• Title/Summary/Keyword: PFCs(Perfluorinated compounds)

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The Study of Emulsion System Containing with Perfluorinated Compounds (PFCs) (Perfluorinated Compounds (PFCs) 안정화 시스템의 연구)

  • Choi, Bong-Ki;Cho, Hee-Won;Kim, Hyo-Jung;Lee, Joo-Dong
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.33 no.4
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    • pp.239-243
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    • 2007
  • When Perfluorinated Compounds (PFCs) are applied in cosmetic products, they have many merits because of unique feeling and characters. However, it is very difficult to use them as cosmetic ingredients because they are insoluble material in oil and water and have high specific gravity. To develop a special system to stabilize PFCs in cosmetic products, we compared three systems, of gel network system, spherulite lamellar system, and nanostructure system. We found that nanostructure system was the optical system for stabilizing PFCs.

Perfluorinated Compounds; New Challenge and Problem (과불화 화합물 (PFCs); 새로운 도전과 과제)

  • Son, Hee-Jong;Yoo, Soo-Jeon;Roh, Jae-Soon
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.12
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    • pp.1151-1160
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    • 2009
  • Perfluorinated compounds (PFCs) have been recognized as emerging environmental pollutants and are widely distributed all over the world. These compounds are hardly degradable and cause bioaccumulation and biomagnification during present for a long time in the environment: thereby after adversely biota and human bodies. It is difficult to remove PFCs using conventional water/wastewater treatment because of resistant property to photodecomposition, biodegradation and chemical decomposition. Moreover, domestic literature data on the pollution of PFCs in rivers and lakes are limited. In this paper, species, sources and risk of PFCs as well as behavior properties in drinking water/wastewater and treatment processes are demonstrated to encourage the domestic concern about PFCs.

Bioconcentration of Perfluorinated Compounds in Fish from Gulpo Stream (굴포천에 서식하는 어류체내 과불화화합물 농축특성)

  • Cho, Chon-Rae;Cho, Jae-Gu;Eom, Ig-Chun;Lee, Byoung-Cheun;Kim, Sue-Jin;Choi, Kyung-Hee;Yoon, Jun-Heon
    • Environmental Analysis Health and Toxicology
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    • v.25 no.3
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    • pp.229-240
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    • 2010
  • During the last decade, perfluorinated compounds (PFCs) have gained more attention due to their toxicity and global distribution. The aim of this study was to examine the distribution and bioaccumulation of perfluorinated compounds (PFCs) in aquatic wildlife effected from a sewage treatment plant. The concentrations of 12 PFCs were determined in water, sediment and fish samples. PFOS were predominantly detected in both ambient environment and fish. In fish, the concentration of PFCs in blood was the highest (i.e., 112.47 ng/mL wet-wt. PFOS) in comparison to other tissues. However, PFOA and PFHpS were highly detected in gonad as 3.87 and 4.58 ng/g wet-wt., respectively. The bioconcentration factor (BCF) of PFCs was greatest in the blood > liver${\cong}$gonad > kidney > gill, and lowest in the muscle tissue. The BCFs of PFUnDA (39,000), PFDA (2,700) and PFOS (1,100) were rated as high values based on wet weight concentration. BCFs increased with increasing the length of the perfluoralkyl chain.

Characteristics of Perfluorinated Compounds Detected in Landfill Leachates on Jeju Island (제주도 쓰레기매립장 침출수 중 과불화화합물의 검출 특성)

  • Paik, Byeong Cheon;Kam, Sang-Kyu
    • Journal of Environmental Science International
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    • v.30 no.8
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    • pp.673-684
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    • 2021
  • Raw leachates from three landfills and treated leachates from two landfills on Jeju Isalnd were analyzed for ten perfluorinated compounds (PFCs) detected in aquaruc environments. The leachates were collected six times in 2014 and 2015. Among the ten PFCs, three were not detected, namely perfluoroundecanoic acid (PFUnDA), perfluorododecanoic acid (PFDoDA), and perfluorodecane sulfonate (PFDS). The total concentrations of PFCs ranged as 724-3313 ng/L (mean 1999 ng/L) in raw leachates and from less than the limit of quantification (LOQ) to 394 ng/L (mean 133.2 ng/L) in treated leachates. The domonant compounds measured were perfluorooctanoic acid (PFOA) (mean contribution 37.7%) and perfluorobutane sulfonate (PFBS) (mean contribution 38.2%) in raw leachates, and PFOA (mean contribution 40.7%), perfluorohexanoic acid (PFHxA) (mean contribution 27.3%) and PFBS (mean contribution 26.5%) in treated leachates. No significant correlations were observed between total/several individual PFCs and leachate pH and CODCr, which may be due to complex chemical nature of landfill leachates and characteristics of waste and landfills.

