizes in the triclinic space group $P{\bar{i}}$ with unit cell dimension $a=4.6085(3){\AA}$, $b=5.9747(3){\AA}$ and $c=5.9747(3){\AA}$ [${\alpha}=83.889(4)^{\circ}$, ${\beta}=86.744(5)^{\circ}$ and ${\gamma}=82.085(5)^{\circ}$]. The title compound is essentially planar conformation. The compound lies across a crystallographic inversion centre and adopts E configurations with respect to the C-N bonds. The crystal packing of the molecules of compound is stabilized through weak O-H...N intra molecular interactions

Crystal Structure Analysis of 4-Chloro-2{[(2-hydroxy-5-methylphenyl)amino]methyl}5-methylphenol

  • Sharmila, P.;Rajesh, R.;Venkatesan, R.;Ganapathy, Jagadeesan;Aravindhan, S.
    • 통합자연과학논문집
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    • 제9권4호
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    • pp.261-267
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    • 2016
  • The crystal structure of the saliciline derivatives 4-chloro-2{[(2-hydroxy-5-methylphenyl)amino]methyl}5-methylphenol ($C_{15}H_{15}ClNO_2$) has been determined from single crystal X-ray diffraction data. In the title compound crystallizes in the monoclinic space group P21/c with unit cell dimension $a=11.5241(2){\AA}$, $b=8.733(2){\AA}$ and $c=13.649(2){\AA}$ [${\alpha}=90^{\circ}$, ${\beta}=130.876(2)^{\circ}$ and ${\gamma}=90^{\circ}$]. the title compound are essentially planar conformation. The compound lies across a crystallographic inversion centre and adopts E configurations with respect to the C-N bonds. The crystal packing of the molecules of compound is stabilized through weak O-H...O inter molecular interactions.

Synthesis of Liquid Crystalline Copolyurethanes Containing Imide Unit

  • Lee, Dong-Jin;Lee, Tae-Jung;Kim, Han-Do
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 1998년도 가을 학술발표회논문집
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    • pp.94-97
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    • 1998
  • We have been studying :he synthesis of thermotropic polyurethanes, based on structural modifications by means of (i) the introduction of bulky substituent group in the aromatic ring to decrease the degree of lateral packing, (ii) the copolymerization of two kinds of monomers having different alkylene lengths to lower the regularity of the polymer structure, and (iii) the use of nonlinear monomers to lower the persistence length of the polymer chain in the liquid crystalline phase and to decrease the lateral interactions in the solid state. (omitted)

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