• Title/Summary/Keyword: PMMA beads

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Drying Characteristics of Fine Polymers in an Inert Medium Fluidized Bed (매체유동층에서 미세 고분자의 건조특성)

  • Kim, Og-Sin;Lee, Dong-Hyun
    • Clean Technology
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    • v.17 no.3
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    • pp.209-214
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    • 2011
  • The effects of inlet gas velocity (0.26-0.31 m/s), inlet gas temperature (315-353 K) and the mass ratio (0.1-0.4) of fine polymer (crosslinked poly methyl methacrylate beads) to inert medium particles on the drying rate of fine polymer in a 0.15 m-ID ${\times}$ 1.0 m-high inert medium fluidized bed dryer have been investigated. Crosslinked PMMA beads of 20 ${\mu}m$ (group C) were used as fine polymer, and glass beads of 590 ${\mu}m$ (group B) were used as the inert medium. The drying rate increases with increasing inlet gas temperature and velocity. However, the drying rate decreases slightly as the mass ratio of fine polymer to inert medium particles increases. The particle size distribution of dried fine polymers was mono distribution.

Manufacturing of Flexible Patterned Cover Film for Solar Cell by Solution Coating (용액 코팅을 이용한 태양전지용 고분자 유연 패턴필름 제조)

  • Park, Chanwook;Kang, Ho-Jong
    • Polymer(Korea)
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    • v.37 no.5
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    • pp.656-662
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    • 2013
  • The flexible patterned cover film was made by a simple solution coating process using polymethyl methacrylate (PMMA) solution with glass beads. The effect of patterned cover film on the efficiency of solar cell has been investigated. It was found that the relative solar cell efficiency increased up to 3.4% with the incident light angle between $0-90^{\circ}$ by the sphere shape of glass bead coated on the film surface. This was understood that the loss of transmittance and scattering due to the light directional dependency on solar cell were minimized because the light entered glass beads normal to its surface regardless of incident light angle. The maximum relative solar cell efficiency was achieved when glass bead shape on the film is hemisphere and the relative efficiency increased with increasing the amount of glass bead on the film surface. However, too much glass beads on the film surface resulted in the lower relative solar cell efficiency due to the lowering of transmittance as well as the occurring of light interference.

Fabrication of Porous W by Heat Treatment of Pore Forming Agent of PMMA and WO3 Powder Compacts (기공형성제 PMMA와 WO3 분말 성형체의 열처리를 이용한 W 다공체 제조)

  • Jeon, Ki Cheol;Kim, Young Do;Suk, Myung-Jin;Oh, Sung-Tag
    • Journal of Powder Materials
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    • v.22 no.2
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    • pp.129-133
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    • 2015
  • Porous W with controlled pore structure was fabricated by thermal decomposition and hydrogen reduction process of PMMA beads and $WO_3$ powder compacts. The PMMA sizes of 8 and $50{\mu}m$ were used as pore forming agent for fabricating the porous W. The $WO_3$ powder compacts with 20 and 70 vol% PMMA were prepared by uniaxial pressing and sintered for 2 h at $1200^{\circ}C$ in hydrogen atmosphere. TGA analysis revealed that the PMMA was decomposed at about $400^{\circ}C$ and $WO_3$ was reduced to metallic W at $800^{\circ}C$. Large pores in the sintered specimens were formed by thermal decomposition of spherical PMMA, and their size was increased with increase in PMMA size and the amount of PMMA addition. Also the pore shape was changed from spherical to irregular form with increasing PMMA contents due to the agglomeration of PMMA in the powder mixing process.

