• Title/Summary/Keyword: PBT

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Ecotoxicological Effects of NaDCC injection method in Ballast Water Management system on Marine Environments (NaDCC 주입 선박평형수 처리기술의 해양생태위해성에 대한 연구)

  • Kim, Tae won;Moon, Chang Ho;Kim, Young Ryun;Son, Min Ho
    • Proceedings of KOSOMES biannual meeting
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    • 2017.11a
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    • pp.236-236
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    • 2017
  • Effluent treated by an NaDCC injection method in Ballast water management system (BWMS) contains reactive chlorine species and disinfection by-products (DBPs). In this study, we conducted whole effluent toxicity (WET) testing and ecological risk assessment (ERA) to investigate its ecotoxicological effects on marine environment. WET testing was carried out for four marine pelagic and freshwater organisms, i.e., diatom Skeletonema costatum, Navicula pellicuosa, chlorophyta Dunaliella tertiolecta, Pseudokirchneriella subcapitata, rotifer Brachionus plicatilis, Brachionus calyciflorus and fish Cyprinodon variegatus, Pimephales promelas. The biological toxicity test revealed that algae was the only biota that showed apparent toxicity to the effluent; it showed no observed effect concentration (NOEC), lowest observable effect concentration (LOEC) and effect concentration of 50% (EC50) values of 25-50%, 50-100% and >100%, respectively, at three water condition, but did not show any significant toxicities on other biota. Meanwhile, chemical analysis revealed that the BWMS effluent contained total residual oxidants (TROs) below $0.03{\mu}g/L$ and a total of 25 DBPs such as bromate, volatile halogenated organic compounds (VOCs), halogenated acetonitriles (HANs), halogenated acetic acids (HAAs), chloropicrin and Isocyanuric acid. Based on ERA, the 25 DBPs were not considered to have persistency, bioaccumulation and toxicity (PBT) properties. The ratio of predicted environmental concentration (PEC) to predicted no effect concentration (PNEC) of the other DBPs did not exceed 1 for General harbor environment. However, four substances (Isocyanuric acid, Tribromomethane, Chloropicrin and Monochloroacetic acid) were exceed 1 for Nearship environment. But observed toxicity in the test water on algal growth inhibition would be mitigated by normal dilution factor of 5 applied for nearship exposure. Thus, our results of WET testing and ERA showed that the BWMS effluent treated by NaDCC injection method would have no adverse impacts on marine environment.

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Design and Implementation of a Large Scale Qualification Management System for Performance Improvement Through the Use of a WCBT(Web and Computer based Test) (WCBT를 이용한 대규모 자격관리 성능개선 시스템의 설계 및 구현)

  • Chang, Young-Hyun
    • Journal of the Korea Society of Computer and Information
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    • v.13 no.2
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    • pp.67-78
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    • 2008
  • The purpose of this paper is to discuss the design and implementation of a WCBT(Web and Computer based Test). The WCBT combines the strengths of both a WBT(Web-based test) and a CBT(Computer-based test) on the basis of efficiency and stability. The current assessment system, considered an important management tool in the construction and operation of a total management system for the national technical qualification, has some unstable elements with regard to system load and stability. The proposed system's technological aspects have been tested through a basic simulation pilot program. The pilot program will be expanded to include the local Chamber of Commerce and Industry because the stability of the system was proved through its application to the real-time national technical examination of KCCI (Korea Chamber of Commerce and Industry). The WCBT system has shown great efficiency in terms of system load, and has solved frequent communication problems which have occurred through the use of foreign qualifying examinations. The server and client systems of the WCBT have been given good evaluations with regard to the convenience of their use and the management system for operators and supervisors.

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Synthesis and Non-Isothermal Crystallization Behavior of Poly (ethylene-co-1,4-butylene terephthalate)s

