• Corrosion Science and Technology
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• 제4권1호
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• pp.15-18
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• 2005

Hydroxyapatite(HAp) was synthesized using the waste sludge from semiconductor process and used as an anticorrosive pigment. The water absorption of coating pigmented with anticorrosive pigment and the corrosion at interface between coating and substrate were monitored using AC impedance techniques. The anticorrosive performance of HAp was compared with those of red lead(RL) and zinc potassium chromate(ZPC), which have been known as representative anticorrosive pigments. The amount of absorbed water in ZPC- and HAp- pigmented coatings was much higher compared to that in RL-pigmented and unpigmented film. However, it seems that the water absorbed into HAp- or ZPC-pigmented film is beneficial to anticorrosive function. The anticorrosive performance of HAp is superior or at least comparable to those of ZPC and RL. The excellent anticorrosive properties of HAp can be explained by its passivating ability, caused by the reaction of the soluble component of HAp with Fe to form iron phosphate in the presence of water.

• 대한토목학회논문집
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• 제44권2호
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• pp.183-190
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• 2024

폴리우레탄(PU) 폼과 같은 가연성 고분자 건축자재의 화재 안전성을 개선하기 위한 새로운 접근의 나노코팅 기술이 개발되었다. 산화 그래핀 (Graphene oxide, GO)과 같은 2차원 소재는 용액상에서 자기 정렬 및 점탄성적 특성을 보이는 액정성(Liquid Crystalline properties, LC)을 나타내며, 이를 이용하면 특정 농도 범위에서 3차원의 다공성 폼을 포함한 다양한 표면에 균일한 코팅이 가능하다. 또한, GO의 액정성을 이용하여 기능성 복합소재의 나노코팅을 위한 골격 구조체(Scaffold)를 형성할 수 있으며, 여기에 도파민(Dopamine)과 같은 무독성의 항산화성 저분자를 도입 후 폴리도파민(polydopamine, PDA)로의 중합을 유도하여 고난연성의 폴리도파민/산화그래핀 (PDA/GO) 나노복합체 코팅층을 형성할 수 있다. 또한 최종적으로 형성된 PDA/GO 코팅은 GO의 2차원 판상구조로 인하여 균일하게 적층된 나노시트 구조로 안정화되며, 이러한 구조적 특성으로 인하여 가스상의 유해 연소생성물의 발생과 확산을 효과적으로 저감할 수 있는 가스 차폐 효과도 유도할 수 있다. 이러한 2차원 소재의 액정성을 활용한 난연성 나노복합소재 코팅 기술은 다양한 유형의 고분자 건축 자재의 화재 안전성을 효과적으로 개선할 수 있는 친환경적이고 새로운 기술적 접근방식이 될 수 있다.

• 한국의류학회지
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• 제29권7호
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• pp.997-1007
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• 2005

The textile finishing methods utilizing chitosan have been mostly focused on the applications in the improvement of the dyeing of cotton fabrics, or the improvement of hand of the cotton or wool fabrics. On the other hand, it Is difficult to find the application examples in the synthetic fiber fabrics including polyester and nylon fabrics. The aim of this study is to improve the stiffness and the poor wash fastness of the fabrics treated only with chitosan. We tried to improve the softness by employing chitosan and polyurethane mixture solution and to prevent the detachment of the chitosan from the fabric. The treatment was applied to cotton, polyester, and nylon fabrics. The change of the properties of the treated fabrics were investigated. The optimum finishing condition was sought by changing the mixture ratio of the chitosan/PU(polyurethane) solutions. The adjusted ratios of the chitosan/PU solutions were 1 : 0, 1 : 0.25, 1 : 0.5, and 1 : 2 during the mixture solution preparation. Using the KES(Kawabata Evaluation System), the physical and mechanical properties of the finished fabric specimens were analyzed, and hand values of the specimens were calculated through the use of translational formulas. According to the chemical composition of the fibers, chitosan solution or chitosan/PU mixture exhibited wide range of coating effect. Since the chitosan acid solution has high polarity, the bonding force with the cotton fibers is high. By the appropriate addition of PU in the chitosan treatment of cotton, KOSHI and HARI values of the fabric improved. The air permeability of the chitosan/PU treated cotton fabric specimen improved, resulting in the highest value at the mixture of chitosan : PU=1:0.25.

