• Analytical Science and Technology
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• v.10 no.4
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• pp.264-273
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• 1997

Anodic oxidation reaction was applied to remove trihalomethanes in an aqueous solution. Each component was determined by using solid phase microextraction(SPME) fiber and GC-ECD. Anodic and cathodic compartments were separated in order to protect contaminants and connected by $KNO_3$-agar bridge. The calibration graphs of the 6 THM components were shown good linearlity from a few ppb up to a few hundreds ppb concentration level. Anodes such as platinum(Pt), titanium(Ti). zircornium(Zr), titanium metal coated with iridium(Ti-Ir), and glassy carbon coated with mixed valence ruthenium(mv Ru) were tried to remove the THMs at different potentials. The best result was obtained on the Ti-Ir anode applied 9 volts DC. The electrode could effectively remove almost all the THM components from the stirring solution within about 1.5 hours. The glassy carbon electrode coated with mixed valence ruthenium showed excellent removing effect at the begining, but the maximum removing level was remained at 60% probably due to the destruction of the electrode surface. The concentration of chloroform, however, tends to be increased due to the electrode reaction producing the component at the condition.

• Korean Journal of Remote Sensing
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• v.38 no.6_1
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• pp.1141-1180
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• 2022

The application of satellite imageries has increased in the field of hydrology and water resources in recent years. However, challenges have been encountered on obtaining accurate evapotranspiration and soil moisture. Therefore, present researches have emphasized the necessity to obtain estimations of satellite-based evapotranspiration and soil moisture with related development researches. In this study, we presented the research status in Korea by investigating the current trends and methodologies for evapotranspiration and soil moisture. As a result of examining the detailed methodologies, we have ascertained that, in general, evapotranspiration is estimated using Energy balance models, such as Surface Energy Balance Algorithm for Land (SEBAL) and Mapping Evapotranspiration with Internalized Calibration (METRIC). In addition, Penman-Monteith and Priestley-Taylor equations are also used to estimate evapotranspiration. In the case of soil moisture, in general, active (AMSR-E, AMSR2, MIRAS, and SMAP) and passive (ASCAT and SAR)sensors are used for estimation. In terms of statistics, deep learning, as well as linear regression equations and artificial neural networks, are used for estimating these parameters. There were a number of research cases in which various indices were calculated using satellite-based data and applied to the characterization of drought. In some cases, hydrological cycle factors of evapotranspiration and soil moisture were calculated based on the Land Surface Model (LSM). Through this process, by comparing, reviewing, and presenting major detailed methodologies, we intend to use these references in related research, and lay the foundation for the advancement of researches on the calculation of satellite-based hydrological cycle data in the future.

• The Korean Journal of Nuclear Medicine
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• v.34 no.4
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• pp.336-343
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• 2000

Purpose: Thallous-201 chloride produced at Korea Cancer Center Hospital(KCCH) is used in detecting cardiovascular disease and cancer. Thallium impurity can cause emesis, catharsis and nausea, so the presence of thallium and other metal impurities should be determined. According to USP and KP, their amounts must be less than 2 ppm in thallium and 5 ppm in total. In this study, the detection method of trace amounts of metal impurities in $[^{201}Tl]$TICI injection with polarography was optimized without environmental contamination. Materials and Methods: For the detection of metal impurities, Osteryoung Square Wave Stripping Voltammetry method was used in Bio-Analytical System (BAS) 50W polarograph. The voltammetry was composed of Dropping Mercury Electrode (DME) as a working electrode, Ag/AgCl as a reference electrode and Pt wire as a counter electrode. Square wave stripping method, which makes use of formation and deformation of amalgam, was adopted to determine the metal impurities, and pH 7 phosphate buffer was used as supporting electrolyte. Results: Tl, Cu and Pb in thallous-201 chloride solution were detected by scanning from 300 mV to -800 mV Calibration curves were made by using $TINO_3,\;CuSO_4\;and\;Pb(NO_3){_2}$ as standard solutions. Tl was confirmed at -450 mV peak potential and Cu at -50 mV Less than 2 ppm of Tl and Cu was detected and Pb was not detected in KCCH-produced thallous-201 chloride injection. Conclusion: Detection limit of thallium and copper is approximately 50 ppb with this method. As a result of this experiment, thallium and other metal impurities in thallous-201 chloride injection, produced at Korea Cancer Center Hospital, are in the regulation of USP and KP Polarograph could be applied for the determination of metal impurities in the quality control of radiopharmaceuticals conveniently without environmental contamination.