• 제목/요약/키워드: PET Dyeing

검색결과 191건 처리시간 0.025초

저온 플라즈마를 이용한 호발 및 염색 선행연구 (Preliminary Study on Desizing and Dyeing Using Low Temperature Plasma)

  • 배백현;조훈제;김효진;이연희;박성민;김정규;정진호
    • 대한환경공학회지
    • /
    • 제27권9호
    • /
    • pp.946-951
    • /
    • 2005
  • 본 연구에서는 청정 호발공정의 하나로 플라즈마 처리를 사용하였다. 폴리에스테르(polyethylene terephthalate, PET) 직물에 가호된 폴리비닐 알콜(polyvinyl alcohol, PVA), 아크릴 호제(polyacrylic acid esters, PACL)과 이들의 혼합된 호제들을 질소($N_2$)와 산소($O_2$) 플라즈마로 처리하였다. 호제제거에 있어서 산소 플라즈마가 질소 플라즈마 보다 더 효과적이었으며, PACL 보다는 PVA 호제 제거가 더 우수하였다. 플라즈마 처리된 시료의 주사전자현미경(scanning emission microscopy, SEM) 사진을 통하여 호제들이 제거되었음을 직접 확인할 수 있었다. 산소 플라즈마 처리 후, 기존의 습식공정을 이용하여 폴리에스테르 직물을 호발하였다. 플라즈마로 처리하지 않은 직물과 비교하여 산소 플라즈마 처리된 직물의 호발폐수는 더 낮은 TOC, COD와 $BOD_5$ 값을 보여주었다. 이것은 플라즈마 처리가 직접적으로 호제를 제거할 수 있을 수 뿐 아니라 호제의 화학적 특성을 변화시킴으로서 이점을 제공할 수 있다는 것을 보여준다. 마지막으로, 플라즈마 처리에 의한 호발 공정이 폴리에스테르 직물의 염색성에 미치는 영향을 색차와 염색견뢰도를 측정하여 살펴보았다. CCM(computer color matching) 측색 실험 결과, 산소 플라즈마로 20분간 처리한 폴리에스테르 직물과 기존 습식공정으로 호제가 제거된 기준직물과의 색차값은 1 정도이었다. 이것은 다른 부수적인 공정 없이 플라즈마로 처리된 직물이 바로 염색공정에 사용될 수 있다는 것을 나타낸다. 또한, 플라즈마로 처리된 직물은 좋은 염색견뢰도 결과를 보여주었는데, 세탁견뢰도, 마찰견뢰도, 승화견뢰도, 일광견뢰도도 기준직물과 비교하여 같거나 더 우수하였다.

디아미노피리딘아조계 Red 분산염료들의 합성과 염색성 (Synthesis and Dyeing Properties of Red Disperse Dyes Derived from Diaminopyridines)

  • 박종호;고준석;배진석;김성동
    • 한국염색가공학회지
    • /
    • 제17권6호
    • /
    • pp.1-10
    • /
    • 2005
  • Disperse dyes derived from heterocyclic compounds such as phenylindole, pyridone, diaminopyridine, and carbazole have been known to exhibit high light fastness and bathochromic shift compared to the coursponding aminoazobenzene. The synthetic method to obtain diaminopyridine derivatives, which can be used as coupling components, was chlorination of pyridone with phosphorous oxychloride, followed by substitution with various primary amines. Four azo disperse dyes were synthesized by coupling four diaminopyridines with 2-cyano-4-nitroaniline as a diazo component. Structures of these dyes were confirmed by $^1H$ NMR spectroscopy. The wavelengths of maximum absorption of the synthesized disperse dyes were in the range of $517\~528nm$, and molar extinction coefficients were $45,700\~50,100$. The dyeability of four disperse dyes toward PET fiber was generally good. Wash and rubbing fastnesses were excellent, while light and dry heat fastness were good.

직기 특성이 PET직물 물성에 미치는 영향(II) (Effects of Weaving Machine Characteristics on the Physical Properties of PET Fabrics (II))

  • 김승진;손준혁;강지만;박명환
    • 한국염색가공학회지
    • /
    • 제16권4호
    • /
    • pp.36-44
    • /
    • 2004
  • This research surveys the differences of fabric mechanical properties according to the different looms and the fabric positions with relation to warp and weft weaving tensions on the Picanol and Omega looms respectively. For this purpose, the grey fabrics woven in the previous paper are processed in dyeing and finishing processes, and the processing shrinkages are measured on each processes such as dryer, scouring, pre-set, dyeing and final-set using the fabric density and width. The mechanical properties of the finished fabrics are measured and discussed with relation to the warp and weft weaving tensions of the two looms and the variations of the fabric mechanical properties according to the fabric positions are also discussed. In addition, the fabric thickness according to the fabric positions such as right, left selvedges and center of the fabrics is also measured and discussed with the characteristics of the Picanol and Omega looms.

용제염색에 관한 기초적 연구 제일보 물, TCE 및 물/TCE 처리에 의한 PET 기질의 변화 (A Foundamental Study on the Solvent Dyeing Part 1. Change of PET Substrate Treated with Water, TCE and Water/TCE Emulsion.)

