• Title/Summary/Keyword: PVDF필름

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The Effect of Crystal Structure on the Piezoelectric Properties of PVDF Film (PVDF의 결정구조가 압전특성에 미치는 영향)

  • 이덕출;박강식
    • Electrical & Electronic Materials
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    • v.2 no.2
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    • pp.127-136
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    • 1989
  • PVDF 필름의 압전성과 결정구조와의 관계를 조사하기 위하여 X선 회절과 압전계수를 측정하였다. 코로나 분극처리된 PVDF의 압전계수는 분극전압에 비례하여 증가하고 결정구조도 .alpha.형, 극성.alpha.형, .betha.형의 순으로 변화하였다. 이와같은 결과로부터 PVDF의 압전특성은 결정영역내의 쌍극자 배향에 의한 결정구조변화에 기인됨을 알 수 있었다.

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Reconstruction of Damage-Induced Impact Force of Gr/Ep Composite Laminates Using Piezoelectric Thin Film Sensor Signals (고분자 압전센서 신호를 이용한 Gr/Ep 복합재 적층판의 손상유발 충격하중의 복원)

  • 박찬익;김인걸;이영신
    • Composites Research
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    • v.15 no.5
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    • pp.7-13
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    • 2002
  • The piezoelectric thin film sensor has good characteristics to observe the impact responses of composite structures. The capabilities for monitoring impact behavior of Gr/Ep laminates subjected to damage-induced impact using the PVDF(polyvinylidene fluoride) film sensor were examined. For a series of low-velocity impact tests from low energy to damage-induced energy, simulated sensor signals were compared with measured signals and the PVDF film sensor. Local impact damages(matrix cracking and delamination) were found at three impact tests, but the measured signals agreed well with the simulated sensor signals based on the linear relationship between the impact forces and the PVDF film sensor signals. And the inverse technique was applied to reconstruct the impact forces using the PVDF film sensor signals. Most of reconstructed impact forces had good agreement with the measured forces. The comparison results showed that the local damage due. to low-velocity impact didn't disturb the global impact responses of composite laminates and the reconstruction of impact forces from PVDF sensor signals wasn't affected by the local damage.

Preparation and Characterization of Polyvinylidene Fluoride by Irradiating Electron Beam (전자빔 조사를 이용한 Polyvinylidene Fluoride의 제조 및 특성)

  • Choi, Yong-Jin;Kim, Min
    • Applied Chemistry for Engineering
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    • v.22 no.4
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    • pp.353-357
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    • 2011
  • For the purpose of introducing hydrophilic function to pristine PVDF, pristine PVDF was modified under atmosphere and aqueous vapor by irradiating electron beam (EB). EB dose was varied from 0 to 125 K Gray, respectively. Their changes of chemical composition /structure were observed and evaluated by FT-IR, EDS and DSC. Also, their surface behaviors were evaluated by contact angle. In FT-IR study, it was confirmed that hydroxyl functions were introduced to pristine PVDF. In EDS analysis, mole ratio of F (fluoride) was almost constant (about 33%) in spite of increasing EB dose, meaning that hydroxyl function was introduced via dehydrozenation, not via deflurodination. In DSC study, $T_g$ increased with increasing EB dose, which was reconfirmed that hydroxyl function was introduced via dehydrozenation. $T_m$ increased with increasing EB dose, inferring that the increase in EB dose led to more outbreak of hydroxyl function which led to more enhanced hydrogen bond. In the result of contact angle, pristine PVDF film was $62^{\circ}$ and 125 K Gray-irradiated PVDF film was even $13^{\circ}$. All results showed that pristine PVDF was successfully changed to hydrophilic PVDF.

Enhanced Performance of PVDF Piezoelectric Speaker Using PVDF/ZnO Nanopillar Composites (PVDF/ZnO Nanopillar 복합재료를 이용한 압전필름 스피커의 성능향상)

  • Kwak, Jun-Hyuk;Hur, Shin
    • Journal of Sensor Science and Technology
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    • v.25 no.6
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    • pp.447-452
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    • 2016
  • In this study, we fabricated and evaluated the performance of film speaker using PVDF/ZnO NP composite structure. PVDF piezoelectric films were fabricated and characterized by XRD and SEM. ZnO nanopillars were prepared by hydrothermal synthesis on prepared PVDF piezoelectric films. We analyzed and tested the acoustic signal characteristics of the piezoelectric film. In order to fabricate an acoustic structure with a wide frequency range from low to high frequency, we have fabricated various types of film speakers and investigated the frequency characteristics. As a result, the fundamental piezoelectric properties of PVDF show that the piezoelectric constant due to ZnO NP increases. And the overall acoustic signal level is also increased by 10% or more. We investigated frequency generation from 500 Hz to 10 KHz using different sizes with PVDF/ZnO NP composite film speaker.

Detection of High-Velocity Impact Damage in Composite Laminates Using PVDF Sensor Signals (고분자 압전 필름 센서를 이용한 복합재 적층판의 고속 충격 손상 탐지)

  • Kim Jin-Won;Kim In-Gul
    • Composites Research
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    • v.18 no.6
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    • pp.26-33
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    • 2005
  • The mechanical properties of composite materials may severely degrade in the presence of damage. Especially, the high-velocity impact such as bird strike, a hailstorm, and a small piece of tire or stone during high taxing, can cause considerable damage to the structures and sub-system in spite of a very small mass. However, it is not easy to detect the damage in composite plates using a single technique or any conventional methods. In this paper, the PVDF(polyvinylidene fluoride) film sensors were used for monitoring high-velocity impact damage initiation and propagation in composite laminates. The WT(wavelet transform) and STFT(short time Fourier transform) are used to decompose the sensor signals. A ultrasonic C-scan and a digital microscope are also used to examine the extent of the damage in each case. This research shows how various sensing techniques, PVDF sensor in particular, can be used to characterize high-velocity impact damage in advanced composite.

Measurements of Dynamic Strain of Structures Using PVDF Films (PVDF 필름을 이용한 구조물의 동적 변형률 측정)

  • Kim, Su-Min;Shin, Sung-Woo;Lee, Jae-Yong;Kim, Nam-Sik
    • Journal of the Korean Society of Safety
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    • v.26 no.6
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    • pp.64-70
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    • 2011
  • In this study, the applicability of PVDF films for measurements of dynamic strain in a structure was investigated. A relationship between the strain and the voltage response of a PVDF film was analytically derived. Free vibration test on a steel cantilever beam was performed and vibration response of the beam was measured both by a convential foil strain gauge and a PVDF film. Strain-voltage relationship obtained from the experiment was compared with the analytic relationship. Good agreement between the analytic and experimental relationships was observed. It was found that a tailored PVDF film can measure the dynamic strain of a structure as accurate as a conventional foil strain gauge.

Study on the Piezoelectric Direct Effect of PVDF Film (PVDF 필름의 압전정효과에 관한 연구)

  • 이용국;한득영
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.9
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    • pp.786-790
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    • 2000
  • This paper is concerned on the theoretical and experimental approaches of direct piezoelectric effect in the PVDF film. When a cantilever structure of PVDF film is bended by the external force, electric charges are concentrated on the electrode surface of the film due to the direct piezoelectric effect, and output voltage is induced from the terminals of the film. In this paper, a symbolic equation between the external force and the output voltage was introduced. Moreover, the theoretical output voltages were compared with the experimental results by falling balls, which were agreed well each other. This results can be useful in a warning system of abnormal pulse rate and breathing, and in detecting impact force and/or mechanical energy using bending of PVDF film.

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