• 멤브레인
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• 제32권5호
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• pp.292-303
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• 2022

이산화탄소 배출이 없는 고분자 전해질 막 연료전지(polymer electrolyte membrane fuel cell, PEMFC)는 수송용, 발전용 시스템에 적용 가능한 친환경 에너지 변환장치이다. PEMFC의 주요 구성품 중 하나인 고분자 전해질 막(polymer electrolyte membrane, PEM)은 구동시간 동안의 높은 수소 이온 전도도와 물리화학적 안정성 갖춘 과불소화계 고분자(perfluorinated sulfonic acid, PFSA) 기반 PEM (PFSA-PEM)이 상용화 되어있다. 하지만 PFSA-PEM의 단점으로 지적되는 낮은 유리전이온도와 높은 기체 투과도의 보완이 요구되고 있다. 이에 본 총설에서는 PFSA-PEM의 성능 향상 및 단점 보완을 위해 1) PFSA의 측쇄부 길이를 조절함으로써 이온교환용량의 증가와 고분자의 결정성을 증가시켜 PFSA-PEM의 능력을 향상시킨 연구와 2) 유/무기 첨가제를 도입하여 수소 이온 전도도 및 물리적 안정성을 향상시키는 복합 막 연구 및 3) 다공성 지지체를 도입하여 PEM의 두께를 효과적으로 감소시켜 막 저항을 효과적으로 줄이고 내구성을 큰 폭으로 개선한 다공-충진막에 관한 연구를 소개하고자 한다.

• International Journal of Automotive Technology
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• 제1권1호
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• pp.9-16
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• 2000

The growing concerns on environmental protection have been constantly demanding cleaner and more energy efficient vehicles without compromising any conveniences provided by the conventional vehicles. The recent significant advances in proton-exchange-membrane (PEM) fuel cell technology have shown the possibility of developing such vehicles powered by fuel cells. Several prototype fuel cell electric vehicles (FCEV) have been already developed by several major automotive manufactures, and all of the favorable features have been demonstrated in the public roads. FCEV is essentially a zero emission vehicle and allows to overcome the range limitation of the current battery electric vehicles. Being motivated by the laboratory and field demonstrations of the fuel cell technologies, variety of fuel cell alliances between fuel cell developers, automotive manufactures, petroleum companies and government agencies have been formed to expedite the realization of commercially viable FCEV. However, there still remain major issues that need to be overcome before it can be fully accepted by consumers. This paper describes the current fuel cell vehicle development status and the staggering challenges for the successful introduction of consumer acceptable FCEVS.

• Advances in Energy Research
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• 제8권4호
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• pp.203-211
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• 2022

The aim of this paper is to analyze the performance of commercial fuel cell (rated capacity 1000W) with the help of resistive load and output power variation with change in H₂ flow rate and calculate the maximum power point (MPP) of the proton exchange membrane (PEM) while changing AC and DC load respectively. The factors influencing the output power of a fuel cell are hydrogen flow rate, cell temperature, and membrane water content. The results show that when the H₂ flow rate is changed from 11, 13, and 15 Lpm, MPP is increased from lower to higher flow rate. The power of the fuel cell is increased at the rate of 29% by increasing the flow rate from 11 to 15 lpm. This study will allow small-scale industries and residential buildings (in remote or inaccessible areas) to characterize the performance of PEMFC. Furthermore, fuel cell helps in reducing emission in the environment compared to fossil fuels. Also, fuel cells are ecofriendly as well as cost effective and can be the best alternative way to convert energy.

• 신재생에너지
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• 제1권4호
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• pp.43-48
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• 2005

This study presents the integrated modeling approach to simulate the proton exchange membrane [PEM] fuel cell system for vehicle application. The fuel cell system consisting of stack and balance of plant (BOP) was simulated with MATLAB/Simulink environment to estimate the maximum system power and investigate the effect of BOP component sizing on system performance and efficiency. The PEM fuel cell stack model was established by using a semi-empirical modeling. To maximize the net efficiency of fuel cell system, multi-variable optimization code was adopted. Using this method, the optimized operating values were obtained according to various system net power levels. The fuel cell model established was co-linked to AVL CRUISE, a vehicle simulation package. Through the vehicle simulation software, the fuel economy of fuel cell powered electric vehicle for two types of driving cycles was presented and compared. It is expected that this study can be effectively employed in the basic BOP component sizing and in establishing system operation map with respect to net power level of fuel cell system.

• 항공우주산업기술동향
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• 제7권2호
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• pp.95-105
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• 2009

연료전지는 소음이 낮고$CO_2$ 배출이 없는 친환경적 특성을 기반으로 항공기 추진시스템에 적용되고 있으며, 현재 연료전지를 탑재한 여러 종류의 무인항공기와 소형 유인항공기 개발이 진행되고 있다. 항공기용 연료전지는 대표적으로 PEMFC(Proton Exchange Membrane Fuel Cell)방식과 SOFC(Solid Oxide Fuel Cell) 방식으로 분류되며, 항공기의 임무 및 운용조건에 적합한 연료전지 시스템이 개발되고 있다. 무인항공기의 경우 대부분 PEM 연료전지 기술을 기반으로 군용 또는 상용으로 활용할 수 있는 다양한 형태와 크기의 항공기가 개발되고 있으며, 시스템의 안정성과 운용시간이 더욱 향상될 것이다. 소형 유인항공기에서는 추진시스템을 연료전지로 대체하기 위한 많은 연구가 수행되고 있으며, 또한 대형 상용 항공기의 보조동력장치(APU)에 연료전지를 적용하여 성능을 높이기 위한 개발이 진행되고 있다. 향후, 연료전지항공기는 연료전지의 전력밀도 증가와 더불어 신뢰성과 효율을 더욱 향상시킬 것으로 기대된다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2005년도 제17회 워크샵 및 추계학술대회
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• pp.541-544
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• 2005

