• 제목/요약/키워드: PLS (Partial Least Squares) Regression

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초분광 영상을 이용한 액비 오염지역의 질산성질소 농도 추정 (Estimation of Nitrate Nitrogen Concentration in Liquid Fertilizer Contaminated Areas using Hyperspectral Images)

  • 임은성;김이슬;한수정;임태양;송원경
    • 한국재난정보학회 논문집
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    • 제16권3호
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    • pp.542-549
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    • 2020
  • 연구목적: 액비의 발효과정에서 생산된 질산성질소는 물의 오염지표로써 본 연구에서는 액비가 살포된 4개의 연구지역을 선정하고, 질산성질소의 오염 농도를 추정할 수 있는 모델을 제작하고자 하였다. 연구방법:현장촬영에 앞서 액비의 비율을 0%, 25%, 50%, 75%, 100%로 5개의 군으로 나누어 스펙트럼 라이브러리를 구축하였다. 스펙트럼의 양상을 토대로 연구지역에서 획득한 초분광 영상에 PLSR (Partial least squares regression) 방법을 적용하였다. 연구결과:구축한 액비의 스펙트럼을 1차, 2차 미분하여 질산성질소의 거동을 확인하였다. 현장실험의 영상을 이용하여 PLSR 농도 추정 모델링을 실시하여 실제 질산성질소의 농도와 비교하였다. 결론: PLSR 농도 추정 모델과 실제 질산성질소의 농도를 비교하였을 때 질산성질소의 농도가 70 mg/kg 이상인 고농도 지역에서 탐지가 가능하다고 판단되었다.

Major Characteristics Affecting the Sensory Quality of Rice Marketed in Korea

  • Jang, Eun-Hee;Kim, Qui-Woung;Kim, Hoon;Kim, Dong-Chul;Lee, Se-Eun;Kim, Sang-Sook
    • Food Science and Biotechnology
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    • 제17권1호
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    • pp.66-71
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    • 2008
  • A total of 284 milled rice (MR) marketed in Korea were analyzed for grading characteristics (head rice, broken kernels, chalky kernels, and damaged kernels%), color characteristics (L-, a-, b-values, and whiteness), protein content (%), and the cooked rice (CR) sensory quality to investigate the key characteristics affecting the overall sensory quality of rice marketed in Korea. Relatively high correlation with the overall sensory quality of the CR was found in color characteristics such b-value of the CR (r=-0.779) and MR (r=-0.545), the a-value of the CR (r=0.513), and the whiteness (r=0.298) of the MR, compared to protein (r=-0.150), and the moisture (r=0.158) contents of the MR and the percentage of head rice (r=0.195). Partial least squares (PLS) regression of the CR b-value with various characteristics of the MR showed that CR b-value was increased with MR b-value effectively, followed by protein content, damaged kernels, chalky kernels, and colored kernels of MR while it was decreased with whiteness and moisture content for the MR.

Factors Influencing Use of Social Commerce: An Empirical Study from Indonesia

  • RAHMAN, Arief;FAUZIA, Refika Nurliani;PAMUNGKAS, Sigit
    • The Journal of Asian Finance, Economics and Business
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    • 제7권12호
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    • pp.711-720
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    • 2020
  • This research aims to analyze the factors affecting the acceptance of social commerce, including performance expectancy, effort expectancy, social support, facilitating conditions, hedonic motivation, habitability, price saving orientation, and privacy concerns using the Unified Theory of Acceptance and Use of Technology (UTAUT2). UTAUT2 has been examined and modified in various contexts. The research model studies the acceptance and use of technology in the context of customers. This study adopts a quantitative method using the partial least squares regression (PLS) approach involving 244 respondents. The respondents are users of social commerce in Indonesia. The result of this research indicates that social influence, facilitating conditions, hedonic motivation, habit, price value orientation, and privacy concerns have a significant effect on behavioral intention. On the other hand, performance expectancy and effort expectancy does not affect behavioral intention. Furthermore, price value has a significant effect on social commerce user behavior. Lastly, facilitating conditions and habits does not affect social commerce user behavior. This research contributes to the development of theory by examining an additional variable, which is privacy concern. This study is significant since social media and social commerce have grown exponentially nowadays. Implications of the results for the development of the theory (UTAUT2) and practice are discussed in the article.

