• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 추계학술대회
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• pp.105-108
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• 2006

The fuel cell is one of the promising environment-friendly energy sources for the next generation. The fuel cell provides good energy efficiency above 40% without pollution or noise. Different fuel cell types are usually distinguished by the kind of electrolyte. Among these, the proton exchange membrane fuel cell (PEMFC) has advantages of high power density. low operating temperature, relatively quick start-up, and rapid response to varying loads. The bipolar plate is a major component of the PEM fuel cell stack, and it takes a large portion of stack volume, weight and cost. In this study, as alternative materials for bipolar plate of PEM fuel cells, graphite composites were fabricated by compression molding and by machining. Graphite particles mixed with epoxy resin were used as the main substance to provide electric conductivity. Flow channels were fabricated by compression molding with design of experiments (DOE) to evaluate moldability. The cost for compression molding of graphite-composite bipolar plate was compared with machining cost to make the same bipolar plate.

• 대한기계학회논문집B
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• 제30권5호
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• pp.489-495
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• 2006

Proton exchange membrane (PEM) should be sufficiently hydrated with a careful consideration of heat and water management. Water management has been a critical operation issue for better understanding the operation and optimizing the performance of a PEM fuel cell. The flooding on cathode side resulting from excess water can limit the fuel cell performance. In this study, the visual cell was designed and fabricated fur the visualization of liquid water droplet dynamics related to cathode flooding in flow channels. The experiment was carried out to observe the formation, growth and removal of water droplets using CCD imaging system. Effects of operating conditions such as cell temperature, air flow rate and air relative humidity on cathode flooding characteristics were mainly investigated. Based on this study, we can get the basic insight into flooding phenomena and its two-phase flow nature. It is expected that data obtained can be effectively used fur the setup and validation of two-phase PEM fuel cell models considering cathode flooding.

• Carbon letters
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• 제11권4호
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• pp.336-342
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• 2010

Different oxidation treatments on CNTs using diluted 4.0 M $H_2SO_4$ solution at room temperature and or at $90^{\circ}C$ reflux conditions were investigated to elucidate the physical and chemical changes occurring on the treated CNTs, which might have significant effects on their performance as catalyst supports in PEM fuel cells. Raman spectroscopy, X-ray diffraction and transmission electron microscope analyses were made for the acid treated CNTs to determine the particle size and distribution of the CNT-supported Pt-Ru nanoparticles. These CNT-supported Pt-based nanoparticles were then employed as anode catalysts in PEMFC to investigate their catalytic activity and single-cell performance towards $H_2$ oxidation. Based on PEMFC performance results, refluxed Pt-Ru/CNT catalysts prepared using CNTs treated at $90^{\circ}C$ for 0.5 h as anode have shown better catalytic activity and PEMFC polarization performance than those of the commercially available Pt-Ru/C catalyst from ETEK and other Pt-Ru/CNT catalysts developed using raw CNT, thus demonstrating the importance of acid treatment in improving and optimizing the surface properties of catalyst support.

• 항공우주산업기술동향
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• 제7권2호
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• pp.95-105
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• 2009

연료전지는 소음이 낮고$CO_2$ 배출이 없는 친환경적 특성을 기반으로 항공기 추진시스템에 적용되고 있으며, 현재 연료전지를 탑재한 여러 종류의 무인항공기와 소형 유인항공기 개발이 진행되고 있다. 항공기용 연료전지는 대표적으로 PEMFC(Proton Exchange Membrane Fuel Cell)방식과 SOFC(Solid Oxide Fuel Cell) 방식으로 분류되며, 항공기의 임무 및 운용조건에 적합한 연료전지 시스템이 개발되고 있다. 무인항공기의 경우 대부분 PEM 연료전지 기술을 기반으로 군용 또는 상용으로 활용할 수 있는 다양한 형태와 크기의 항공기가 개발되고 있으며, 시스템의 안정성과 운용시간이 더욱 향상될 것이다. 소형 유인항공기에서는 추진시스템을 연료전지로 대체하기 위한 많은 연구가 수행되고 있으며, 또한 대형 상용 항공기의 보조동력장치(APU)에 연료전지를 적용하여 성능을 높이기 위한 개발이 진행되고 있다. 향후, 연료전지항공기는 연료전지의 전력밀도 증가와 더불어 신뢰성과 효율을 더욱 향상시킬 것으로 기대된다.

• Journal of Electrochemical Science and Technology
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• 제15권3호
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• pp.388-404
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• 2024

In the present work, the operating parameters were optimized using Box Behnken Design (BBD) in response surface methodology (RSM) to maximize the hydrogen production rate (R₁) and hydrogen production rate per unit watt consumed (R₂) of a proton exchange membrane electrolysis cell (PEMEC), a third response (R₃) which was the sum of the scaled values of R₁ and R₂ were selected to be maximized so that both hydrogen production rate and hydrogen production rate per unit watt consumed could be maximized. The major parameters which were influencing the experiment for enhancing the output responses were oxygen electrode/anode electrocatalyst loading (A), current supplied (B) and water inlet temperature (C). The commercial proton exchange membrane Nafion^® was used as the electrolyte. The acetylene black carbon (C_AB) supported IrO₂ was used as the electrocatalyst for preparing oxygen electrode/anode whereas commercial Pt (40 wt%)/C_HSA was used as the H₂ electrode/cathode electrocatalyst. The quadratic model was developed to predict the output/ responses and their proximity to the experimental output values. The developed model was found to be significant as the P values for both the responses were < 0.0001 and F values were greater than 1. The optimum condition for both the responses were O₂ electrode/anode electrocatalyst loading of 1.78 mg/cm², supplied current of 0.33 A and water inlet temperature of 54℃. The predicted values for hydrogen production rate (R₁) and hydrogen production rate per unit watt consumed (R₂) were 2.921 mL/min and 2.562 mL/(min·W), respectively obtained from the quadratic model. The error % between the predicted response values and experimental values were 1.47% and 3.08% for R₁ and R₂, respectively. This model predicted the optimum conditions reasonably in good agreement with the experimental conditions for the enhancement of the output responses of the developed PEM based electrolyser.