  • Jinshu Yu;Deri Zhou;Weimin Chai;Lee, Byeongdu;Le, Seung-Woo;Jinhwan Yoon;Moonhor Ree
    • Macromolecular Research
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    • v.11 no.1
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    • pp.25-35
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    • 2003
  • A series of random poly(ethylene-co-1,4-butylene terephthalate)s (PEBTs), as well as poly(ethylene terephthalate) (PET) and poly(1,4-butylene terephthalate) (PBT), were synthesized by the bulk polycondensation. Their composition, molecular weight, and thermal properties were determined. All the copolymers are crystallizable, regardless of the compositions, which may originate from both even-atomic-numbered ethylene terephthalate and butylenes terephthalate units that undergo inherently crystallization. Non-isothermal crystallization exotherms were measured over the cooling rate of 2.5-20.0 K/min by calorimetry and then analyzed reasonably by the modified Avrami method rather than the Ozawa method. The results suggest that the primary crystallizations in the copolymers and the homopolymers follow a heterogeneous nucleation and spherulitic growth mechanism. However, when the cooling rate increases and the content of comonomer unit (ethylene glycol or 1,4-butylene glycol) increases, the crystallization behavior still becomes deviated slightly from the prediction of the modified Avrami analysis, which is due to the involvement of secondary crystallization and the formation of relatively low crystallinity. Overall, the crystallization rate is accelerated by increasing cooling rate but still depended on the composition. In addition, the activation energy in the non-isothermal crystallization was estimated.

A Survey on the Perception and Satisfaction of Korean Traditional Medical Students on Computer-Based Test (컴퓨터기반시험에 대한 한의과대학 학생들의 인식 및 만족도 조사)

  • Kim, Mikyung;Han, Chang-ho
    • Journal of Society of Preventive Korean Medicine
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    • v.25 no.3
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    • pp.57-71
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    • 2021
  • Objectives : Computer-based test (CBT) will be introduced in the national examination of Korean medicine doctors from 2023. This study was aimed to provide some information, including prior considerations, to those preparing for CBT, by presenting a summary of the survey results from participants in a CBT simulation test. Methods : In December 2020, applicants from the graduating class of the college of Korean medicine from four universities participated in the simulation test for CBT. An online anonymous survey on the applicants' preference for CBT versus paper-based tests (PBT) was conducted. The questionnaire consisted of multiple-choice questions on a 5-point Likert scale and free-form questions. Results : A total of 176 students responded to the survey. Their response to CBT was generally positive. The item with the highest agreement was that it should provide a sufficient opportunity to experience CBT in the undergraduate exam (4.38±0.839). Concerns about the possibility of cheating or poor concentration were also detected. In addition to guaranteeing the stability of the CBT system, there were many comments expressing the need to supplement functions within the CBT system, including the memo or highlighter function. Conclusions : This study confirmed the feasibility of CBT including multimedia questions in the field of Korean medicine education and identified overall positive responses from those who experienced the CBT simulation test. Although time is short and there is so much to prepare, we hope this will be a leap forward for effective educational innovation in line with the changing environment of the health care education field.

Physicochemical Quality Characteristics of Tomato Sauce Added with Pimpinella brachycarpa (참나물을 첨가한 토마토소스의 이화학적 품질특성)

  • Jang, Sang-Jun
    • Culinary science and hospitality research
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    • v.20 no.4
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    • pp.169-182
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    • 2014
  • This study investigates the physicochemical quality characteristics of tomato sauce added with different kinds of pimpinella brachycarpa. The results are as follows. The pH of tomato sauce added with freeze-dried pimpinella brachycarpa, in contrast to the tomato sauce with raw pimpinella brachycarpa, decreased as the addition quantity of the sample increased. As for sugar content, PBP0 with Pimpinella brachycarpa contained was shown to be the highest with 10.83. For chromaticity, all values (e.g, L, A and B) of tomato sauce added with pimpinella brachycarpa and with freeze-dried pimpinella brachycarpa decreased showing significant differences among the samples as the addition quantity of the samples increased. With increased addition quantity of the sample with freeze-dried Pimpinella brachycarpa, its water content decreased. PBP4, addition group with 4% of freeze-dried Pimpinella brachycarpa, was shown to be the highest DPPH free radical scavenging activity as 29.58. When adding Pimpinella brachycarpa to tomato sauce, a total number of micro-organisms decreased. In case of adding raw Pimpinella brachycarpa rather than freeze-dried Pimpinella brachycarpa, it created a further effect on an inhibitive action of growing and developing micro-organisms. In the preference of tomato sauce with Pimpinella brachycarpa, PBF2 with 2% of Pimpinella brachycarpa had the highest score as 5.1 for the color. For taste, 3.7, the lowest taste score, was shown in PBF1with 1% of Pimpinella brachycarpa. The overall preference revealed that PBF2 was the highest scoring 5.8.. PBF3 was scored highest with 5.9 for overall preference. From the comprehensive findings, 2~3% of the addition ratio between raw Pimpinella brachycarpa and freeze-dried Pimpinella brachycarpa in the production of tomato sauce is considered the most preferable.