ANALYTICAL APPLICATIONS OF NEW PORTABLE NEAR INFRARED (NIR) SPECTROMETER SYSTEM

  • Ahn, Jhii-Weon;Kang, Na-Roo;Lim, Hung-Rang;Lee, Jung-Hun;Woo, Young-Ah;Kim, Hyo-Jin
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1122-1122
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    • 2001
  • A compact and handhold near infrared (NIR) system using microspectrometer was developed. This system was suitable not only in the laboratory, but also in the field or in the process. This system was first applied for classification of geographical origin of herbal medicine such as ginseng and sesame. To identify the origin of ginseng on site, the portable NIR system is more suitable for real field application. For this study, using the compact NIR system, soft independent modeling of class analogies (SIMCA) with 1100-1750 nm NIR spectra was utilized for classification of geographical origin (Korea and China) of both ginseng and sesame. The accuracy of results is more than 90%. Quantitative analysis for petroleum such as toluene, benzene, tri-methyl benzene, and ethyl benzene was performed with partial least squares (PLS) regression with NIR 1100-1750 nm spectra. This study showed that the NIR method and gas chromatography (GC), which is a standard method, have good correlations. Furthermore, the ash content of Cornu Cervi Parvum was analyzed and the accuracy was confirmed by the developed compact NIR system.

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Studies on pharmaceutical assay method using Near Infrared Spectroscopy (NIRS) (II)

  • Kang, Shin-Jung;Yun, Mi-Ok;Lee, Su-Jung;Choi, Hyun-Chul;Kim, Ho-Jeong;Kim, Ji-Yeon
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.4113-4113
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    • 2001
  • This study developed effective assay method of pharmaceutical quality control was developed by near-infrared spectroscopy (NIRS). The calibration equation model of assay was developed by 2nd deriviative PLS(Partial Least Squares) regression method with NIRS over the wavelength range from 1100 to 1400nm using diazepam tablets (2mg, 5mg). Although diazepam tablets are made by 5-different manufacture, they have similar formulation. When the correlation was compared with values by NIRS and HPLC, the R-2s and standard error of calibration (SEC) for 2mg were 0.9300 and 0.98%, the R-2s and SEC for 5mg were 0.9165 and 0.63%. The validation of the calibration equation model yield that the R-2s and standard error of prediction (SEP) for 2mg were 0.9611 and 0.995%, the R-2s and SEP for 5mg were 0.9114 and 0.842%. The method was validated on assay method for diazepam tablets by the calibration equation.

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The Mediating Effects of Bidirectional Knowledge Transfer on System Implementation Success

  • Kim, Jong Uk;Kim, Hyo Sin;Park, Sang Cheol
    • Asia pacific journal of information systems
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    • 제25권3호
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    • pp.445-472
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    • 2015
  • Although knowledge transfer between two different parties occurs in IS development projects, the majority of prior studies focused on knowledge transfer from IT consultants to clients. Considering two parts of knowledge transfer in IS development projects, we must consider both 'where knowledge is transferred from' and 'where it is transferred to'. Therefore, in this study, we attempt to describe two different routes of knowledge transfer, such as knowledge transfer from an IT consultant to a client and knowledge transfer from a client to an IT consultant. In this regard, we have examined the effect of two different routes of knowledge transfer on system implementation success in IS development project. Specifically, we adopted the knowledge stock-flow theory to examine the causal relationship between IT consulting firms and clients in terms of knowledge transfer and eventual system implementation success. Survey data collected from 213 pairs of individuals (both clients and IT consultants) were used to test the model using three different analytic approaches such as PLS (partial least squares) and two types of mediated regression techniques. We found that knowledge transfers partially mediated both the relationships between IT consultants' IT skills (project members' business knowledge) and system implementation success. Furthermore, the effects of each knowledge transfer were distinguished by depending on the types of system, such as ERP or groupware. Our attempts have significant implications for both research and practice given the importance of effective knowledge transfer to IT consulting.

근적외선 분광분석법을 이용한 생약의 원산지 판별 (Discrimination of Herbal Medicine According to Geographical Origin (Korea, China) Using Near Infrared Reflectance Spectroscopy)

  • 우영아;조창희;김효진;조정환;조경규;정승성;김수정;김중환
    • 약학회지
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    • 제42권4호
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    • pp.359-363
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    • 1998
  • Near infrared reflectance spectroscopy (NIRS) was applied for discrimination according to geographical origin (Korea, China) of herb drugs. Herbal medicine has an important role in clinical therapy in Asian countries such as Korea and China. The objective of this study is to provide a convenient and accurate method to determinate geographical origin (Korea, China) of herbal medicine for quality control whose quality is generally different according to geographical origin. A rapid, nondestructive and accurate discrimination was achieved by NIRS. Second derivative spectra of herb drugs were subjected to discriminant analysis. Herbal medicine drugs such as Cassia Semen, Ganoderma and Smilacis Rhizoma was discriminated accurately according to geographical origin using PLS regression method.