This study presents the integrated modeling approach to simulate the proton exchange membrane (PEM) fuel cell system for vehicle application. The fuel cell system consisting of stack and balance of plant (BOP) was simulated with MATLAB/Simulink environment to estimate the maximum system power and investigate the effect of BOP component sizing on system performance and efficiency. The PEM fuel cell stack model was established by using a semi-empirical modeling. To maximize the net efficiency of fuel cel1 system, multi-variable optimization code was adopted. Using this method the optimized operating values were obtained according to various system net power levels. The fuel cell model established was co-linked to AVL CRUISE, a vehicle simulation package. Through the vehicle simulation software, the fuel economy of fuel cell powered electric vehicle for two types of driving cycles was presented and compared. It is expected that this study tan be effectively employed in the basic BOP component sizing and in establishing system operation map with respect to net power level of fuel cell system.

• 전기학회논문지
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• 제58권8호
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• pp.1551-1558
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• 2009

This paper proposes a new power conditioning system for the fuel cell power generation, which consists of a LLC resonant DC-DC converter and 3-phase inverter. The LLC resonant converter boosts the fuel cell voltage of 26-48V up to 400V, using the hard-switching boost converter and the high-frequency ZVS half-bridge converter. The operation of proposed power conditioning system was verified through simulations with PSCAD/EMTDC software. The feasibility of hardware implementation was verified through experimental works with a laboratory prototype, which was built with 1.2kW PEM fuel-cell stack, 1kW LLC resonant converter, and 3kW PWM inverter. The proposed system can be utilized to commercialize a real interconnection system for the fuel-cell power generation.

• 전기학회논문지
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• 제58권9호
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• pp.1728-1734
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• 2009

This paper proposes a new power conditioning system for the fuel cell power generation, which consists of a ZVS DC-DC converter and 3-phase inverter. The ZVS DC-DC converter with a digital controller boosts the fuel cell voltage of 26-50V up to 400V, and the grid-tie inverter controls the active power delivered to the grid. The operation of proposed power conditioning system was verified through simulations with PSCAD/EMTDC software. The feasibility of hardware implementation was verified through experimental works with a laboratory prototype, which was built with 1.2kW PEM fuel-cell stack, 1kW DC-DC converter, and 3kW PWM inverter. The proposed system can be utilized to commercialize an interconnection system for the fuel-cell power generation.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2005년도 춘계학술대회
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• pp.326-329
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• 2005

Proton exchange membrane (PEM) should be sufficiently hydrated with proper water management to maintain a good ionic conductivity and performance of a PEM fuel cell. However. cathode flooding resulting from excess water can impede the transport of reactants and hence deteriorate the fuel cell performance. For the PEM fuel cell to be commercially viable as vehicle or portable applications, the flooding on the cathode side should be minimized during the fuel cell operation. In this study, visualization technique was applied to understand the cathode flooding phenomena on the cathode side of a PEM fuel cell. To this end. a transparent PEM unit fuel cell wi th an act ive area of $25cm^2$ was designed and manufactured to allow for the visualization of cathode channel with performance characteristics. Two-phase flow resulting from the electro-chemical reaction of fuel cell was investigated experimentally. The images photographed by CCD camera with cell operating temperatures $(30\~50^{\circ}C)$ were presented. Results indicated that the flooding on the cathode side first occurs near the exit of cathode channel. As the operating temperature of fuel cell increases. it was found that liquid water droplets tend to evaporate easily and it can have an influence on lowering the flooding level. It is expected that this study can effectively contribute to the detailed researches on modeling water transport of an operating PEM fuel cell including two-phase flow phenomena.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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• pp.274-277
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• 2009

본 논문에서는 소형 PEM(Proton Exchange Membrane) 연료전지 스택의 BOS(Balance of Stack) 제어에 관하여 논의한다. 별도의 가습 장치가 필요치 않고 BOS의 구성이 비교적 간단한 소형 PEM 연료전지 시스템에서는 팬과 퍼지밸브만의 제어를 통해 스택 내부 수분의 조절과 열 관리가 수행된다. 따라서 본 논문에서는 부하에 따른 최적의 공기유량을 계산하고 요구되는 유량의 공급을 위해 팬을 제어하는 알고리즘을 통해 소형 연료전지 시스템의 과도응답 특성과 안정성을 향상시키는 방법에 관하여 제안한다. 150W급 소형 연료전지 시스템을 꾸미고, 마이크로컨트롤러를 이용한 제어회로를 구현하여 실험함으로써 제안된 알고리즘의 유용함을 검증하였다.