Analytical trend of perfluorinated compounds in environmental and biota samples (환경 및 생체시료 중 과불화 화합물의 분석 동향)

  • Lee, Won-Woong;Chang, Won-Hee;Pyo, Hee-Soo;Kang, Tae-Seok;Hong, Jong-Ki
    • Analytical Science and Technology
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    • v.23 no.4
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    • pp.331-346
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    • 2010
  • Perfluorinated compounds have characteristics of resistance to heat, acidic, basic conditions and also resist water, oil, grease, pollutant. Futhermore they are used by various industrial material, nowadays, they produced in large scale for indutrial and commercial areas. However, they also resist metabolizing and degrading in environmental system (plant, animal, even human body). Moreover, in animal's bodies, PFCs can be accumulated in organ (eg; liver) and lead to liver cell necrosis even oncogenesis. Perfluorinated compounds are newly registered as new persistent organic pollutants (POPs) on Stockholm convention in 2009. Therefore necessity for analytical methodology for determination of PFCs in various environmental samples is even more increased. This study discussed sample preparation and instrumental conditions for the analysis of PFCs in environmental and biota samples.

Monitoring of Perfluorinated Compounds (PFCs) in the Seawater of the East and West Coast in Korea (동·서해안지역 해수에서 과불화 화합물의 모니터링)

  • Son, Jun-ho;Chung, Seon-Yong;Kwon, Bum Gun
    • Journal of the Korean GEO-environmental Society
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    • v.18 no.11
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    • pp.5-12
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    • 2017
  • Perfluorinated compounds (PFCs) as environmental pollutants are an important environmental issue. However, little is known on the PFCs monitoring of sea waters around estuaries on the East and West Coasts of Korea. This study shows the monitoring results of PFCs in sea waters in these Coasts. Among 10 PFCs selected in this study, concentrations of perfluorooctanesulfonate (PFOS), perfluorooctanoate (PFOA), perfluorobutane sulfonate (PFBS), and perfluorohexane sulfonate (PFHxS) in the East Coast were 9.6-50.7 ng/L (total mean${\pm}$standard deviation: $26.14{\pm}12.66ng/L$), 13.79-44.58 ng/L ($27.95{\pm}11.41ng/L$), limit of quantification (LOQ)-2.6 ng/L ($0.96{\pm}1.15ng/L$), and 2.95-11.05 ng/L ($4.25{\pm}2.57ng/L$), respectively. In the West Coast, concentrations of PFOS, PFOA, PFBS, and PFHxS were 27.66-51.71 ng/L ($36.27{\pm}7.79ng/L$), 8.97-22.53 ng/L ($14.47{\pm}4.25ng/L$), LOQ-2.27 ng/L ($1.63{\pm}0.93ng/L$), and 3.0-7.66 ng/L ($4.27{\pm}1.49ng/L$), respectly. Other PFCs were below LOQ. The result of this study provides the distribution pattern of PFCs for assessing environmental pollution in two coastal areas of Korea.

Levels of perfluorinated compounds in prepared foods in Korea (국내의 조리 식품 중 과불화화합물의 잔류 수준)

  • Shin, Jae-Ho;Kho, Younglim;Park, Nayoun;Bang, Sunah;Lim, Cho Rong;Kim, Pan-Gyi;Kim, Jung Hoan
    • Korean Journal of Food Science and Technology
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    • v.48 no.6
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    • pp.555-559
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    • 2016
  • Perfluorinated compounds (PFCs) are linked to adverse effect on human healths, therefore, the aim of this study was to determine the levels of PFCs in prepared food. One hundred and fifty-one samples of six prepared food groups were purchased from retail food establishments in Korea. Twelve PFCs were detected in the sample, the accuracy ranged between 80.8-119.4% and precision ranged between 2.2-2.89% high and low concentrations in PFCs spiked samples. The detection frequency of perfluoro-pentanoic acid (PFPeA) was and perfluorooctanoic acid (PFOA) above the limit of detection, which was 84.1 and 82.8%, respectively, but positive detection frequency of perfluorooctanesulphonic acid (PFOS) was as shown as low as 29.1%. Residual PFOA levels in most of the samples were higher than the PFOS levels. The average concentration of total PFCs in the samples was $1.68{\pm}1.79ng/g$, and PFPeA and PFOA were the predominant PFCs.

