• Title/Summary/Keyword: PREPOLYMER

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A Study on the Physical Properties of Polyurethane Resin Blended With Liquid Rubber (액상(液狀)고무를 Blend한 Polyurethane 수지(樹脂)의 특성(物性)에 관(關)한 연구(硏究))

  • Park, Seong-Ho;Choi, Sei-Young
    • Elastomers and Composites
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    • v.29 no.3
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    • pp.226-233
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    • 1994
  • The properties of the mixed prepolymer-urethane in the range of 10-40 phr were observed. LBR and LCR have same functional group but different in structure of molecular. The viscosity of mixture depending on content of rubber, adhesive strength, thermal property and compatibility with a diluted solvent are as follows: 1. The viscosity of the mixture was influenced by solubility of the diluent for urethane resin and liquid rubber. 2. Adhesive strength showed the highest value at 30phr rubber, decreased gradually at above 30phr rubber. And LBR revealed better physical property than that of LCR. 3. The most effective factors affecting adhesive strength are molecular structure of rubber, the type of solvent, and volatility. 4. Urethane resin containing LBR showed better compatibility for solvent and faster drying velocity. 5. LBR showed more favorable compatibility and dispersion state than those of LCR by analyzing the results of SEM.

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A Study on Curing Properties and Structures of Phase Separation for UV-Curable Resing and Alkyd Resin Blends (UV중합성 수지와 알키드 수지 혼합물의 경화특성 및 상분리 구조에 관한 연구)

  • 최정병
    • Journal of the Korean Graphic Arts Communication Society
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    • v.18 no.1
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    • pp.13-24
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    • 2000
  • UV-curable resin has the properties of quick-drying, high productivity at low temperature, energy, space saving, solventless, non-polluting and low-stinking, and thus, UV-curing system has been widely used in the fields of printing inks, adhesives, paints and coating agents. This study has been executed to develop a new functionnal material by the polymerization induced phase separation. The results obtained were as follows. As for the curing properties of the monomer/prepolymer/alkyd resin blends, it was found out that there was a peak by the polymerization induced phase separation when measuring the changes of viscosity and elasticity. It was also found out that such polymerization phase separation occurred in case that the alkyd resin contents were 20wt% and 30wt% and not found at the contents of 40wt%. Therefore, it would be desirable to maintain the contents of alkyd resin at less than 30wt% in order to use the polymerization induced phase separation.

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Synthesis and characterization of photoreactive prepolymers bearing cyclic moiety (Epoxy resin을 이용한 cyclic moiety가 포함된 고내열 감광성 prepolymer의 합성 및 특성연구)

  • 이성범;이명섭;임현순;강태수;김환건;이준영
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.44-47
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    • 2003
  • 21C 고도정보화 시대를 맞이하여 평판표시소자에 대한 요구가 급증하여 현재는 액정표시소자 (Liquid Crystal Display, LCD)가 가장 널리 사용되고 있는데, 특히 해상도가 우수한 TFT(Thin Film Transistor)-LCD에 대한 수요가 급증하고 있다. Full color TFT-LCD를 구성하는 재료 중 가장 높은 비중을 차지하고 있는 것이 color filter이며, 이것을 제조하는 데 있어 가장 중요한 기술은 화소 형성기술이다. 특히 가격은 고가이지만 해상성이 뛰어난 TFT-LCD에 주로 사용되는 안료분산법은 신뢰성, 특히 내열성 및 공정의 복잡성 등 문제점을 가지고 있다[1]. (중략)

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Effect of Process Parameters on Residual NCO and Viscosity of Pre-Polymers (Pre-Polymer의 제조에서 공정변수가 잔류 NCO 및 점도에 미치는 영향)

  • Kim, Sang-Oh;You, Man-Hee;Ha, Man-Kyung;Kwak, Jae-Seob
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.7 no.3
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    • pp.61-66
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    • 2008
  • For the production of urethane prepolymer, the effect of process parameters such as diisocyanate MDI and polyol TDI was tested. In this paper, design of experiments has been adopted for studying the effect of the process parameters on the improvement of NCO and viscosity of pre-polymer. As a result of comparison of different parameters, the effect of polyol was stronger than that of isocyanate in comparison of reactivity according to the amounts of isocyanate and polyol. Especially, NCO and viscosity of pre-polymer affected a product safety.

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Preparation and Properties of Waterborne Polyurethane-Urea/Poly(vinyl alcohol) Blends for High Water Vapor Permeable Coating Materials

  • Yun, Jong-Kook;Yoo, Hye-Jin;Kim, Han-Do
    • Macromolecular Research
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    • v.15 no.1
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    • pp.22-30
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    • 2007
  • High water vapor permeable coating materials were prepared by blending aqueous poly(vinyl alcohol) (PVA) solution with waterborne polyurethane-urea (WBPU) dispersions synthesized by prepolymer mixing process. Stable WBPU/PVA dispersions were achieved at PVA content below 30 wt%. As the water soluble polymer PVA content increased, the number and density of total micro-pores (tunnel-like/isolated micro-pores) formed after the dissolution of PVA in water increased, and the water vapor permeability of coated Nylon fabric also increased significantly. Using WBPU/water soluble polymer PVA blends as a coating material and then dissolving PVA in water was confirmed to be an effective method to obtain prominent breathable fabrics.