The Study on the Marine Eco-toxicity and Environmental Risk of Treated Discharge Water from Ballast Water Management System using Plasma and MPUV (Plasma와 MPUV를 이용한 평형수관리장치의 배출수에 대한 해양생태독성 및 해양환경위해성에 관한 연구)

  • Shon, M.B.;Son, M.H;Lee, J.;Lee, S.U.;Lee, J.D.;Moon, C.H.;Kim, Y.S.
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.15 no.4
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    • pp.281-291
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    • 2012
  • In this study, WET (whole effluent toxicity) test with Skeletonema costatum, Tigriopus japonicus and Paralichthys olivaceus and ERA (environmental risk assessment) were conducted to assess the unacceptable effect on marine ecosystem by emitting the treated discharge water from 'ARA Plasma BWTS' BWMS (ballast water management system) using filtration, Plasma and MPUV module. 34 psu treated discharge water from ARA Plasma BWTS shown slight chronic toxicity effect on the P. olivaceus ($7d-LC_{50}{\Rightarrow}100.00%$ treated discharge water, $7d-LC_{25}{\Rightarrow}85.15%$ treated discharge water). Bromobenzene, chlorobenzene and 4-chlorotoluene in 34 psu treated discharge water from ARA Plasma BWTS were higher than in the background original content of seawater. The PECs (predictive environmental concentrations) of bromobenzene, chlorobenzene and 4-chlorotoluene calculated by MAMPEC (marine antifoulant model to predict environmental concentrations) program (ver. 3.0) were 3.34E-03, 2.10E-03 and 1.73E-03 ${\mu}g\;L^{-1}$, respectively and PNECs (predicted no effect concentrations) of them were 1.6, 0.5 and 1.9 ${\mu}g\;L^{-1}$. The PEC/PNEC ratio of bromobenzene, chlorobenzene and 4-chlorotoluene did not exceed one and 3 substances did not consider as persistence, bioaccumulative and toxic. Therefore, it was suggested that treated discharge water from ARA Plasma BWTS did not pose unacceptable effect on marine ecosystem.

Improvement of Shallow Soil Using Electric Heating Equipment (전기가열장치를 이용한 표층지반개량)

  • Park, Min-Cheol;Im, Eun-Sang;Shin, Beck-Chul;Han, Heui-Soo
    • Journal of the Korean Geotechnical Society
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    • v.28 no.10
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    • pp.41-54
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    • 2012
  • This paper is to develop the method of surface soil improvement by electric heating equipment. For this purpose, the electric heating systems were invented to apply to the in-situ soil. Iaboratory tests were done to study the behaviors of sea clays by eletric heating. In lab tests, two different heating temperatures, $70^{\circ}C$ and $110^{\circ}C$, were applied to the saturated clays to examine the relationship between evaporation and compaction. In addition, trafficability was analyzed to the heated by applying cone penetrometer to the heated clays Furthermore, in-situ tests were conducted to analyze the range of soil improvement and strength variations. The temperature changes in field were measured and they were compared with those of the commercial program (Temp/W). Also, the bearing capacities of electrically heated field were tested by PBT (plate bearing test). Several conclusions were derived from the results of the numerical analysis and tests (lab and field). The improvement ranges and strength variations of electrically heated soil depended on the heating temperature and time. If the heating temperature is more than $100^{\circ}C$ evaporating the ground water, the bearing capacity and settlement increased rapidly. The bearing capacities of in-situ soil increased more than 3 times, and heated soil emitted a lot of vapors. The soil around electric heater was sintered completely, and its range was almost 20 cm.

The usefulness of Forward IMRT for Head and Neck Cancer (두경부(Head & Neck)종양에서 Forward IMRT 유용성에 관한 고찰)

  • Baek Geum Mun;Kim Dae Sup;Park Kwang Ho;Kim Chung Man
    • The Journal of Korean Society for Radiation Therapy
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    • v.15 no.1
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    • pp.41-52
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    • 2003
  • I. Purpose The dose distribution in normal tissues and target lesions is very important in the treatment planning. To make the uniform dose distribution in target lesions, many methods has been used. Especially in the head and neck, the dose inhomogeneity at the skin surface should be corrected. Conventional methods have a limitation in delivering the enough doses to the planning target volume (PTV) with minimized dose to the parotid gland and spinal cord. In this study, we investigated the feasibility and the practical QA methods of the forward IMRT. II. Material and Methods The treatment plan of the forward IMRT with the partial block technique using the dynamic multi-leaf collimator (dMLC) for the patients with the nasopharyngeal cancer was verified using the dose volume histogram (DVH). The films and pinpoint chamber were used for the accurate dose verification. III. Results As a result of verifying the DVH for the 2-D treatment plan with the forward IMRT, the dose to the both parotid gland and spinal cord were reduced. So the forward IMRT could save the normal tissues and optimize the treatment. Forward IMRT can use the 3-D treatment planning system and easily assure the quality, so it is easily accessible comparing with inverse IMRT IV. Conclusion The forward IMRT could make the uniform dose in the PTV while maintaining under the tolerance dose in the normal tissues comparing with the 2-D treatment.

