• Title/Summary/Keyword: PC5

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Solvent Extraction of Nd from Chloride Solution with PC88A (염산용액에서 PC88A에 의한 Nd의 용매추출)

  • Lee Gwang-Seop;Lee Jin-Young;Kim Sung-Don;Kim Joon-Soo;Lee Man-Seung
    • Resources Recycling
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    • v.13 no.4
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    • pp.39-45
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    • 2004
  • Solvent extraction experiments of Nd from chloride solution were studied with PC88A. Solvent extraction reaction of Nd with PC88A and the equilibrium constant were evaluated from the extraction experimental data and extraction conditions. Nd$aq^{3+}$ + 1.5 $H_2$$A_2$,org = $NdA_3$,org + 3H/sun $aq^{+}$ , K=0.25 The predicted distribution coefficients of Nd agreed well with the experimental results. The effect of saponification of PC88A on the extraction of Nd and on the change of equilibrium pH was investigated. Saponified PC88A present as a monomer in the organic reaction and enhanced the distribution coefficient of Nd. The initial extraction conditions had a great effect on the equilibrium pH.

Study of Polycarbonate/MWNT Electrospun Nanofiber and Its Multi-Filament Application (전기방사에 의한 카본나노튜브/폴리카보네이트 나노섬유와 복합필라멘트 특성에 관한 연구)

  • Choi, Jae-Won;Lee, Kwang-Hoon;Hwang, Seok-Ho;Kim, Jeong-Yeol;Lee, Sang-Won;Huh, Wansoo
    • Applied Chemistry for Engineering
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    • v.19 no.4
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    • pp.413-420
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    • 2008
  • Over the past decade, there have been significant advancement in the field of electrospinning area. This study has focused on preparing yarn using polycarbonate (PC) nanofibers including modified multi-walled carbon nanotube (mMWNT) by solution electrospinning process using the mixture of solvents consisting of tretrahydronfuran (THF) and N,N-dimethylformamide (DMF). In order to enhance the dispersion, MWNT was chemically modified. TEM analysis for the prepared PC/mMWNT nanofibers reveals that mMWNT was well-dispersed into the PC nanofiber matrix. Also with increasing contents of mMWNT, thermal stability of PC/mMWNT nanofibers was improved than that of PC nanofibers. Moreover when 3 to 5 wt% of mMWNT was added, the nanofibers showed good electrical properties expecting antistatic effect, ranging 109.1~109.5 ${\Omega}$. It was confirmed that the multi-filament fibers using PC/mMWNT had $60{\sim}100{\mu}m$ in diameter and 4~5 cm in length.

A Study on the Characteristics of PC Use Space and Users' Consciousness at Residences (주거 내 PC 사용공간의 특성 및 사용자 의식에 관한 조사연구)

  • Jeong, Byeol-Ah;Kim, Bong-Ae
    • Journal of the Korean housing association
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    • v.17 no.5
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    • pp.55-65
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    • 2006
  • The objective of this study is to provide new direction on house design in consideration of the PC users' life pattern. This study found that PC use present conditions at home, demand for PC using space, and requirements for PC using area were analyzed. A survey was taken by 1108 residences, and the SPSS win.10 was applied for analysis. The survey was conducted to see the computer usage at home, demand and satisfaction for the PC using space. The results of this study were as follows; forty-seven percent of respondents said they used the PC in son's and daughter's room while 36.8% answered living room. It reflects that the whole family want to use the PC in the same area, or for their children's convenience. Users' consciousness was analyzed four factor, which were 'physical inconvenience:'satisfactions in PC position', 'inconvenience caused by narrowness', 'notion of privacy'. PC users' consciousness had significant differences in the satisfaction by PC users' characteristic and housing characteristic. It was to be classified that the PC use space into several pattern according to furniture arrangement, and channel pattern had the highest satisfaction among those pattern. Through this study, it is expected that new housing designs need to be made to reflect lese requirements into interior design and house plan for PC user's needs.

