• Analytical Science and Technology
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• v.30 no.6
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• pp.319-328
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• 2017

The identification of explosive residues on specimens obtained from an explosion event is a crucial factor for assessing the cause of the explosion. In order to detect the components of explosives, the explosive residues deposited on surfaces are commonly extracted using swabbing materials pre-wetted with an organic solvent. The residues are then analyzed with analytical instruments such as LC/MS and CE/MS. Most conventionally used swabbing media such as cotton swabs or cotton tip swabs seem unsuitable for extracting explosive residues from the surface of a large area of clothes because the swabbing materials tend to be damaged easily, and because only a relatively small amount of explosives is collected. To overcome these problems, we have introduced a novel wiper ($215{\times}210mm$, single layer, Yuhan-Kimberly, Republic of Korea) as a swabbing material to recover representative organic explosives, namely, TNT, RDX, tetryl, HMX, PETN, and NG, from a large area of clothes. Different sides of the wiper, which was folded in half five times, was used to swab the surface of a clothing. We compared this novel wiper with a cotton swab and a cotton tip swab in terms of the recovery efficiency for the aforementioned organic explosives by pre-wetting with methanol, acetone, and acetonitrile, respectively. We identified that this novel wiper collected a significantly higher amount of organic explosive residues than a cotton swab or a cotton tip swab when using methanol as an extracting solvent.

• Tunnel and Underground Space
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• v.16 no.5 s.64
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• pp.413-421
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• 2006

In order to explain entirely dynamic fracture process induced by blasting in rock mass, it needs to consider detonation pressure and gas pressure acting on blasthole wall simultaneously. In this study, prior to simulating the coupling between gas flow and rock mass, we analyzed effects of gas pressure-time history, length of cracks and equation of state adopted to calculate the gas pressure on the gas flow within a radial fracture created by single-hole blasting. The effects were investigated on two assumptions: (a) the radial fracture was composed of 5 cracks which were 0.01 m in length and 0.001 m in asperity each and (b) the PETN explosive which diameter was 36 mm was charged in a blasthole of 45 mm diameter. It was concluded that the maximum gas pressure and its travel time were dependent on characteristics of charged explosives and geometrical properties of radial fracture.