• 제목/요약/키워드: PMMA material

검색결과 234건 처리시간 0.031초

Bracket bonding to polymethylmethacrylate-based materials for computer-aided design/manufacture of temporary restorations: Influence of mechanical treatment and chemical treatment with universal adhesives

  • Goracci, Cecilia;Ozcan, Mutlu;Franchi, Lorenzo;Di Bello, Giuseppe;Louca, Chris;Vichi, Alessandro
    • 대한치과교정학회지
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    • 제49권6호
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    • pp.404-412
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    • 2019
  • Objective: To assess shear bond strength and failure mode (Adhesive Remnant Index, ARI) of orthodontic brackets bonded to polymethylmethacrylate (PMMA) blocks for computer-aided design/manufacture (CAD/CAM) fabrication of temporary restorations, following substrate chemical or mechanical treatment. Methods: Two types of PMMA blocks were tested: $CAD-Temp^{(R)}$ (VITA) and $Telio^{(R)}$ CAD (Ivoclar-Vivadent). The substrate was roughened with 320-grit sandpaper, simulating a fine-grit diamond bur. Two universal adhesives, Scotchbond Universal Adhesive (SU) and Assure Plus (AP), and a conventional adhesive, Transbond XT Primer (XTP; control), were used in combination with Transbond XT Paste to bond the brackets. Six experimental groups were formed: (1) $CAD-Temp^{(R)}/SU$; (2) $CAD-Temp^{(R)}/AP$; (3) $CAD-Temp^{(R)}/XTP$; (4) $Telio^{(R)}$ CAD/SU; (5) $Telio^{(R)}$ CAD/AP; (6) $Telio^{(R)}$ CAD/XTP. Shear bond strength and ARI were assessed. On 1 extra block for each PMMA-based material surfaces were roughened with 180-grit sandpaper, simulating a normal/medium-grit ($100{\mu}m$) diamond bur, and brackets were bonded. Shear bond strengths and ARI scores were compared with those of groups 3, 6. Results: On $CAD-Temp^{(R)}$ significantly higher bracket bond strengths than on $Telio^{(R)}$ CAD were recorded. With XTP significantly lower levels of adhesion were reached than using SU or AP. Roughening with a coarser bur resulted in a significant increase in adhesion. Conclusions: Bracket bonding to CAD/CAM PMMA can be promoted by grinding the substrate with a normal/medium-grit bur or by coating the intact surface with universal adhesives. With appropriate pretreatments, bracket adhesion to CAD/CAM PMMA temporary restorations can be enhanced to clinically satisfactory levels.

Effects of Injection Molding Parameters and their Interactions on Mechanical Properties of PMMA/PC Blend

  • Hoang, Van Thanh;Luu, Duc Binh;Toan Do, Le Hung;Tran, Ngoc Hai;Nguyen, Pham The Nhan;Tran, Minh Sang;Tran, Minh Thong
    • 한국재료학회지
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    • 제30권12호
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    • pp.650-654
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    • 2020
  • A combination of Polycarbonate (PC) material and Polymethylmethacrylate (PMMA), fabricated using an injection molding machine, has been investigated to determine its advantages, as studied in Ref. 1). This paper aims to investigate the optimization of PMMA/PC blend for both tensile yield strength and impact strength. Furthermore, interaction effects of process conditions on mechanical properties including tensile yield strength and impact strength of PMMA/PC blend by injection molding process are interpreted in this study. Tensile and impact specimens are designed following ASTM, type V, and are fabricated by injection molding process. The processing conditions such as melt temperature, mold temperature, packing pressure, and cooling time are applied; each factor has three levels. As a result, in comparison with optimization of separated responses, mechanical properties of PMMA/PC are found to decrease when optimizing both tensile and impact strengths simultaneously. The melt temperature is found to be the most significant interaction parameter with the mold temperature and packing pressure. In addition, there is more interaction between the mold temperature and cooling time. This investigation provides a useful understanding of the control of injection molding processing of polymer blends in optical application.

