• Title/Summary/Keyword: PBT

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Preparation and Properties of Polymer PTC Composites for Process Safety (공정안전용 Polymer PTC 소재의 제조 및 특성)

  • 강영구;조명호
    • Journal of the Korean Society of Safety
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    • v.18 no.3
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    • pp.101-108
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    • 2003
  • Polymeric positive temperature coefficient(PTC) composites have been prepared by incorporating carbon black(CB) into high density polyethylene(HDPE), polyphenylene sulfide(PPS) and polybutylene terephthalate(PBT) matrices. A PTC effect was observed in the composite, caused by the large thermal expansion due to He consecutive melting of HDPE, PPS and PBT crystallites. This theory is based upon the premise that the PTC phenomenon is due to a critical separation distance between carbon particles in the polymer matrix at the higher temperature. The influence of PTC characteristics of the PPS/CB composite can be explained by DSC result. HDPE, one of prepared composition, exhibit the higher performance PTC behavior that decreaseing of negative temperature coefficient(NTC) effect and improved reproducibility by chemically crosslinking. Also, PBT/CB and PPS/CB composites exhibit the higher PTC peack temperature than HDPE/CB PTC composite, individually $200^{\circ}C$ and $230^{\circ}C$. These PTC composite put to good use in a number of safety application, such as self$.$controlled heater, over-current protectors, auto resettable switch, high temperature proctection sensor, etc.

A Study on Local Segmental Motions of Methylene Chain in Poly(Butylene Terephthalate) in Solution Phase

  • NamGung, Hyeon;O, Jeong Rae;Lee, Jo Ung
    • Bulletin of the Korean Chemical Society
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    • v.21 no.11
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    • pp.1071-1076
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    • 2000
  • Temperature dependent data of 13C spin-lattice relaxation times and NOE factors for methylene carbons at 50.3MHz and 125.5 MHz have been used to probe the local chain dynamics of poly(butylene terephthalate) (PBT) in solution phase. The interpretation of the relaxation data for methylene chain carbons in PBT was attempted on the basis of several proposed motional models, among which the DLM model was found to be superior. Analysis based on the DLM model indicated that the motion of the $OCH_2groups$ was more restricted compared with the central methylene carbon, which is consistent with conclusions from solid state experiments reported by other investigators. Librational amplitudes of terminal and central carbon of PBT were estimated to be $29.84^{\circ}$ and $32.01^{\circ}respectively.

Frosting Behavior on the Plate of Thermally Conductive Plastic (열전도성 플라스틱 평판에서의 착상거동)

  • 이장석;이관수
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.7
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    • pp.667-672
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    • 2004
  • An experimental study has been carried out to investigate the frosting behavior on the plate of thermally conductive plastic (PBT based resin) by comparing it with those of aluminum and some plastic test specimens (PTFE based resin). It is found that the frosting behavior of plastic specimens with 1 mm thickness shows similar trend to that of aluminum except PTFE. The properties of frost formed on the specimens are found to be affected by both thermal conductivity and surface characteristics of the materials. The results indicate that the heat and mass transfer rates of PBT resin are almost equivalent to those of aluminum.

Sintering of Surface-Modified PMN-PT-BT Powder with MgO Sol and Its Dielectric Properties (MgO 졸로 표면개질된 PMN-PT-BT 분말의 소결 및 유전특성)

  • Han, Kyoung-Ran;Kim, Chang-Sam
    • Journal of the Korean Ceramic Society
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    • v.41 no.12 s.271
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    • pp.929-932
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    • 2004
  • It is known that small amount of MgO in excess is often added to develop pure perovskite single phase of PMN-based composite, however, extra MgO precipitates in grains and inhibits densification of PMN. In this study PMN-PT-BT (PBT) powder was prepared by a conventional mixed oxide method using $(MgCO_3)_4{\cdot}Mg(OH)_2{\cdot}5H_{2}O$ instead of MgO. The precursor was heated at $500^{\circ}C/1h$ and its surface was modified with MgO sol. This effect was investigated in the aspects of sintering and dielectric properties. Small amount of added MgO sol ($0.5{\sim}1.0wt\%$) enhanced sintering substantially below $1000^{\circ}C$. The PBT with $0.5wt\%$ MgO sol sintered at $900^{\circ}C/2h$ had density of $7.62\;g/cm^3$, room temperature dielectric constant of 14800, loss of dielectric constant of $1.1\%$, which were comparable to those of the PBT sintered at $1000^{\circ}C/2h$. It was noticeable that the extra MgO precipitated mostly on triple points and grain boundaries and resulted in inhibition of grain growth.

