• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1997년도 춘계학술대회 논문집
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• pp.297-300
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• 1997

In this study, The PVDF thin film was fabricated on the one method of dry-process the physical vapor deposition method, applied electric field, and evaporation control in $\beta$-PVDF thin film preparation. A study on the electric-field-phase change of PVDF thin film in physical vapor deposition using the polymer deposition apparatus which are manufactured for oneself. In the analysis of Fourier-Transform Infrared spectra, according to increasing of electric field intensity, the 510$cm^{-1}$ / peak and 1273$cm^{-1}$ / peak which are showed in $\beta$-PVDF increase, on the contrary the 530$cm^{-1}$ / peak and 977$cm^{-1}$ / peak which are showed in $\alpha$-PVDF decrease.

• 한국안전학회지
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• 제26권6호
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• pp.64-70
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• 2011

In this study, the applicability of PVDF films for measurements of dynamic strain in a structure was investigated. A relationship between the strain and the voltage response of a PVDF film was analytically derived. Free vibration test on a steel cantilever beam was performed and vibration response of the beam was measured both by a convential foil strain gauge and a PVDF film. Strain-voltage relationship obtained from the experiment was compared with the analytic relationship. Good agreement between the analytic and experimental relationships was observed. It was found that a tailored PVDF film can measure the dynamic strain of a structure as accurate as a conventional foil strain gauge.

• 한국진공학회:학술대회논문집
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• 한국진공학회 1999년도 제17회 학술발표회 논문개요집
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• pp.110-110
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• 1999

Polyvinylidenefluoride (PVDF) is most used in piezoelectric polymer industry. Electrode effect on the electrical properties of PVDF has been investigated. al has been used due to fair adhesion for PVDF. Work function of metal plays an important role on the electrical properties of ferroelectrics for top and /or bottom electrode. However, Al has much lower work function than Pt or Au and so leakage current of Al/PVDF/Al may be large. Pt or Au has not been used for electrode of PVDF system due to poor adhesion. PVDF irradiated by Ar+ ion beam with O2 environment takes good adhesion to inert metal. Contact angle of PVDF to triple distilled water was reduced from 75$^{\circ}$ to 31$^{\circ}$ at 1$\times$1015 Ar+/cm2. Working pressure was 2.3$\times$10-4 Torr and base pressure was 5$\times$10-6 Torr. Pt was deposited by ion beam sputtering and thickness of pt film was about 1000$\AA$. in previous study, enhancing adhesion of Pt on PVDF was shown. in this study, effect of electrode on PVDF will be represented.

• 한국전기전자재료학회논문지
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• 제11권11호
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• pp.1007-1013
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• 1998

In this paper, the dielectric properties of fabricated Polyvinylidene fluoride(PVDF, $PVF_2$) thin film with substrate temperature from 30 to at vapor deposition. The dielectric properties of PVDF thin film had been studied in the frequency range from 10Hz to 4MHz at measuring temperature between 20 and $100^{/circ}C$. The anomalous increasing in dielectric constant and dielectric loss at low frequencies and high temperature was described for PVDF thin film containing ion impurities. In particularly, ion mobility of fabricated PVDF thin film at substrate temperature at $30^{/circ}C$ decrease from $2\times10^{-5}\;to\;3.07$\times10^{-7}cm^2/V.s$ On the other hand, ion density increase abruptly from 1.49\times$$10^{13}$ to $1.5\times$10^{16}$cm^{-3}$ In spite of decreasing of ion mobility, dielectric constants and dielectric loss for PVDF thin film increase rapidly with decreasing frequency and high temperature. It was concluded that the dielectric constants and dielectric loss was related to ion density than to ion mobility at low frequency and high temperatures.

• 한국전기전자재료학회논문지
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• 제27권11호
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• pp.736-739
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• 2014

In this paper, we propose a enhanced anti-corrosion property of the ground system by coating the CNT/PVDF composite film on it. Polymer material used for preventing the corrosion of ground system is polyvinylidene fluoride (PVDF), and conducting filler for obtaining conductivity of the composite film is multi-walled carbon nanotubes (MWCNTs). The MWCNTs were dispersed in the organic solvent of methyl ethyl ketone 2-butanone (MEK) with different concentration ratios, and the PVDF was solved in the MEK solvent with constant concentration ratio of 1 wt%. The CNT/PVDF composite solution was perpared by mixing and re-dispersing the CNT solution and the PVDF solution. Finally, the CNT/PVDF composite films were fabricated by the spray coating method using the above composite solution. Electrical conductivity, surface states, and anti-corrosion property of the CNT/PVDF composite films coated on the Cu substrate were evaluated. We found that the CNT/PVDF composite film showed relatively low resistance, hydrophobic surface state, and chemical stability. Consequently, we could improve the anti-corrosion property and maintain the electrical conductivity of the ground system by coating the CNT/PVDF composite film on it.

