• 한국염색가공학회지
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• 제15권3호
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• pp.132-139
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• 2003

PTT[Poly(trimethylene terephthalate)] fibers was annealed by passing on the plate heater to illuminate the effects of annealing on the alkaline hydrolysis behavior properties with varying the treatment temperature for 0.5 second. The L010 and crystallinity were increased with increases in temperature. With the increases of the temperature, the dynamic viscoelastic behaviors were analyzed to be reduction in $T_{max}(tan\;\delta)$. The weight loss in alkaline solution was two times more rapid for the PTT annealed at $200^\circ{C}$ than the control samples. The kinetics of hydrolysis was confirmed that the hydrolysis of the PTT fibers in the alkaline solution was started from the surface of the fibers and selective to the amorphous region in continuation, on the basis of the results of the increase in crystallinity and the decrease in dye uptake at the initial stage of the hydrolysis.

• 한국염색가공학회지
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• 제15권2호
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• pp.59-67
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• 2003

PTT[poly(trimethylene terephthalate)] fiber was annealed by passing on the plate heater to illuminate the effects of annealing on the mechanical properties and dyeability with varying the treatment temperature for 0.5 second. The apparent crystal sizes and crystallinity were increased with increases in temperature. With the increases of the temperature, the dynamic viscoelastic behaviors were analyzed to be reduction in $T_{max} (tan{\delta})$. The initial modulus were observed to be a small enhanced. The shrinkage in hot water were reduced. The dyeability for disperse dye enhanced dramatically, for example, a satisfactory degree of exhaustion was obtained by dyeing at $95^\circ{C}$ for 30 min with the PTT fibers heat treated at $180^\circ{C}$.