Frbrication and characteristics of NO$_{2}$ Gas sensor using the phthalocyanines (프탈로시아닌을 이용한 NO$_{2}$ 가스센서의 제작 및 특성)

  • 전춘배;박효덕;이덕동
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.32A no.7
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    • pp.85-93
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    • 1995
  • In this study, phthalocyanine thin films were prepared by vacuum sublimation method and investigated sensing characteristics of the films. The phthalocyannies used for the prepaation of the NO$_{x}$ sensors were metal-free Pc(H$_{2}$Pc) and metal Pc(CuPc, CoPc, PbPc). And the substrate temperatures maintained during the fomation of Pc films were varied between R.T. and 200$^{\circ]C$, and the base pressure was 5${\times}10^{6}$ torr. The relationships between NO$_{2}$ sensing properties and SEM analyses as a function of substrate temperatures during the formation of the films were investigated. Among the Pc films, PbPc film showed the best sensing characteristics. Particularlly, the PbPc films prepared at 70$^{\circ]C$ of the substrage temperature showen good sensitivity of 85% to 1ppm NO$_{2}$ gas at operating temperature 190$^{\circ]C$ and response time was about 24 seconds.

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Inhibitory Effects of the Stem Bark of Albizia julibrissin on Catecholamine Biosynthesis in PC12 Cells

  • Lee, Myung-Koo
    • Korean Journal of Pharmacognosy
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    • v.27 no.2
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    • pp.155-158
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    • 1996
  • The methanol extract of Albizzia julibrissin Durazz. (Leguminosae) was successively partitioned into dichloromethane, ethylacetate, butanol (BuOH) and water fractions, and the effects of the each solvent extract on catecholamine biosynthesis in PC12 cells were investigated. Among them, the BuOH fraction $(5{\mu}g/ml\;medium)$ showed 68.8% and 63.6% inhibition on dopamine and norepinephrine content in PC12 cells, respectively. Tyrosine hydroxylase (TH) activity was also reduced markedly by treatment of the BuOH fraction (41.8% inhibition at $5{\mu}g/ml$ in the medium). Each solvent fraction did not show cytotoxicity towards PC12 cells by trypan blue exclusion test. This result suggests that the BuOH fraction has an inhibitory effect on catecholamine biosynthesis by reducing TH activity in PC12 cells.

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TRAO를 이용한 ORION A의 $^{12}CO$, $^{13}CO$ 관측

  • Kim, Yeong-Sik;Kim, Gwang-Tae
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.1
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    • pp.78.2-78.2
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    • 2012
  • Orion A 분자운은 별탄생이 활발하게 일어나는 영역이면서 태양계에 비교적 가깝다. 그렇기 때문에 낮은 분해능으로도 자세한 관측이 가능하다. Orion A 분자운까지의 거리가 450 pc 이므로 대덕전파안테나 1' beam으로 0.13 pc 가 된다. 이곳에는 필라멘트 구조가 있는데 FCRAO를 통한 다파장관측을 통해서 필라멘트 구조가 확인되었다.(Melnick et al. 2011). 필라멘트는 길이 4.8 pc, 너비 1.5 pc 로 대덕전파망원경의 1' beam으로 자세한 관측이 가능하였다. 2010년 11월-2011년 5월까지 Orion A 분자운을 대덕전파망원경을 이용하여 $^{12}CO$, $^{13}CO$(J=1-0) 분자선 관측을 하였으며, 관측영역은 적경: 5h 32m - 5h 37m, 적위: $-5^{\circ}$ 14' - $-5^{\circ}$ 37'으로 ($1^{\circ}{\times}1^{\circ}$) 영역을 관측하였다. 그 결과 필라멘트구조를 확인할 수 있었으며 일자 형태로 분포되어 있다는 구조적 결과 얻었다. 관측된 필라멘트 덩어리의 전형적인 크기는 약 0.7 pc, 밀도는 약 $10^4cm^{-3}$, 질량은 약 500 $M_{\odot}$이다. 매우 밀한 곳은 1000 M${\bigodot}$이상의 질량분포도 나타내고 있다. 이것은 이 지역이 일반적인 분자운과 비교했을 때 고밀도 영역임을 나타내고 있다. 더욱 자세한 밀도구조와 질량분포를 밝혀보고 별탄생과의 관련성을 연구하고자 한다.

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Self-Assembled and Alternative Porphyrin-Phthalocyanine Array