THE USE OF VANCOMYCIN-IMPREGNATED POLYMETHYLMETACTYLATE BEADS FOR THE TREATMENT OF CHRONIC OSTEOMYELITIS (반코마이신을 함유한 Polymethylmetacrylate 비드를 이용한 만성 골수염의 치험례)

  • Lee, Hyung-Seok;Park, Young-Ju;Choi, Dong-Ju;Kim, Mi-Ja;Jang, Gae-Pyo;Kim, Jung-Rae;Kim, Sun-Youp;Ahn, Byung-Keun
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.26 no.6
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    • pp.672-676
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    • 2000
  • One of the current treatment methods for chronic osteomyelitis is removal of the infected and necrotic tissue to reduce the bacterial concentration as much as possible. This is performed concomitantly with antibiotic therapy. Chronic osteomyelitis(C.O.) implies chronic ischemia of the diseased bone. Thus, the treatment for C.O. requires high systemic level of antibiotics. In some cases, however, inherent undesirable adverse effects(for example, nephrotoxicity, ototoxicity, and others) may render this course of treatment difficult. Knowing that residual monomers are released from hardened bone cement, installation of antibiotic-impregnated PMMA(polymethyl-methacrylate) beads in situ have been one of treatment methods of C.O. When introduced into the wound, they established an exceedingly high level of local antibiotics for prolonged period without high systemic level of antibiotics. We experienced favorable results with vancomycin-impregnated PMMA beads for the treatment of C.O. of the mandible. So, we report it with literature reviews.

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Fabrication of Poly(methyl methacrylate) Beads Monolayer Using Rod-coater and Effects of Solvents, Surfactants and Plasma Treatment on Monolayer Structure (Rod 코팅을 이용한 Poly(methyl methacrylate) 비드의 단일층 형성 및 단일층 구조에 미치는 용매, 계면활성제, 플라즈마 처리의 영향)

  • Kim, Da Hye;Ham, Dong Seok;Lee, Jae-Heung;Huh, Kang Moo;Cho, Seong-Keun
    • Journal of Adhesion and Interface
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    • v.20 no.1
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    • pp.1-8
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    • 2019
  • Fabrication of monolayer is important method for enhancing physical and chemical characteristics such as light shielding and antireflection while maintaining thin film properties. In previous studies, monolayers were fabricated by various methods on small substrates, but processes were complicated and difficult to form monolayers with large area. We used rod coating equipment with a small amount of coating liquid to form a HCP (hexagonal closed packing) coating of PMMA beads on PET(poly(ethylene terephthalate)) substrate with $20cm{\times}20cm$ size. We observed that changes in morphologies of monolayers by using the solvents with different boiling points and vapor pressures, by adapting surfactants on particles and by applying plasma treatment on substrates. The coverage was increased by 20% by optimizing the coating conditions including meniscus of beads, control of the attraction - repulsion forces and surface energy. This result can potentially be applied to optical films and sensors because it is possible to make a uniform and large-scale monolayer in a simple and rapid manner when it is compared to the methods in previous studies.

AC Plasma Display Panel with Irregular Micro-scale Holes in the Front Dielectric Layer

  • Cho, Kwan-Hyun;Ahn, Sung-Il;Kim, Woo-Hyun;Choi, Kyung-Cheol
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.711-712
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    • 2009
  • The fabrication of micro-scale irregular holes by using PMMA (Poly Methyl Methacrylate) beads in the front dielectric layer was proposed to improve luminous efficacy of an ac plasma display panel. Through the firing process of front dielectric layer, bowl shaped holes with a depth of $2.5{\mu}m$, a top diameter of $8-12{\mu}m$, and a bottom diameter of $4-7{\mu}m$ were fabricated. The proposed ac plasma display panel with the irregular micro-scale holes improved the luminous efficacy by 18 % due to the decrease in the minimum sustain voltage.