• 한국산학기술학회논문지
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• 제16권1호
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• pp.822-826
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• 2015

이 연구에서는 터널 시공 시 터널 배수관으로 유입되는 미세입자의 흐름과 이에 의한 물리/화학적 폐색현상에 따른 터널배수재의 성능저하를 PVDF film의 진동을 이용하여 성능을 향상시키는 방법의 적용 가능성에 대해 실내실험을 통하여 고찰하였다. 연구에서 터널로 유입되는 미세입자 슬러리 유입의 터널 환경을 모사하여 진행하였고 PVDF film을 이용한 기초 실험과 배수재를 모사한 모형실험으로 나누어 수행하였다. 기초 실험에서는 PVDF film에 50% 함수비(민물과 바닷물)의 점토를 흘려 주파수별 점토 슬러리의 흐름특성에 대한 효율성을 고찰하였으며 배수재 모사 실험에서는 배수관에 부직포를 부착시켜 슬러리의 흐름과 막힘 현상 해소에 대한 진동 효과를 고찰하였다. 실험결과는 진동에 의한 배수재의 배수성능, 즉 슬러리의 흐름과 막힘 해소현상이 아주 높게 나타났다. 이상의 실험결과를 종합하여 배수관을 기존 배수재와 융합, 응용, 활용할 수 있는 하이브리드 배수시스템을 개발할 수 있는 기초 자료를 확립하였다.

• 대한전자공학회논문지SD
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• 제40권8호
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• pp.565-571
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• 2003

본 연구에서는 전압을 인가하는 진공 증착법으로 PVDF 박막을 제작하였으며, PVDF 박막들의 적외선 흡수 분포 결정화 특성을 분석한 결과, 조건에 따른 표면 형상 등의 분석을 기초로 하여 β 상을 가지는 PVDF 박막의 증착을 위한 조건을 구하였다. 적외선 흡수 분포를 통하여 제작된 PVDF 박막의 상을 조사하였으며, 기판 온도와 인가 전압이 각각 30℃ 에서 90℃ 로, 0kV 에서 9kV 로 증가하면서 64% 이상의 β 결정화 특성을 나타내었는데 이는 기판온도와 인가 전압의 증가에 따라 P 상으로의 상변이가 더 용이하게 이루어질 수 있음을 의미하는 것이다. 한편, 기판 온도가 증가함에 따라서 제작된 PVDF 박막의 표면 거칠기는 65.1nm 에서 36.6nm 로 감소하는 특성을 나타내었다. 이러한 결과들을 기초로 β형 PVDF 박막을 위한 최적 증착조건을 구하였으며, 이 최적 증착조건을 이용하여 PVDF 박막을 제작하여 유전특성을 측정한 결과, 비유전률과 유전손실은 주파수가 증가함에 따라 각각 2.34 에서 0.44 로, 0.27 에서 0.04 로 감소하였다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 추계학술대회 논문집
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• pp.339-342
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• 1999

The equation of output voltage from the PVDF was derived. When impact force applied to the PVDF films of cantilever beam and one-end fixed, other-end supported beam structure, output voltage equation induced. Experimental output voltages by falling ball agreed quite well with induced theoretical data. This PVDF film showers to be in high possibility in a warning system of abnormal pulse rate and breathing, and in detecting impact force and/or mechanical energy.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 1998년도 춘계학술대회논문집; 용평리조트 타워콘도, 21-22 May 1998
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• pp.444-449
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• 1998

A modal transducer in two-dimensional structure can be implemented by varying the distributed transducer's gain spatially. In this paper, a method based on finite element method is developed for optimizing spatial gain distribution of PVDF transducer to create the modal transducer for specific modes. Using this concept, one can design the modal transducer in two-dimensional structure having arbitrary geometry and boundary conditions. As a practical means for implementing this continuous gain distribution without repoling die PVDF film, the gain distribution is approximated by optimizing gain-weights of interface circuit. The whole spatial area of the PVDF film is divided into several electrode segments and the signals from each segment are properly weighted and summed by interface circuit. This corresponds to the approximation of a continuous function using discrete values. The electrode partition is optimized using the genetic algorithm. Gain-weights are optimized using the simplex search method. A modal sensor for first to fourth modes of aluminum plate is designed using PVDF film with gain-weighted interface circuit. Various lamination angles of PVDF film are taken into consideration to utilize the anisotropy of the PVDF film. Performance of the optimized' PVDF sensor is demonstrated by numerical simulations..

• 한국구조물진단유지관리공학회 논문집
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• 제4권4호
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• pp.109-119
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• 2000

PVDF film sensor was applied to measure the stress concentration for monitoring the structural integrity. The strain calibration of this film sensor was performed by the bending test of aluminum beam. The PVDF sensor and the electrical strain gage were bonded on the beam. When the beam was loaded, the output of electrical strain gage was compared with the output of the PVDF sensor. The waveform of PVDF sensor output was shown as the same form of the output of electrical strain gage. The gain was determined as 1.7 by comparing these two signals to determine the exact value of the strain. In order to experiment the stress concentration, the stress field was analyzed by finite element analysis. The tensile test of notched steel specimens was conducted to develop the measurement technique of stress concentration. The output voltage ratio between the PVDF sensor near the notch and the PVDF sensor far from the notch could give the information about the load bearing capacity of steel specimen.