100 W급 LED 보안 등기구용 비대칭 배광의 2차 렌즈 설계 (Secondary Optics Design of Dissymmetrical Light Distribution for 100 W LED Safety Luminaires)

  • 신익태;양종경;이동진;박대희
    • 한국전기전자재료학회논문지
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    • 제23권6호
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    • pp.471-476
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    • 2010
  • This paper has studied dissymmetrical light distribution design using the secondary optics in the simulation. fundamental Lambertian radiation distribution based on LED has been cut off by the secondary optics, and the first surface slope of lens and second surface slope of total reflection area have been calculated through formula. PMMA (the index of refraction: 1.49361) which is material of lens has been selected. critical angle($42.02993^{\circ}$) between Air and PMMA has been calulated by snell's law, and total reflection angle slope has been selected about $16.67^{\circ}$ to occur the total reflection. when the first surface slope and the second surface slope has been set up, Rays of all total reflection area have generated the total reflection. finally, designed LED Module has been estimated by Korean Industrial Standards for LED safety street lighting. dissymmetrical light distribution have been analyzed with reached effect of road illuminance, and average road illuminance which are each 70.6 lx, 40.35 lx, and 25.88 lx have been satisfied with Korean Industrial Standards for LED safety street lighting.

엑스선 촬영 시 보조도구 재료로써 탄소 섬유 강화 플라스틱의 유용성 (Usefulness of Carbon Fiber Reinforced Plastics as a Material of Auxiliary Tool for X-ray Imaging)

  • 문준호;구본열
    • 대한방사선기술학회지:방사선기술과학
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    • 제46권3호
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    • pp.197-205
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    • 2023
  • When taking X-rays, various auxiliary tools were used to fix a patient's exact shooting position and posture. In this study, we evaluated the usefulness of carbon fiber reinforced plastics(CFRP) 3K as a material of auxiliary tools by comparing poly methyl metha acrylate(PMMA), polycarbonate(PC), and CFRP 3K each of which has high radiolucency. X-ray radiolucencies were measured by stacking 1 mm panels of each material, and contrast to noise ratio(CNR) and signal to noise ratio(SNR) of images of each material were measured by comparing with None, which stands for images that are taken without any material. All three materials showed over 90% X-ray radiolucencies within 2 ㎜ thickness, and there was no significant difference. PC, PMMA and CFRP 3K had high CNR and SNR in order, and CFRP 3K showed the closest CNR and SNR to those of None. While taking X-rays, by using CFRP 3K material within 2 ㎜ thickness as a material of auxiliary tools, which are used to reduce re-shooting and X-ray exposure by fixing a patient's exact shooting position and posture and improve the quality of medical images, a high X-ray radiolucency of over 90% would be obtained, and the influence on the image could be minimized.

선형 이온 소스 적용을 통한 폴리머 소재의 표면구조 제어 (The surface morphology control of the polymeric material using a linear ion source)

  • 신민호;김병준;박영배;김도근
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.141.2-141.2
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    • 2016
  • 디스플레이, 센서 등 전자소자는 소형화 단계를 지나 인체 부착형 소자로의 발전을 요구하고 있다. 인체 부착을 위해서는 민감한 피부에 장시간 부착시 무해성과 탈부착의 자유로움이 요구되기에 기존의 화학물질을 활용한 접착 방식에서 개코도마뱀 또는 딱정벌레 발바닥에서 영감을 얻은 자연모사형 건식 접착 방식에 대한 연구가 활발하게 진행되고 있다. 폴리머를 이용하여 자연모사형 마이크로/나노구조 형성은 기계적으로 가공된 금형 몰딩과 후처리를 통한 매우 복잡한 공정이 요구된다. 본 연구에서는 이러한 복잡한 공정을 단순화하기 위해서 폴리머 소재에 플라즈마를 활용한 나노구조를 형성하는 방법을 소개하고자 하며, 건식 접착용 폴리머 소재(PMMA, PDMS)에 따른 표면구조 변화와 표면에너지 변화에 대한 연구를 수행하였다. 플라즈마 표면처리를 위해서 본 연구실에서 자체 개발한 선형이온소스를 활용하였으며 입사에너지, 노출시간, 사용가스에 따른 표면형상 변화를 주사전자현미경을 활용하여 관찰하였다. 또한 처리조건에 따른 표면에너지 변화를 확인하기 위해 물접촉각 변화를 측정하였다. PMMA는 입사에너지, 노출시간이 증가함에 따라 쉽게 나노기둥구조가 형성되었으나, 과도한 입사에너지 또는 노출시간에서는 표면구조가 에칭되면서 무너지는 것이 관찰되었다. 또한 PDMS는 동일한 조건에서 주름구조 형태를 보였으며 노출시간이 증가할수록 주름구조의 간격이 늘어남을 확인하였다. 본 연구 결과를 통해 나노 구조를 쉽게 제어할 수 있는 PMMA가 피부 부착형 접착 패치에 응용이 가능할 것으로 기대된다.