• 한국수소및신에너지학회논문집
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• 제27권4호
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• pp.341-348
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• 2016

The experiments related on structure and water electrolysis performance of HALE UAV stack were conducted in this study. Anode catalyst $IrRuO_2$ was prepared by Adam's fusion methods as 2~3 nm nano sized particles, and the cathode catalyst was used as commercial product of Premetek. The MEA (membrane electrode assembly) was manufactured by decal methods, anode and anode catalytic layers were prepared by electro-spray. HALE stack was composed of 5 multi-cells as $0.2Nm^3/hr$ hydrogen production rate with hydrogen pressure as 10 bar. The water electrolysis performance was investigated at atmospheric pressure and temperature of $55^{\circ}C$. Best performance of HALE UAV stack was recorded as cell voltage efficiency as 86%.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2005년도 제17회 워크샵 및 추계학술대회
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• pp.541-544
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• 2005

This study presents the integrated modeling approach to simulate the proton exchange membrane (PEM) fuel cell system for vehicle application. The fuel cell system consisting of stack and balance of plant (BOP) was simulated with MATLAB/Simulink environment to estimate the maximum system power and investigate the effect of BOP component sizing on system performance and efficiency. The PEM fuel cell stack model was established by using a semi-empirical modeling. To maximize the net efficiency of fuel cel1 system, multi-variable optimization code was adopted. Using this method the optimized operating values were obtained according to various system net power levels. The fuel cell model established was co-linked to AVL CRUISE, a vehicle simulation package. Through the vehicle simulation software, the fuel economy of fuel cell powered electric vehicle for two types of driving cycles was presented and compared. It is expected that this study tan be effectively employed in the basic BOP component sizing and in establishing system operation map with respect to net power level of fuel cell system.

• 신재생에너지
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• 제1권4호
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• pp.43-48
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• 2005

This study presents the integrated modeling approach to simulate the proton exchange membrane [PEM] fuel cell system for vehicle application. The fuel cell system consisting of stack and balance of plant (BOP) was simulated with MATLAB/Simulink environment to estimate the maximum system power and investigate the effect of BOP component sizing on system performance and efficiency. The PEM fuel cell stack model was established by using a semi-empirical modeling. To maximize the net efficiency of fuel cell system, multi-variable optimization code was adopted. Using this method, the optimized operating values were obtained according to various system net power levels. The fuel cell model established was co-linked to AVL CRUISE, a vehicle simulation package. Through the vehicle simulation software, the fuel economy of fuel cell powered electric vehicle for two types of driving cycles was presented and compared. It is expected that this study can be effectively employed in the basic BOP component sizing and in establishing system operation map with respect to net power level of fuel cell system.

• 신재생에너지
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• 제3권2호
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• pp.24-30
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• 2007

The transient response of PEMFC (proton exchange membrane fuel cell) is important criteria in the application of PEM fuel cell to real automotive system. In this work, using a transparent unit PEM fuel cell, the transient response and cathode flooding during load change are investigated. The cell voltage is acquired according to the current density change($0.3Acm^2$ to $0.6A/cm^2$) under various stoichiometry conditions and different flooding intensities, Also the cathode gas channel images are obtained by CCD imaging system simultaneously. The different level of undershoots appeared at the moment of load changes under different cathode stoichiometries and flooding intensities. It takes about 1s that the product water comes up onto the flow channel so that oxygen supply is temporarily blocked which causes voltage loss in that "undershoot". The correlation of the dynamic behavior with stoichiometry and cathode flooding is induced from the results of these experiments.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2005년도 춘계학술대회 논문집 전기기기 및 에너지변환시스템부문
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• pp.277-279
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• 2005

The imbalance of energy demand and supply caused by rapid industrialization around the world and the associated environmental issues require and alternative energy source with possible renewable fuels. Political instability and depletion of cruel oils are other factors that cause fluctuation of oil price. Securing a new alternative energy source for the next century became an urgent issue that our nation is confronting with. As a matter of fact, the fuel cell technology can be widely used as next generation energy regardless of regions and climate. Specially, the ability of expansion and quick installation enable one to apply it for distributed power, where the technology is already gaining remarkable attentions for the application. Particularly, leading industrialized nations are focusing on the PEM fuel dell with anticipation that this technology will find their place of applications in the vehicles and homes. In this study, demonstrate the multi physics modeling of a proton exchange membrane(PEM) fuel cell with interdigitated flow field design. The model uses current balances, mass balance(Maxwell-Stefan diffusion for reactant, water and nitrogen gas) and momentum balance(gas flow) to simulate the PEM fuel cell behavior.