• 패션비즈니스
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• 제15권4호
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• pp.110-121
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• 2011

As car seat is the closest part between driver and rider, the interest of the security and comfort of the seat is increasing. This research discovered the best condition for dyeing and finishing to produce a fabric for car seat and also developed the design of fabrication to give the feeling from such a finishing. The best condition of coating finishing solution is aqueous PU 65%, dye resist reagent 20%, water 12%, thicker 3%, and knife thickness 2mm, tenter temperature $170^{\circ}C$, tenter speed 35yard/min, viscosity 12,000cps and stirring time 100kg * 30min. According to the processing time of knife coating upon stirring the change of resin and the uneven of coating quantity was shown. This problems will be solved by means of automatic temperature control apparatus for resin and sealing device through a coming research.

• 폴리머
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• 제33권6호
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• pp.602-607
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• 2009

심혈관용 소재로서 혈관내피전구세포의 포획을 통해 in vivo 내피세포화가 가능한 표면을 가진 폴리우레탄 표면을 개발하였다. 혈관내피전구세포의 점착을 유도하는 CD34 단일클론항체(monoclonal antibody, mAb)를 표면에 도입하기 위해, poly (poly (ethylene glycol) acrylate-co-butyl methacrylate), poly (PEGA-co-BMA) 공중합체가 합성되었고, 이를 폴리우레탄 표면에 코팅하여 CD34 단일클론항체를 화학적으로 고정화하였다. 중합된 공중합체의 $^1H$-NMR 분석은 원하는 조성을 가진 poly(PEGA-co-BMA)의 합성이 가능함을 확인해 주었다. 이전 연구에서 개발된 PEG가 그래프트된 폴리우레탄과의 비교를 통해, 본 연구에서 제조된 poly(PEGA-co-BMA)가 코팅된 폴리우레탄 표면이 CD34 mAb의 고정화에 더 효과적인 것으로 나타났으며, 이는 CD34 mAb의 표면밀도와 활성도가 32배 이상 증가된 결과를 통해 증명되었다. 개질된 폴리우레탄 표면의 물리화학적 특성은 XPS와 물 접촉각, AFM에 의해 분석되었으며, 각각의 개질된 표면에 따른 표면의 특이적 성질을 잘 보여주었다. 본 연구에서 얻어진 결과들은 poly(PEGA-co-BMA)의 코팅을 통해 제조된 표면이 CD34 mAb의 고정화에 효과적임을 설명하였으며, 실제로 심혈관용 소재의 개발에 적용 가능성이 크다는 것을 증명해 주었다.

• 한국대기환경학회지
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• 제19권1호
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• pp.57-66
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• 2003

TiO$_2$ sol was prepared by sol-gel method, and this sol was coated in ceramic and glass bead by dip-coating method. The coated catalyst was applied to degrade benzene in the gas phase by exposing to UV -lamp (365 nm) in a batch reactor. The removal efficiency of the benzene was compared by changing various conditions such as the kind of chemical additives, the coating beads (ceramic and glass), solution pH, the initial concentration of TiO$_2$ sol, UV intensity, and benzene concentration. The physical structure of TiO$_2$ sol used in this study was found to be pu-rely anatase type from XRD analysis. The results showed that ceramic bead was effective as the coating agent rath-er than glass bead. The significant change in the benzene removal efficiency of benzene did not occur with chang-ing coating frequency and the initial concentration of TiO$_2$ sol. The removal efficiency of benzene increased with increasing UV intensity, and with acidic treatment of TiO$_2$-coated ceramic bead.