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단일 구조 및 진공층이 있는 이중 구조 폴리머 방음패널의 음향투과손실 비교 (Comparison of Sound Transmission Loss Through Single and Double with Vacuum Layer Polymer Soundproof Panel)

  • 이주행;김일호;안광호
    • 한국도로학회논문집
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    • 제15권6호
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    • pp.11-15
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    • 2013
  • PURPOSES : This study is to compare sound transmission loss(STL) value depending on the four kinds of materials, PC(Polycarbonate), PMMA(Polymethyl mathacrylate), PE(Polyethlyene), PP(Polypropylene), and two types of structure, single layer and double with vacuum layer, of soundproof panel. METHODS : With four sorts of polymer material, the specimens were made as various structures, 4 mm and 8 mm of single soundpoof panel and vacuum layered 4 mm of one. The experimental condition and procedures were complied with authorized process test, KS F 2808. RESULTS : STL of single panel made of PC were the greatest followed by PMMA, PE, PP regardless of the thickness of panel, However, STL of PMMA panel began to decrease around 2500 Hz and reached the lowest value among others in 5000 Hz. Vacuum layer soundproof panel showed good performance in more than 2000 Hz. Only vacuum layer panel made of PC presented resonance frequency at 800 Hz while that of other vacuum ones at 1000 Hz. CONCLUSIONS : According to results of single layer, it was found that single panel functioned as the theorical way we expected in terms of surface density. That trends were blurred as the panel got thicker. And it was suggested also that vacuum layer panel performed well at high frequency, more than 2000 Hz.

Bendable Photoelectrodes by Blending of Polymers with $TiO_2$ For Low Temperature Dye-sensitized Solar Cells

  • 유기천;리위롱;이도권;김경곤;고민재
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
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    • pp.319-319
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    • 2010
  • Dye-sensitized solar cells (DSSCs) based on plastic substrates have attracted much attention mainly due to extensive applications such as ubiquitous powers, as well as the practical reasons such as light weight, flexibility and roll-to-roll process. However, conventional high temperature fabrication technology for glass based DSSCs, cannot be applied to flexible devices because polymer substrates cannot withstand the heat more than $150^{\circ}C$. Therefore, low temperature fabrication process, without using a polymer binder or thermal sintering, was required to fabricate necked $TiO_2$. In this presentation, we proposed polymer-inorganic composite photoelectrode, which can be fabricated at low temperature. The concept of composite electrode takes an advantage of utilizing elastic properties of polymers, such as good impact strength. As an elastic material, poly(methyl methacrylate) (PMMA) is selected because of its optical transparency and good adhesive properties. In this work, a polymer-inorganic composite electrode was constructed on FTO/glass substrate under low temperature sintering condition, from the mixture of PMMA and $TiO_2$ colloidal solution. The effect of PMMA composition on the photovoltaic property was investigated. Then, the enhanced mechanical stability of this composite electrode on ITO/PEN substrate was also demonstrated from bending test.