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A Study on the Fatigue Analysis of Glass Fiber Reinforced Plastics with Linear and Nonlinear Multi-Scale Material Modeling (선형과 비선형 다중 스케일 재료 모델링을 활용한 유리섬유 강화 플라스틱의 피로해석 연구)

  • Kim, Young-Man;Kim, Yong-Hwan
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.33 no.2
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    • pp.81-93
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    • 2020
  • The fatigue characteristics of glass fiber reinforced plastic (GFRP) composites were studied under repeated loads using the finite element method (FEM). To realize the material characteristics of GFRP composites, Digimat, a mean-field homogenization tool, was employed. Additionally, the micro-structures and material models of GFRP composites were defined with it to predict the fatigue behavior of composites more realistically. Specifically, the fatigue characteristics of polybutylene terephthalate with short fiber fractions of 30wt% were investigated with respect to fiber orientation, stress ratio, and thickness. The injection analysis was conducted using Moldflow software to obtain the information on fiber orientations. It was mapped over FEM concerned with fatigue specimens. LS-DYNA, a typical finite element commercial software, was used in the coupled analysis of Digimat to calculate the stress amplitude of composites. FEMFAT software consisting of various numerical material models was used to predict the fatigue life. The results of coupled analysis of linear and nonlinear material models of Digimat were analyzed to identify the fatigue characteristics of GFRP composites using FEMFAT. Neuber's rule was applied to the linear material model to analyze the fatigue behavior in LCF regimen. Additionally, to evaluate the morphological and mechanical structure of GFRP composites, the coupled and fatigue analysis were conducted in terms of thickness.

A Study on Marine Ecological Risk Assessment of Ballast Water Management Technology Using the Sodium Dichloroisocyanurate (NaDCC) Injection Method (이염화이소시아뉼산나트륨(NaDCC) 주입 선박평형수 처리기술의 해양생태위해성평가에 대한 연구)

  • Kim, Tae Won;Moon, Chang Ho;Park, MiOk;Jeon, MiHae;Son, Min Ho
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.24 no.2
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    • pp.203-214
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    • 2018
  • Ballast water treated by sodium dichloroisocyanurate (NaDCC) injection method in ballast water management system (BWMS) contains reactive bromine, chlorine species and disinfection by-products (DBPs). In this study, we conducted whole effluent toxicity (WET) testing and ecological risk assessment (ERA) to investigate its ecotoxicological effects on the marine environment. WET testing was carried out for eight marine and fresh water organisms, i.e. diatom, Skeletonema costatum, Navicula pelliculosa, green algae, Dunaliella tertiolecta, Pseudokirchneriella subcapitata, rotifer, Brachionus plicatilis, Brachionus calyciflorus and fish, Cyprinodon variegatus, Pimephales promelas. The WET test revealed that diatom and green algae were the only organisms that showed apparent toxicity to the effluent; it showed no observed effect concentration (NOEC), lowest observable effect concentration (LOEC) and effect concentration of 50 % (EC50) values of 25.0 %, 50.0 % and over 100.0 %, respectively, in seawater conditions. In contrast, rotifer and fish showed no toxicities to the effluent in the all salinity conditions. Meanwhile, chemical analysis revealed that the BWMS effluent contained total of 25 DBPs such as bromate, isocyanuric acid, formaldehyde, chloropicrin, trihalomethanes (THMs), halogenated acetonitriles (HANs) and halogenated acetic acids (HAAs). Based on ERA, the 25 DBPs were not considered to have persistency, bioaccumulation and toxicity (PBT) properties. The ratio of predicted environmental concentration (PEC) to predicted no effect concentration (PNEC) of the all DBPs did not exceed 1.0 for general harbour environments, but isocyanuric acid, tribromomethane, chloropicrin and monochloroacetic acid exceed 1.0 for near ship environments. However, when NOEC (25.0%) of the WET test results where actual effluent was applied, it was concluded that the NaDCC injection method did not have unacceptable ecological risks to the general harbor including near ship environments.