The Evaluation of Adsorption Characteristics of Perfluorinated Compounds (PFCs) in GAC Process Using Continuous Column Adsorption Test (연속 컬럼흡착 실험을 이용한 GAC 공정에서의 과불화 화합물(PFCs) 흡착 특성 평가)

  • Son, Hee-Jong;Yoo, Soo-Jeon;Jang, Seung-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.3
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    • pp.206-212
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    • 2013
  • This study accessed the adsorption characteristics of the 11 perfluorinated compounds (PFCs) on coal-based granular activated carbon (GAC). The breakthrough appeared first for PFODA and sequentially for PFHDA, PFTeDA, PFTDA, PFDoDA, PFUnDA, PFDA, PFNA, PFOA, PFOS, and PFHpA. The maximum adsorption capacity (X/M) for the 11 PFCs with apparent breakthrough points ranged from 2.43 ${\mu}g/g$ (for PFODA) to 64.5 ${\mu}g/g$ (for PFHpA). Carbon usage rate (CUR) for PFODA was 0.291 g/day, 11.2 times higher than that for PFHpA (0.026 g/day). The X/M values for the 11 PFCs were fitted well with a linear regression ($r^2$ = 0.89) by their molecular weight (chain length).

Application of On-Line SPE-LC/MSD to Measure Perfluorinated Compounds (PFCs) in Water (On-Line SPE-LC/MSD 시스템을 이용한 수중의 과불화 화합물(PFCs) 분석)

  • Son, Hee-Jong;Yoom, Hoon-Sik;Jung, Jong-Moon;Jang, Seung-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.2
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    • pp.75-83
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    • 2013
  • We applied a sensitive method based on on-line solid-phase extraction (SPE) and liquid chromatography/mass spectrometry (LC/MSD) using an electrospray interface for the determination of eleven perfluorinated compounds (PFCs) in water. The on-line connection suppressed the target loss by keeping the cartridge from drying, which resulted in improvement of the recovery and saving of the analytical time. For the on-line solid-phase extraction of 10 mL water samples, recoveries were between $80.4{\pm}5.2%{\sim}109.5{\pm}1.4%$ and limit of quantification (LOQ) were 3.6~15.9 ng/L for the PFCs. The total PFCs concentrations of the tributaries and main stream of Nakdong River water samples were in the range of $8.0{\sim}678.6{\mu}g/L$.

Evaluation of perfluorinated compounds removal performance and automatic regeneration performance by activated carbon adsorption process (활성탄 흡착공정에 의한 과불화화합물의 제거 및 활성탄 자동재생 성능 평가)

  • Jung, Jinho;Lee, Sanghoon;Yun, Wonsang;Choi, Daehee;Jung, Jinyoung;Han, Ihnsup
    • Journal of Korean Society of Water and Wastewater
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    • v.36 no.2
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    • pp.121-134
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    • 2022
  • In this study, the removal efficiency of PFCs(perfluorinated compounds) in the GAC(granule activated carbon) process based on the superheated steam automatic regeneration system was investigated in laboratory scale and pilot-scale reactor. Among PFCs, PFHxS(perfluorohexyl sulfonate) was most effectively removed. The removal efficiency of PFCs was found to be closely related to the EBCT, and the removal efficiencies of PFOA(perfluorooctanoic acid), PFOS(perfluorooctyl sulfonate), and PFHxS were 43.7, 75, and 100%, respectively, under the condition of EBCT of 6 min. Afterward, PFOA, PFOS, and PFHxS exhibited the earlier breakthrough time in the order. After that, GAC was regenerated, and the removal efficiency of the PFCs before and after regeneration was compared. As a result, it was shown that the PFCs removal efficiency in the regenerated GAC process were higher, and that of PFOA was improved to 75%. The findings of this study indicate the feasibility of the superheated steam automatic regeneration system for the stable removal of the PFCs, and it was verified that this technology can be applied stably enough even in field conditions.