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세 가지 방식의 근적외선 분광분석기를 이용한 글루코오스 수용액의 측정 (Aqueous Glucose Solution Measurement by Three Types NIR Spectrometer)

  • 백주현;강나루;우영아;김효진
    • 약학회지
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    • 제47권6호
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    • pp.461-468
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    • 2003
  • A method is described for measuring clinically relevant levels of glucose in a pH 7.4 phosphate buffer by nearinfrared (NIR) absorption spectroscopy. Three types of NIR spectrometer, dispersive type, photo-diode array (PDA) type, and fourier transform (FT) type spectrometer were used and the performance was compared. Spectra were collected with a cuvette cell or quartz liquid fiber of 1 mm or 2 mm optical pathlength as transmittance method. Glucose absorption band appeared at second overtone, first overtone, and combination region for all systems. By use of the multivariate technigue of partial least squares (PLS) regression, glucose concentrations can be determined with a 16, 44, and 9.1 mg/d l standard error of prediction for dispersive type, photo-diode array type, and fourier transform type system, respectively. Sensitivity of spectrometer was evaluated by absorbance for the difference of 10 mg/d l glucose. Three absorption bands, second overtone, first overtone, and combination region were suited to three types systems, dispersive type, photo-diode array type, and fourier transform type systems, respectively. This investigation showed that three types NIR spectrometer were proper method for identification and quantitative analysis of glucose and possible for noninvasive blood glucose monitoring.

근적외선 분광분석법을 이용한 낙엽송 목분의 함수율 예측 모델 개발 (Development of Moisture Content Prediction Model for Larix kaempferi Sawdust Using Near Infrared Spectroscopy)

  • 장윤성;양상윤;정현우;강규영;최준원;최인규;여환명
    • Journal of the Korean Wood Science and Technology
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    • 제43권3호
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    • pp.304-310
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    • 2015
  • 저장 또는 운송단계에서 목분에 포함된 수분의 부적절한 조절은 생물학적 열화로 인한 품질하락 및 손실을 야기할 수 있기 때문에 목분의 함수율은 정확하게 측정되어야 하고 적절하게 조절되어야 한다. 본 연구에서는 근적외선(파장 대역: 1000-2400 nm) 분광분석법을 적용하여 낙엽송(Larix kaempferi) 목분의 함수율을 측정하고자 하였다. 각 상대습도($25^{\circ}C$, RH 30~99%) 단계별로 조습된 목분의 근적외선 반사스펙트럼을 측정하고, 적정 수학적 전처리(smoothing, standard normal variate)와 부분최소자승법을 적용하여 예측모델을 개발하였다. 도출된 함수율 예측모델은 높은 신뢰도를 보였다($R^2$ = 0.94, RMSEP = 1.544). 본 연구에서 개발된 근적외선 분광분석법을 통하여 비파괴적이면서 정확하고 신속한 목분 함수율의 측정과 효율적인 목재이용을 견인할 수 있으리라 기대된다.

Simultaneous Spectrometric Determination of Caffeic Acid, Gallic Acid, and Quercetin in Some Aromatic Herbs, Using Chemometric Tools

  • Kachbi, Abdelmalek;Abdelfettah-Kara, Dalila;Benamor, Mohamed;Senhadji-Kebiche, Ounissa
    • 대한화학회지
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    • 제65권4호
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    • pp.254-259
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    • 2021
  • The purpose of this work is the development of a method for an effective, less expensive, rapid, and simultaneous determination of three phenolic compounds (caffeic acid, gallic acid, and quercetin) widely present in food resources and known for their antioxidant powers. The method relies on partial least squares (PLS) calibration of UV-visible spectroscopic data. This model was applied to simultaneously determine, the concentrations of caffeic acid (CA), gallic acid (GA), and quercetin (Q) in six herb infusion extracts: basil, chive, laurel, mint, parsley, and thyme. A wavelength range (250-400) nm, and an experimental calibration matrix with 21 samples of ternary mixtures composed of CA (6.0-21.0 mg/L), GA (10.0-35.2 mg/L), and Q (6.4-17.5 mg/L) were chosen. Spectroscopic data were mean-centered before calibration. Two latent variables were determined using the contiguous block cross-validation procedure after calculating the root mean square error cross-validation RMSECV. Other statistic parameters: RMSEP, R2, and Recovery (%) were used to determine the predictive ability of the model. The results obtained demonstrated that UV-visible spectrometry and PLS regression were successfully applied to simultaneously quantify the three phenolic compounds in synthetic ternary mixtures. Moreover, the concentrations of CA, GA and Q in herb infusion extracts were easily predicted and found to be 3.918-18.055, 9.014-23.825, and 9.040-13.350 mg/g of dry sample, respectively.