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골다공증성 추체골절에 대한 경피적 척추성형술 : 초기성적 (Percutaneous Vertebroplasty in Treatment of Osteoporotic Vertebral Body Fractures : Early Result)

  • 유영상;신재학;김일만
    • Journal of Korean Neurosurgical Society
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    • 제30권2호
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    • pp.163-167
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    • 2001
  • Objective : Percutaneous vertebroplasty has recently been introduced as an interesting therapeutic alternative for the treatment of thoracolumbar vertebral body fractures in elderly persons with osteoporosis. The authors present the early results of this method. Method and Material : From July 1999 to April 2000, percutaneous transpedicular technique was used in 20 patients (2 men and 18 women) whose mean age was 67.5 years old(range 59-79) with painful vertebral compression(22) and burst(2) fractures. The interval between fracture and vertebroplasty ranged 1 day to 4 months. The procedure involved percutaneous puncture of the injured vertebra via transpedicular approach under fluoroscopic guidance, followed by injection of polymethylmetacrylate(PMMA) into the vertebral body through a disposable 11-guage Jamshidi needle. Result : The most common cause of fracture was slip down and the most frequent injured level was the twelfth thoracic spine. The procedure was technically successful bilaterally in 18 patients(9 thoracic and 15 lumbar spines) with an average injection amount of 7.7ml PMMA in each level. Seventeen(94.4%) patients reported significant pain relief immediately after treatment. Two leaks of PMMA were detected with postoperative CT in spinal epidural space and extravertebral soft tissue without clinical symptoms. Conclusion : Although this study represents the early results, percutaneous vertebroplasty seems to be valuable tool in the treatment of painful osteoporotic vertebral body fractures in elderly, providing acute pain relief and early mobilization.

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Evaluating the absorption loading technique to acrylic resin for drug delivery

  • Al-Kaabi, Arshad F.;Hamid, Mohammed A.
    • Advances in materials Research
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    • 제11권2호
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    • pp.165-170
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    • 2022
  • Acrylic resin or polymethylmethacrylate (PMMA) is one of the most attractive materials to be used for dental appliances manufacturing. It has been introduced as a biomaterial during the last century. This study aims to evaluate the compounds absorption and release through acrylic resin to be used for drug delivery as well. The study specimens were 10 pieces of heat-cured clear acrylic resin with dimensions of 10 × 10 × 2 mm. The specimens were dipped in methylene blue solution at a powder-water ratio of 1:20 for 5 days. The samples were removed and dipped in 5 ml distilled water vials for 24 hours. Then the specimens were replaced into new 5 ml vials and the process lasted for 4 days. The extracted solutions were analyzed by the visible light spectroscopy for absorbance. The statistical results showed a gradual increase in stain release from day 1 to day 4 with a significant difference between day 1 and day 4 solutions. The study showed that PMMA resin is able to absorb and release some compounds constantly and the absorption drug-loading technique is applicable to this material.

아크릴계 페놀수지 합성과 이를 이용한 도료의 물성연구 (A Study on the Synthesis of Acrylic Phenol Resins and Their Properties as a Paint)

  • 황수인;김영진;김동권
    • 공업화학
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    • 제24권2호
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    • pp.171-176
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    • 2013
  • 지구온난화 문제가 대두되면서 volatile organic compound (VOC) free 도료의 필요성이 크게 증가하고 있다. 현재 국내외적으로 사용되고 있는 도료의 약 70~80% 정도가 용매형 도료이다. 따라서 지구온난화 문제의 근본적인 해결을 위해서는 도료의 희석제로 사용되고 있는 용매인 휘발성 유기화합물(VOCs)의 배출을 최소화 할 수 있는 무용제형도료의 개발이 필수적이다. 본 연구에서는 무용제도료를 개발하기 위하여 기존의 페놀수지의 특성인 산성화로 인해 도료로 사용 시 부착성이 떨어지는 단점을 보완하기 위해 아크릴계 단량체들을 첨가하였다. 합성한 페놀수지와 PF/PMMA 블렌드 수지와 PF/PHEMA 블렌드 수지의 구조분석결과 블렌드된 형태를 확인하였고 접착인장강도실험을 통해 PF/PMMA 블렌드 수지가 2.818 Mpa의 값으로 도료시스템에 적용 가능성을 확인하였다.