• 한국염색가공학회지
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• 제2권4호
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• pp.251-256
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• 1990

Bis-(p-bromopheny)phosphate(BBPP) , which serves as flame retardant for PET fabric, was synthesized from phenol and phosphorus oxychloride, and from bromine. In order to investigate the flame retardancy of BBPP, PET fabrics were steam-cured with diluted BBPP solution. The following conclusions were drawn : 1. Flame retardancy of PET fabrics treated with BBPP was excellent, and optimal treating condition was 10% concentration of flame retardant at $170^{\circ]C$ 2. Clark softness and tensile strength before and after the laundering of PET fabrics treated with flame retardant remained nearly unchanged.

• 한국염색가공학회지
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• 제20권2호
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• pp.66-74
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• 2008

Effect of disperse dyeing on flame retardant finishing of PET fabrics via UV curing using three UV curable phosphorous-containing methacrylates and ammonium polyphosphate(APP) was investigated. The dye fixation and flame retardancy of PET fabrics did not change significantly with excellent durability to five laundering cycles irrespective of the dyeing and finishing sequence. However, the flame retardancy of Pekoflam-treated fabrics was lower than that of the UV treated and decreased substantially when heat treatment was carried out before the dyeing. The dyeability of the flame-retardant PET fabrics was not affected in the case of UV curing of the methacrylates alone. However, UV finishing after the dyeing caused significant decrease in K/S and ${\Delta}E$ due to changed refraction and inherent color of surface coating of the UV curable monomers and APP. Whereas the heat treatment with Pekoflam decreased both color fastness to laundering and sublimation, surprisingly the UV finish of PET fabrics before and after the dyeing increased the color fastness probably resulting from the presence of photopolymerized surface layer on the fabrics.

• 한국염색가공학회지
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• 제6권2호
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• pp.55-62
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• 1994

The mend for fabric products has been increased remarkably with increasing population, housings, mutistory buildings,...and etc. during the last two decades. However, since fabrics are highly combustible and can produce toxic gases during the combution, fabric products can result in serious human injury as well as financial damage. Acknowledged by this, a new phosphorus based flame retardant suitable for PET fabric has been synthesized by making use of the reaction of diphenyl chloro phosphate and hexamethylenediamine. Since the starting meterials are relatively cheap and the yield of this reaction is high (more than 90%), this reaction seems to be very effective as wall as very economic. By analyzing various spectrophotometric analysis data such as NMR, FT-IR, and Mass, this new flame retardant is identified to be N,N’-Bis(diphenyl chlorophosphoro)diamino hexane. In the mean time, DSC measurement has shown that the melting point and the boiling point of this material are around 115$^{\circ}C$ and around 40$0^{\circ}C$, respectively. The flame retardancy test done on the PET fabric processed by this flame retardant have shown excellent in times of flame contact, times of flame contact for washable. The most economical finishing condition estimated 10% in concentration of BDPDH, Moreover, it has been also found that the drape stiffness of the PET fiber processed by the flame retartant is changed very litter compared to the unprocessed original PET fabrics. Judging from this, the potential of this new phosphrdus based compond as a flame retardant for PET fabric seems to be high.

• 한국염색가공학회지
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• 제20권5호
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• pp.1-6
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• 2008

3-(Hydroxyphenyl phosphinyl) propanoic acid (HPPA) has been one of the most commonly used durable flame retardant agents for polyethylene terephthalate (PET) for many years. We intended to explore the application of HPPA to cellulose fabrics as formaldehyde-free phosphorus based flame retardants (FRs) through green chemistry process. The flame retardancy of the flame-retardant treated cellulose fabrics were characterized by using inductively coupled plasma spectroscopy (ICP) and limiting oxygen index (LOI). Structural changes of the treated cellulose fabrics were carried out by thermogravimetric analysis (TGA) and Fourier transform infrared (FT-IR) spectroscopy. To enhance the flame retardancy of HPPA treated cellulose fibers, glycerol polyglycidyl ether (GPE), a crosslinking agent was employed. Both HPPA and GPE treated cotton fabric imparted an LOI value over 26.