• 자원리싸이클링
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• 제26권6호
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• pp.97-101
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• 2017

메탈폼은 매우 많은 기공을 포함하는 세포상 구조를 갖는 고체금속을 일컫는다. 특히 관통 기공 같은 개기공들은 고온용 필터 및 촉매 지지체 등으로 산업적으로 많이 사용되고 있다. 본 연구에서는 슬러리 코팅공정으로 90% 이상의 기공율과 2 mm 이상의 기공크기를 갖는 Fe 폼을 제조하였다. 이때 Fe 분말과 $Fe_2O_3$ 분말의 혼합비를 달리하여 기공율과 기공크기를 제어하였다. 이를 위해 우선 분말, 증류수 및 폴리비닐알콜(PVA)를 균일하게 혼합하여 슬러리를 제조하였다. $Fe_2O_3$ 분말의 혼합 비율이 증가할수록 PU 폼에 코팅된 슬러리의 양이 증가한 반면 Fe 폼의 수축 및 기공율은 각각 감소하였다.

• 접착 및 계면
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• 제12권3호
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• pp.94-98
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• 2011

열경화성 및 열가소성 우레탄 수지 첨가에 따른 헤라크론/페놀수지 복합재료의 방탄성능 변화를 고찰하였다. 먼저 페놀 또는 우레탄 수지를 헤라크론 직조섬유에 스프레이 코팅하여 프리프레그를 제조하고, 이들의(페놀/우레탄) 비율을 변화시켜 16층의 복합재료를 $150^{\circ}C$에서 $150kg/cm^2$의 압력으로 25 min간 성형하여 제조하였다. 방탄성능은 1.1 g 모의파편탄(22 cal)으로 분석하였으며, 우레탄 수지의 종류 및 페놀/우레탄 프리프레그의 비율에 따른 V50 변화를 고찰하였다.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.374-374
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• 2006

Poly (N-isopropylacrylamide) (PNIPAAm) shows a lower critical solution temperature (LCST) at $32^{\circ}C$. Consequently, its thermosensitivity has extensively been investigated in coating materials as well as biomedical and agricultural industry. However, mechanical properties of the swollen gels are generally poor and reinforcement is often desired. A series of interpenetrating polymer networks (IPNs) and emulsion blends hydrogels of polyurethane (PU) and PNIPAAm were prepared in order to overcome the shortcomings of a normal PNIPAAm hydrogels. Regarding the mechanical reinforcement of swollen gel, a significant increase in compression and tensile properties has been obtained by incorporating PU.

• 한국의류산업학회지
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• 제15권4호
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• pp.630-634
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• 2013

Cow leather coated with polyurethane film that contains various organic photosensitizers was investigated to demonstrate the antimicrobial properties in the application of the material to protective clothing and home appliances. To prepare the antimicrobial coating on leather surfaces with high potency against microbes, photoactive agents, such as benzophenone (BP), 4,4'-bis(dimethylamino) benzophenone (MK), 4,4'-dihydroxybenzophenone (DHBP) and methylene blue (MB), were incorporated into polyurethane-based coating solutions. The photoactive antimicrobial agent treated leather samples were characterized by SEM, color appearance, color fastness against abrasion, and antimicrobial tests. The optical properties of organic photosensitizers indicated that active UV absorbance ranges were different: BP (around 250 nm), MK (around 360 nm), DHBP (around 305 nm) and MB (around 295 nm &570 nm-685 nm). The intensity of the UV absorbance curve at the UVA light wavelength for the antimicrobial test showed the highest value with MK; subsequently, this was followed by MB, DHBP and BP in decreasing order. The treated-leather samples demonstrated excellent antibacterial activity under UVA light. The antimicrobial effects for the Staphylococcus aureus were superior to Escherichia coli. Moreover, the polyurethane finishing showed an effective durability to abrasion. The overall results indicated that DHBP is the most suitable PU coating additive to provide antimicrobial properties to leather as well as color and surface appearance than MK, MB, and BP.