Synthesis and Characterization of Poly(trimethylene terephthalate-co-trimethylene 2,6-naphthalate) Copolymers (Poly(trimethylene terephthalate-co-trimethylene 2,6-naphthalate) 공중합체의 합성과 분석)

  • 김영호;최재원;서용환;이한섭
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.41-44
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    • 2002
  • 블렌딩이나 공중합체의 합성은 한가지 또는 모든 구성성분 고분자의 단점을 보완하면서 효과적인 물성 발현을 위해 연구되어 왔다. 특히 방향족 폴리에스테르계 고분자들 사이에서는 PET/PEN, PEN/PHN, PBT/PBN, 또는 PET/PBT 등의 공중합체가 보고되고 있다[1-3]. 한편, poly(trimethylene terephthalate)(PTT)는 최근 섬유로 방사되어 카펫, 의류 등으로 응용된 이후 PTT를 주성분으로 하는 bicomponent 멜트블로운 부직포[4], 염색[5] 등의 연구가 활발히 이루어지고 있다. (중략)

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Effect of Drawing Conditions on the Structure of Poly(butylene terephthalate) Film (연신 조건이 PBT Film의 구조에 미치는 영향)

  • 김응수;김상용
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.10a
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    • pp.268-271
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    • 1998
  • Poly(butylene terephthalate) (이하 PBT)는 두 종류의 결정형태를 가지는 고분자로 널리 알려져 있다. 이 두 가지 결정형태를 각각 $\alpha$상 결정과 $\beta$상 결정이라고 하는데, 이 두 결정형은 방사나 연신 또는 열처리 등의 공정에 의하여 생성되기도 하고 $\alpha$-$\beta$상 간 전이를 일으키기도 한다[1],[2]. (중략)

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Fine Structure Formation and Properties with Take-up Velocities and Solvent Treatment Conditions of Poly(butylene terephthalate) Fibers (Poly(butylene terephthalate) 섬유의 방사속도와 용제처리조건에 따른 미세구조 형성과 물성)

  • 이선희;조현혹
    • Proceedings of the Korean Fiber Society Conference
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    • 2001.10a
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    • pp.456-458
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    • 2001
  • PBT는 엔지니어링 플라스틱용으로 전기ㆍ전자부품, 자동차부품에 주로 사용되며 이 두 종의 용도로 약 80%정도 소비된다. 섬유로 사용하는 것은 매우 소량이다. PBT섬유는 가연가공하여 주로 사용되며 스트레치 가공사로 되었을 때 중요한 특징은 권축의 신장회복성이 PET 및 나일론 6 섬유보다 아주 우수하다는 것이다. (중략)

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Studies on the thermal stability and Hydrolysis of the polymeric phosphorous-containing PBT (인계 난연제를 포함하는 PBT의 가수분해성과 열적 안정성에 관한 연구)

  • 조영호;박연흠;박종민
    • Proceedings of the Korean Fiber Society Conference
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    • 2001.10a
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    • pp.334-337
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    • 2001
  • 오늘날 건설, 교통, 섬유 등의 일상 생활에서부터 최첨단 분야인 항공 및 IT 까지 난연성을 요구하는 분야가 점차 확대되고 있어, 그에 대한 연구가 활발히 이루어지고 있다. 지금까지 가장 효율적인 고분자 재료의 난연제로써 할로겐화 화합물을 사용해 왔지만, 이러한 할로겐화 화합물은 우수한 난연 효과에 비해 심각한 단점들을 많이 가지고 있다. (중략)

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A Study on Establishing the Subbase Compaction Control Method based on the In-situ Elastic modulus (현장탄성계수에 근거한 보조기층 다짐관리방안 연구)

  • Choi, Jun-Seong;Kim, Jong-Min;Han, Jin-Seok;Kim, Bu-Il
    • International Journal of Highway Engineering
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    • v.13 no.1
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    • pp.33-40
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    • 2011
  • The resilient modulus which is presented mechanical properties of compacted subbase material is the design parameter on the Mechanistic - Empirical pavement design guide. The compaction control method on the Mechanistic - Empirical pavement design guide will be the way to confirm whether the in-situ elastic modulus measured after the compaction meets the resilient modulus which is applied the design. The resilient modulus in this study is calculated by the neural network suggested by Korea Pavement Research Program, and degree of compaction as the existing compaction control test and plate bearing capacity test(PBT) was performed to confirm whether the in-situ elastic modulus is measured. The Light Falling Weight Deflectometer(LFWD) is additionally tested for correlation analysis between each in-situ elastic modulus and resilient modulus, and is proposed correlation equation and test interval which can reduced overall testing cost. Also, the subbase compaction control procedure based on the in-situ elastic modulus is proposed using the in-situ PBT and LFWD test result.