• 제목/요약/키워드: PMMAs

검색결과 5건 처리시간 0.021초

미세성형공정에서의 폴리머 레올로지의 정량화 (Quantitative rheology of polymers in high resolution structuring)

  • 김병희;김헌영;김호;김광순;강신일
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 춘계학술대회
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    • pp.1036-1042
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    • 2003
  • The hot embossing process has been mentioned as one of major nanoreplication techniques. This is due to its simple process, low cost, high replication fidelity and relatively high throughput. As the initial step of quantitating the embossing process , simple parametric study about embossing time have been carried out using high-resolution masters which patterned by the DRIE process and laser machining. Under the various embossing time, the viscous flow of thin PMMA films into microcavities during compression force has been investigated. Also, a study about simulating the viscous flow during embossing process has planned and continuum scale FDM analysis was applied on this simulation. With currently available test data and condition, simple FDM analysis using FLOW3D was made attempt to match simulation and experiment.

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Molecular Conformation and Application of Stereoregular PMMA Langmuir-Blodgett Films

  • Kim, Jang-Joo;Jung, Sang-Don;Hwang, Wol-Yon
    • ETRI Journal
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    • 제18권3호
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    • pp.195-206
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    • 1996
  • Molecular conformations of stereoregular poly(methyl methacrylate) (PMMA) monolayers have been investigated by scanning probe microscopes. Isotactic and syndiotactic PMMAs were found to have right and left hand helical structures, respectively. On the contrary atactic PMMA showed rather random arrangement of the chains. It has been demonstrated that the PMMA Langmuir-Blodgett (LB) films can be utilized to form nanoscale patterns down to 50 nm and to forma geodesic lens. It has also been manifested that the quantum efficiency of a polymer electroluminescent device can be significantly enhanced by inserting the PMMA LB films between the emitting layer and the cathode. All the applications utilize the unique characteristics of the LB films to form thin and uniform films in the molecular level.

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분자동역학을 이용한 PMMA 평판의 열접합 및 분리에 대한 연구 (Investigation of Thermal Fusion Bonding and Separation of PMMA Substrates by using Molecular Dynamics Simulations)

  • 이태일
    • 한국기계가공학회지
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    • 제17권5호
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    • pp.111-116
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    • 2018
  • Thermal fusion bonding is a method to enclose open microchannels fabricated on polymer chips for use in lab-on-a-chip (LOC) devices. Polymethyl methacrylate (PMMA) is utilized in various biomedical-microelectromechanical systems (bio-MEMS) applications, such as medical diagnostic kits, biosensors, and drug delivery systems. These applications utilize PMMAs biochemical compatibility, optical transparency, and mold characteristics. In this paper, we elucidate both the conformational entanglement of PMMA molecules at the contact interfacial regime, and the qualitative nature of the thermal fusion bonding phenomena through systematic molecular dynamics simulations.

반응성 아조염료로 착색한 PMMA의 성질 (Properties of PMMA Dyed with Reactive Azo Dye)

  • 금내리;허지원
    • 공업화학
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    • 제17권4호
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    • pp.426-431
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    • 2006
  • Poly(methyl methacrylate) (PMMA)의 착색을 위하여 아크릴 그리고 비닐설폰기를 가지는 청색 및 오렌지 아조 염료들을 6-bromo-2-cyano-4-nitroaniline과 2,5-dimethoxy-4-(vinylsulfonyl)benzenamine을 3-acrylamido-(N,N-diethylamino) benzene과 3-methyl-(N,N-diethylamino)benzene의 아조 짝지음 반응을 이용하여 각각 합성하였다. 또한 알릴기를 가지는 염료는 비닐설폰과 allylamine과의 반응에 의하여 제조하였다. PMMA의 착색은 아크릴, 비닐설폰 그리고 알릴 작용기를 가지는 염료를 직접 methyl methacrylate (MMA)와 공중합하거나, MMA와 공중합한 고분자염료 및 반응성기가 없는 염료 2를 직접 MMA에 용해하여 중합과 동시에 착색하였다. 3가지로 착색한 PMMA의 염색 견뢰도를 여러 환경 조건에서 염료의 용해도를 비교하여 평가하였다.

악교정수술환자에서 폴리메틸메터크릴레이트(아테콜$^{(R)}$) 주입을 통한 융비술 (PMMA MICROSPHERES (ARTECOLL$^{(R)}$) INJECTION FOR NASAL RIDGE AUGMENTATION IN THE ORTHOGNATHIC SURGERY)

  • 옥용주;김명진;팽준영;명훈;황순정;최진영;이종호;정필훈
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • 제31권4호
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    • pp.329-334
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    • 2005
  • Polymethyl-methacrylate(PMMA; Artecoll$^{(R)}$) microspheres suspended 1 : 3 in a 3.5% collagen solution has been used as an injectable implant for long lasting correction of wrinkles and minor skin defects. The patients with mandibular prognathism have increased necessity for nasal augmentation. Usually these patients usually get an additional rhinoplasty after orthognathic surgery. The purpose of this study is to evaluate the result of PMMA injection for nasal ridge augmentation simultaneously with the orthognathic surgery. PMMAs were injected to the nasal dorsum of 13 patients with mandibular prognathism to augment the nasal ridge at the end of the orthognathic surgery. The cephalometric X-ray and clinical facial photograph were taken at 2, 4 and 6 months after operation. Using S-N line, we calculated the change of soft tisuue on the nasal ridge and also investigated the degree of patients satisfaction at 6 months after operation. Most of the patients were satisfied with their nasal ridge height status from moderate to good degree. The average amount of nasal ridge augmentation was $1.4{\pm}0.5$ mm immediately after operation, $1.2{\pm}0.4$ mm at 2 months after operation. The postoperative nasal ridge height seemed to be remained stable after 2 months. Intraoperative PMMA injection is considered to be simple and effective technique which can be used for the minor augmentation of nasal ridge in the orthognathic patients.