• Title/Summary/Keyword: PBO support

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Property Changes of Anion Exchange Pore-filling Membranes According to Porous Substrates (지지체 종류에 따른 음이온 교환 함침막 특성 변화)

  • Jeon, Sang Hwan;Choi, Seon Hye;Lee, Byeol-Nim;Son, Tae Yang;Nam, Sang Yong;Moon, Sun Ju;Park, Sang Hyun;Kim, Ji Hoon;Lee, Young Moo;Park, Chi Hoon
    • Membrane Journal
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    • v.27 no.4
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    • pp.344-349
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    • 2017
  • Alkaline fuel cells using polymer electrolyte membranes are expected to replace proton exchange membrane fuel cells, which have similar system configurations. In particular, in alkaline fuel cells, a low-cost non-platinium catalyst can be used. In this study, to fabricate high performance and high durability anion exchange membranes for alkaline fuel cell systems, two kinds of supports, polybenzoxazole and polyethylene supports, were impregnated with Fumion FAA ionomer, by which we tried to fabricate the support-impregnated membrane which has higher mechanical strength and higher ion conductivity than the Fumion series. Finally, the Pore-filling membranes were successfully fabricated and ionic conductivity and mechanical properties were different depending on the properties of the supports. In the pore-filling membranes with Fumion ionomer on the PE support, excellent mechanical properties were obtained, but ionic conductivity decreased. On the other hand, when the PBO support was impregnated with Fumion ionomer, high ionic conductivity was shown after impregnation due to high basicity of PBO, but the mechanical strength was relatively low as compared with Fumion-PE membrane. As a result, it was concluded that it is necessary to consider the characteristics of the support according to the operating conditions of the alkaline fuel cell during the preparation of the pore-filling membranes.