  • 정두진
    • 한국의류학회지
    • /
    • 제2권2호
    • /
    • pp.245-252
    • /
    • 1978
  • In order to obtain some information for solvent dyeing, polyethylene terephthalate (PET) was treated with water, tetrachloroethylene yarn (TCE), and water/TCE emulsion for three hours at the temperatures from $40^{\circ}$ to $140^{\circ}C$. The change of fine structure of substratum by measuring the shrinkage, the degree of crystallinity, the stress relacxation modulus and Young's modulus. The P.E.T. film was also treated in water (at $140^{\circ}C$) for 4 hours to stabilize the substratum. By means of film roll cyliderical method, the Disperse Blue 27 was diffused. Then, calculated the diffusion coefficient and examined the application of WLF equation. However, the temperature dependence of the shrinkage could be explain with WLF equation, the diffusion coefficient couldn't be applied the WLF equation when the substratum was stabilized. From the result, the effects on shrinkage were in the order of water

  • PDF

제직 준비 공정특성이 PET 직물 감성에 미치는 영향 (Effect of the Weaving Preparatory Process Characteristics on the PET FabricsSensibility)

  • 김승진
    • 감성과학
    • /
    • 제11권1호
    • /
    • pp.123-129
    • /
    • 2008
  • 본 연구에서는 PET 직물의 물성개선과 품질의 향상을 위해 직물 제조 공정 중 제직준비공정인 ITY, P/W, 2-for-1공정에서 여러 가지 공정인자의 변화를 주어 염색 가공 공정을 거친 최종 11가지 직물의 역학적 특성치 및 각 공정별 시료의 물성을 측정하여 직물의 감성특성인 Handle, 의복성능 및 봉제성을 평가하여 직물 제조 공정특성이 직물 감성에 미치는 영향에 대해 분석하였다.

  • PDF

잠재권축사를 적용한 기모편성물의 염색 및 물성변화에 대한 연구 (A Study on the Dyeing and Physical Properties of Napping Knit Fabric using Latent Crimped Yarn)

  • 이범훈
    • 한국염색가공학회지
    • /
    • 제33권4호
    • /
    • pp.182-190
    • /
    • 2021
  • The purpose of this study is to provide the dyeing and physical characteristics of napped knit fabrics composed of latent crimped yarn. The K/S values, dyeing fastness, thickness, bulkiness, and shrinkage characteristics of three knit fabrics were investigated. The original knit fabric (SK) was composed of 1ply latent crimped yarn (75/36) in the ground and PET DTY (70/100) in the pile loop, in order of napped process the napped knit fabric (SN) was napped SK fabric. In order to compare of latent crimped yarn content, the last knit fabric (DN) was napped 2ply latent crimped yarn were included in the same structure of SK. Dyeability of three knit fabrics was similar but the shrinkage properties of DN fabric were significant different. The bulkiness shows a tendency to increase the bulkiness as increasing the dyeing temperature, and the bulkiness of the SN was higher because of the napping process and optimal content of latent crimped yarn.

폴리에스테르 섬유의 분산염색에 있어서 캐리어의 작용기구 (The Carrier Mechanism in the Disperse Dyeing of Poly(ethylene terephthalate))

  • 이일건;윤남식;임용진
    • 한국염색가공학회지
    • /
    • 제2권4호
    • /
    • pp.231-236
    • /
    • 1990
  • The diffusion coefficient of C.I. Disperse Red 4 in the dyeing of carrier-pretreated poly (ethylene terephthalate) film was Investigated by Sekido's film-rolled method. From the result it was shown that the diffusion coefficient increases exponentially with the content-ration of carrier in the film, and, for the films containing same concentration of carrier, the carrier effect was enhanced with the molar volume of the carriers. The greater carrier effect was accompanied by the decrease in diffusion activation energy and entropy, which shows that the carrier with larger molar volume plasticizes PET film to more extent.

  • PDF

고강력 직물의 열융착 라미네이팅을 통한 충격 완화용 에어쿠션 소재로의 적용 가능성 검토 연구 (Study on the Applicability of the Air Cushion Material for Impact Relief through Thermal Bonding of High Strength Fabrics)

  • 김지연;김훈민;민문홍
    • 한국염색가공학회지
    • /
    • 제32권3호
    • /
    • pp.176-183
    • /
    • 2020
  • In order to study wearable air cushion materials capable of responding to massive impact in high-altitude fall situation, high tenacity woven fabrics were bonded by heat only depending on various type of thermoplastic films and then mechanical properties were measured. Tensile strength, elongation, and 100% modulus measurement results for 4 types of films show that TPU-2 has higher impact resistance and easier expansion than PET-1. After thermal bonding, the combination with the highest tensile strength was a material with a TPU-2 film for nylon and a PET-2 film for PET, so there was a difference by type of fabric. The tear strength of the bonded materials were increased compared to the fabric alone, which shows that durability against damage such as tearing can be obtained through film adhesion. All of the peel strengths exceeded the values required by automobile airbags by about 5 times, and the TPU-2 bonded fabric showed the highest value. The air permeability was 0 L/dm2 /min. For both the film and the bonded material, which means tightness between the fabric and the film through thermal bonding. It is expected to be applied as a wearable air cushion material by achieving a level of mechanical properties similar to or superior to that of automobile airbags through the method of bonding film and fabric by thermal bonding.