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Design of MMA-Type Thermosetting Road Markings to Improve Reflectivity (재귀반사도 개선을 위한 MMA계 열경화성 차선도료의 설계)

  • Lee, Seung Bum;Lee, Chang Geun;Hong, In Kwon
    • Applied Chemistry for Engineering
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    • v.26 no.4
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    • pp.439-444
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    • 2015
  • Several attempts to design the best-available thermosetting road markings by using MMA to improve the durability and retroreflectivity are presented in this paper. In order to improve field applicability, the components of main materials were designed by means of reducing the hardening time lower than eight minutes. The optimum mixing ratio of thermosetting road marking was TSRM-6 composed of 15.6 wt% of MMA monomer ($Tg=105^{\circ}C$), 6.0 wt% of PMMA (MW = 70,000, $Tg=60^{\circ}C$) and 1.2 wt% of TMPTA (MW = 338, $Tg=27^{\circ}C$). Also the homogeneous mixing of all components was necessary. The use of ceramic glass beads with an optimized TSRM-6 exhibited excellent performance by achieving retroreflectivity coefficients of 431, 354 and $172mcd{\cdot}m^{-2}{\cdot}lux^{-1}$ for dry, wet and rainy test condition, respectively at two hundred thousand cycles.

Fabrication and characterization of the nano- and micro-particles applied dry adhesives (나노 또는 마이크로 입자의 전사를 이용한 건식 접착제의 제조 및 특성 분석)

  • Yu, Min Ji;Vu, Minh Canh;Han, Sukjin;Park, Jae Hong;Kim, Sung-Ryong
    • Journal of Adhesion and Interface
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    • v.20 no.1
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    • pp.23-28
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    • 2019
  • In this study, the micro- and nano-particles were used and their shapes were transferred into the polydimethylsiloxane (PDMS) film to fabricate the dry adhesives and their properties were investigated. The Cu nanoparticles of the sizes of 20 nm, 40 nm and 70 nm and the polymethylmethacrylate (PMMA) beads of the size of $5{\mu}m$ were used to transfer their images and the resultant properties of the dry adhesives were compared. The effects of particle size and materials on the mechanical property, tensile adhesion strength, light transmittance, surface morphology, water contact angle were studied. The dry adhesives obtained from the transfer process of Cu nanoparticles with the size of 20 nm resulted in the enhancement of tensile adhesion strength more than 300% compared to that of the bare PDMS. The formation of nanostructure of large surface area on the surface of the PDMS film by the Cu nanoparticles may responsible for the improvement. This study suggests that the use of nanoparticles during the fabrication of PDMS dry adhesives is easy and effective and could be applied to the fabrication of the medical patch.

Prediction of Mechanical and Electrical Properties of NiO-YSZ Anode Support for SOFC from Quantitative Analysis of Its Microstructure (미세조직 정량 분석을 통한 고체산화물연료전지용 NiO-YSZ 연료극 지지체의 기계적/전기적 성능 예측)

  • WAHYUDI, WANDI;KHAN, MUHAMMAD SHIRJEEL;SONG, RAK-HYUN;LEE, JONG-WON;LIM, TAK-HYOUNG;PARK, SEOK-JOO;LEE, SEUNG-BOK
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.5
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    • pp.521-530
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    • 2017
  • Improving the microstructure of NiO/YSZ is one of several approaches used to enhance the electrical and mechanical properties of an anode support in Solid Oxide Fuel Cells (SOFCs). The aim of the work reported in this paper was to predict the relationship between these microstructural changes and the resulting properties. To this end, modification of the anode microstructure was carried out using different sizes of Poly (Methyl Methacrylate) (PMMA) beads as a pore former. The electrical conductivity and mechanical strength of these samples were measured using four-probe DC, and three-point bend-test methods, respectively. Thermal etching followed by high resolution SEM imaging was performed for sintered samples to distinguish between the three phases (NiO, YSZ, and pores). Recently developed image analysis techniques were modified and used to calculate the porosity and the contiguity of different phases of the anode support. Image analysis results were verified by comparison with the porosity values determined from mercury porosimetry measurements. Contiguity of the three phases was then compared with data from electrical and mechanical measurements. A linear relationship was obtained between the contiguity data determined from image analysis, and the electrical and mechanical properties found experimentally. Based upon these relationships we can predict the electrical and mechanical properties of SOFC support from the SEM images.