New Polymerization using Microwave Radiation

  • Lee, Jae-Heung;Kim, Yong-Seok;Hong, Young-Taik;Jung, Hyun-Min;Oh, Hyoung-Suk
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.213-213
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    • 2006
  • High molecular weight of polycarbonate(PC) and well dispersed PC/MMT nanocomposites were successfully prepared through the novel technology, microwave solid-state polymerization. In our studies, the microwave irradiation is more effective than conventional oil-bath heating on achieving the high molecular weight and uniform nanocomposites. Using the polycarbonate prepolymer made it possible to intercalate the short chains into the galleries of MMT more easily. And it was observed that prepared nanocomposites by microwave solid-state polymerization have more uniform dispersion of silicate of MMT into the polymer matrix than by oil heating.

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Novel RGB Polymer Dispersed Liquid Crystal Display using Color Pigments.

  • Shim, S.H.;Choi, S.Y.;Baek, D.H.;Kim, W.;Choi, S.E.;Son, G.;Suh, D.H.;Choia, J.W.;Lee, J.Y.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.784-787
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    • 2006
  • We have developed a RGB polymer dispersed liquid crystal film (RGB PDLC). To obtain the color display, color pigments are mixed in the prepolymer. We have presented an electro-optical performance of our cell and analyzed the electro optical properties for varying LC/ pre-polymer ratio and polymer type.

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Preparation of Microcapsules Containing Fragrant Oil and Its Application to Textile Finishing

  • Hwang, Jun-Seok;Kim, Jin-Nam;Wee, Young-Jung;Ryu, Hwa-Won;Yun, Jong-Sun;Jang, Hong-Gi;Kim, Sun-Ho
    • 한국생물공학회:학술대회논문집
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    • 2005.10a
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    • pp.860-863
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    • 2005
  • The microcapsules containing fragrant oil as functional material were prepared by in-situ polymerization with prepolymer that was made from melamine-formaldehyde (MF) as wall material of microcapsules. The effects of polymerization variables, such as the nature and concentration of surfactants, stirring rate, and stirring time, on the size and distribution of the particles were investigated. Fourier transform-infrared spectroscopy (FT-IR), thermal analysis, particle size analysis, scanning electron microscopy (SEM) observation were used to investigate the characteristics of microcapsules. Through the FT-IR and SEM analysis, we found that the prepared microcapsules were containing fragrant oil and the shape of particle was spherical. The nature and concentration of surfactants, stirring rate, and stirring time had profound effects on the particle size and particle size distribution.

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Fabrication of a CNT Filter for a Microdialysis Chip

  • An, Yun-Ho;Song, Si-Mon
    • Molecular & Cellular Toxicology
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    • v.2 no.4
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    • pp.279-284
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    • 2006
  • This paper describes the fabrication methods of a carbon nanotube (CNT) filter and a microdialysis chip. A CNT filter can help perform dialysis on a microfluidic chip. In this study, a membrane type of a CNT filter is fabricated and located in a microfluidic chip. The filter plays a role of a dialysis membrane in a microfluidic chip. In the fabrication process of a CNT filter, individual CNTs are entangled each other by amide bonding that is catalyzed by 1-Ethyl-3-(3-dimethylaminopropyl)carbodiimide (EDC) and N-hydroxysuccinimide (NHS). The chemically treated CNTs are shaped to form a CNT filter using a PDMS film-mold and vacuum filtering. Then, the CNT filter is sandwiched between PDMS substrates, and they are bonded together using a thin layer of PDMS prepolymer as adhesive. The PDMS substrates are fabricated to have a microchannel by standard photo-lithography technique.

Electrically controllable polymer-dispersed liquid crystal (전기적 스위칭이 가능한 고분자 분산형 액정 제작 및 동적 홀로그램 기록 특성)

  • 성기영;경천수;이영락;최병철;곽종훈;최옥식;이윤우
    • Korean Journal of Optics and Photonics
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    • v.10 no.6
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    • pp.494-499
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    • 1999
  • We report on the results of holographic transmission grating that can be controlled by the applied AC electric field. We have fabricated a polymer-dispersed liquid crystal material that composed of multifunctional acrylate monomer blended with the liquid crystal mixture E7. To investigate an electro-optic properties of fabricated HPDLC, diffraction efficienties (DE) are measured as a fuction of applied electric field and density of liquid crystal. Maximum DE of about 70% is obtained about 30 wt% of LC concentration at a zero field. We have also shown that optical image was recorded in the tllm, and then the reconstructive image was switchable with the applied electric fields. ields.

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