  • Kwag, Gwang-Hoon;Park, Eun-Joo;Kim, Sung-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.25 no.2
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    • pp.298-300
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    • 2004
  • An alternative molecular porphyrin-phthalocyanine aggregate was prepared and characterized with UV-visible and X-ray absorption spectroscopies. UV-visible experiments evidence 1-dimensional porphyrin-phthalo-cyanine array formed by mixing $SnTPPCl_2 ({\lambda}_{max}=429,\;{\varepsilon}=2.4{\times10^ 5 /M{\cdot}cm)\;and\;NiPc(OBu)_8({\lambda}_{max}=744 nm,\;{\varepsilon}= 2.0{\times}10^ 5 /M{\cdot}cm)$ in solution. In the UV-visible spectrum of the porphyrin-phthalocyanine array, $(SnPNiPc)_n$, a new Q-band appeared at 844 nm with decrease of the Q-band peak of $NiPc(OBu)_8$ at 744 nm. The red-shift of Q-band evidences an alternative porphyrin-phthalocyanine array formed in solution through metal-halide interaction rather than ${\pi}-{\pi}$ facial interaction, in which nickel of $NiPc(OBu)_8$ coordinates with chloride of $SnTPPCl_2$ through self assembly. Ni K-edge XANES (X-ray absorption near edge structure) spectra also support the axial ligation of nickel to chloride. The square planar structure of $NiPc(OBu)_8$ turns to an octahedral structure in (SnPNiPcSnP) by axial ligation. A higher energy-shift (0.2 eV) of the preedge peak of (SnPNiPcSnP) indicaties partial oxidation of nickel by charge transfer from NiPc$(OBu)_8$ to SnTPPCl$_2$.

Selective Cytotoxicity of Novel Platinum(II) Coordination Complexes Containing DL-2-Hydroxy 3-Methylbutyric Acid (DL-2 하이드록시 3-메틸 부틸산물 배위자로 한 새로운 항암성 백금(II) 착체의 위암세포와 정상신장세포에 대한 선택적 세포독성)

  • 정지창;홍언표;최승기;장성구;육창수;노영수
    • Biomolecules & Therapeutics
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    • v.11 no.2
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    • pp.91-98
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    • 2003
  • A new series of highly water soluble platinum(II) complexes[Pt(II)(DL-2-hydroxy-3-methylbutyrate)(trans-l-1,2-dimninocyc1ohexane)] (PC-1) and [Pt(II)DL-2-hydroxy-3-methylbutyrate](cis-1,2-diaminocyclohexane)](PC-2) were synthesized and characterized by their elemental analysis and by various spectroscopic techniques [infrared(IR), $^{13}C$-nuclear magnetic resonance (NMR)]. In vitro antitumor activity of new Pt(II)complexes was tested against MKN-45, MKN/ADM and MKN/CDDP human gastric adenocarcinoma cell lines using colorimetric MTT[3-(4,5-dimethyl thiazol-2-yl)-2,5-diphenyltetrazoliumbromide] assay for cell survival and proliferation. PC-1 and PC-2 showed active against MKN-45/P, MKN/ADM and MKN/CDDP human gastric cancer cell lines, and the antitumor activity of these compounds were comparable or superior to that of cisplatin. The nephrotoxicities of PC-1 and PC-2 were found quite less then that of cisplatin using MTT and [$^3H$] thymidine uptake tests in rabbit proximal tubule cells, human kidney cortical cells human renal cortical tissues. Based on these results, these novel platinum(II) complex compounds(PC-1 & PC-2) represent a valuable lead in the development of the new anticancer chemotherapeutic agents capable of improving antitumor activity and low nephrotoxicity.

스마트 그리드에 그린 IT 활용 연구

  • Jeong, Hyeon-Su;Kim, Byeong-Sik;Wang, Mi-Gyeong;Kim, Jong-Hun;Han, Myeong-Ji
    • Proceedings of the Korea Database Society Conference
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    • 2010.06a
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    • pp.33-41
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    • 2010
  • Recently the number of IT equipment have increased. It consumes large amounts of energy and is emissions of greenhouse gases. Co2 emissions with the PC and the monitor has the highest percentage to 39% more than other IT equipment. In addition, Plan for your PC's power management and technology development is being pursued in developed countries. To reduce energy costs of organizations with large numbers of the PC and to cut down on Co2 emissions, the energy load control technology of ACPI standards-based PC IS suggested. AMI-based PC power-management system was constructed, Approximately 20% of operating a result of the test power consumption was reduced. Looking at the case of the United States, PC monitors from the University of Wisconsin-Oshkosh was Sleep mode. As a result, the monitor on a, $ 20 for a year reduced energy costs. In GE(General Electronic), Approximately 75,000 PC's power setting time was Monitor Off :15 minutes/ Hard Drives Off 30 minutes/ System Standby 30 minutes/ Hibernation mode 2 hours. 1 year, electric bill was $ 2.5 million savings and 3 years electric bill was $ 6.5 million savings. Measuring energy usage data, using the measured data, electric energy management technology is not. Platform development to measure energy usage for Individual energy-consuming equipment is urgently required.

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