• 한국의류학회지
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• 제42권3호
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• pp.397-410
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• 2018

This study investigated the flame retardant, anti-static property and wear comfort of knitted fabrics made of two kinds of composite yarns comprised of modacryl, antistatic PET, cotton and excel(R) fibers. A Low Oxygen Index (LOI) above 28 was observed in the modacryl knitted fabric specimens. The flame retardant was superior at the excel(R) fiber (including modacryl knitted fabric) than the one including cotton fiber. Anti-static properties of the modacryl knitted fabrics imbedded by 3wt% of antistatic PET fibers were observed by rubbing with wool fabric attached to the measuring apparatus, which showed a better anti-static property than the excel(R) fiber (including modacryl knitted fabric). Wear comfort indicated that quick perspiration absorption and the fast dry property of excel(R) (including modacryl knitted fabric) was better than one that included cotton fiber. Warmth keepability and breathability of the knitted fabrics indicated good results in the excel(R) (including cotton and the modacryl knitted fabrics). However, the tactile hand property of cotton fiber (including modacryl knitted fabric) was better than excel(R) fiber due to high extensibility and compressibility, and low bending and shear rigidity of the cotton fiber (including modacryl knitted fabrics).

• 한국염색가공학회지
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• 제6권3호
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• pp.8-14
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• 1994

A new flame retardant diphenyl butylamidophosphate (DPBAP) for PET fabric was synthesized and its flame retardancy was examined. The results have shown that PET fabrics treated by DPBAP(with DPBAP and on 4-10 %) show excellent flame retardancy. Since the DPBAP treated PET fabric show essentially no change in the drape stiffness and the tensile strength, it is believed that DPBAP is chemically stable in PET fabric. In addition to this, the washing fastness of DPBAP on PET fabric tested by the 5 times of water washing method also appeared to be excellent. Judging from the fact that DPBAP was synthesized from relatively cheap material as well as the above cited DPBAP properties as a good flame retardant, the potential of DPBAP to be developed as a commercial flame retardant for PET fabric seems to be high.

• 한국의류산업학회지
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• 제6권5호
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• pp.667-672
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• 2004

Poly(ethylene terephthalate) (PET) fabrics were treated with a silica particle and phosphate flame retardant to determine the optimum process condition of the digital textile printing(DTP) media. The treating conditions for the study were 6 conditions, from F1 to F6, in which F3, F4 and F5 were treated with mixture of both silica particle and phosphate compound in process of pad, dry and cure fixation. F6 was treated with phosphate compound only and silica particle coating successively. Xanthan gum was used to control the migration of liquid phosphate compound onto PET fabrics. The change in surface morphology of fabrics treated with silica particle and phosphate compound was observed by SEM and flame retardance was evaluated by limiting oxygen index(LOI). It was observed that F6 was the excellent flame retardance and low bleeding in printing, Collectively, the printing characteristics of silica to cyan, magenta, yellow and black ink and flame retardance of fabrics finished with phosphate compound were identified in this study.

• 한국염색가공학회지
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• 제8권6호
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• pp.65-72
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• 1996

Polyester(PET) fabrics were treated by corona discharge equipment with the small amount of flame retardants to enhance flame retardancy. The surface properties of corona discharged fabrics were investigated using water penetration time, SEM, ESCA, and TGA. When corona discharge was applied to PET fabrics, the flame retardants were evenly distributed. As a result, the oxygen-containing functional groups were produced, and the LOI value increased. Thermogravimetric analysis indicated that the flame retardancy was operative by gas-phase mechanism.

• 한국염색가공학회지
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• 제9권2호
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• pp.1-9
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• 1997

This paper was carried out to introduce flame retardant and antibiotic properties to polyester(PET) and polyester/cotton(P/C) blend fabrics. PET and P/C blend fabrics were treated by a paddry-cure method in the aqueous solutions of the finishing agents(JA 6034, JA 6050, DC-5700). The corona discharge technique was applied to increase the polar group of the polymer surface. The characteristics of the treated fabric were investigated by means of scanning electron microscope (SEM) and electron spectroscopy for chemical analysis(ESCA), and water penetration time, limiting Oxygen index(LOI), and K/S value were also measured. Wettability of the fabrics was increased considerably with the corona discharge treatment. ESCA was used to elucidate the surface chemical composition of the fabrics treated with the corona discharge. Relative Ols intensity increased and oxygen was incorporated in the form of -C-O-, -C=O, and O=C-O on the polymer surface. The current study indicated that corona discharge treatment was effective for modifying the polymer surface.