• 제목/요약/키워드: PB-22

검색결과 491건 처리시간 0.027초

Pb(Mg1/3Nb2/3)O3-PbTiO3계의 조성변화에 의한 다층 콘덴서 물성 (Properties of Multilyer Condensor with Composition Change in the System of Pb(Mg1/3Nb2/3)O3-PbTiO3)

  • 김복희
    • 한국세라믹학회지
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    • 제35권2호
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    • pp.123-128
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    • 1998
  • Multilayer ceramic capacitors(MLCC) were prepared by laminating the layer of composition with dif-ferent Curie temperature to improve temperature coefficient in the Pb(Mg1/3Nb2/3)O3-PbTiO3 binary system. Green sheet was formed by tape casting using Pb(Mg1/3Nb2/3)O3-PbTiO3 and PbTiO3 synthesized with solid state reaction of PBO. Nb2O5 MgO and TiO2. Green sheet with electrode of 70Ag-30Pd was laminated under 300 kg/cm2 at 70$^{\circ}C$ and sintered at 1100$^{\circ}C$ for 2hr. Curie temperatues for MLCC with 10 layers of pure PMN and 0.9PMN-0.1PT were lowered to -22$^{\circ}C$ and 36$^{\circ}C$ respectively. MLCC with 7 layers of PMN and 3 layers of 0.9PMN-0.1PT showed nearly zero temperature coefficient of capacitance in the range of -20∼30$^{\circ}C$ and sum of dissipation factor of each layer.

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효소를 이용한 동물성 식품가공부산물의 식품 소재화 탐색 (Study on Utilization of Animal By-products from Food Processing by Enzyme Treatment)

  • 채희정;인만진
    • Applied Biological Chemistry
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    • 제47권2호
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    • pp.197-201
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    • 2004
  • 식품 가공의 부산물 중 동물성 부산물을 재활용하여 조미소재로의 개발 가능성을 탐색하였다. 부산물 원료로는 돼지뼈(PB)와 닭뼈(CB), 그리고 참치 혈합육(TDF)을 사용하였다. PB와 CB를 열수로 18시간 추출한 후 단백질과 지방 분해효소를 처리하여 가수분해물을 제조하였다. 각각의 열수 추출물에서 지방의 제거를 위하여 1차로 lipase활성이 있는 pancreatic enzyme을 처리하고 2차로 Flavourzyme을 사용하는 경우 가수분해도(DH)가 PB는 약 70%, CB는 약 80%까지 증가하였다. 지방이 적은 TDF는 단백질 분해효소인 Alcalase와 Flavourzyme으로 분해한 결과 고형분 회수율은 약 22%, 단백질 회수율은 9%이었으며, 효소분해액 중 유리 아미노산 함량은 고형분 중 27%까지 향상되었다. 세 종류 분해액에 가염한 후 관능적인 특성을 조사한 결과 전체적으로 TDF>PB>CB의 순으로 우수하여 참치 혈합육은 조미소재의 원료로 적합한 동물성 부산물로 판단되었다.

홍천 철-희토류 광상의 편마암질 주변암에 대한 SHRIMP U-Pb 연령측정 (SHRIMP U-Pb Age Determination for the Gneissic Country Rocks Around the Hongcheon Iron-REE Depsosit)

  • 김명정;박계헌;고상모;이기욱
    • 암석학회지
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    • 제22권4호
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    • pp.299-305
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    • 2013
  • 홍천에는 카보내타이트-포스코라이트 복합체로 구성된 철-희토류 광상이 분포한다. 이 광상배태 지역의 모암인 변성암류에 대한 저어콘 U-Pb 연대측정을 실시하였다. 그 결과 약 1830Ma의 연령이 확인되었다. 이러한 연령은 경기육괴에서 일반적으로 산출되는 1870Ma의 화성 및 변성연령보다 다소 젊은 연령이며, 경기육괴의 고원생대 지질사건들의 시기와 지구조적 진화에 대한 보다 정밀한 연구의 필요성을 제기한다.

Preparation of YBCO with additives of PbO, $BaPbO_3$ and its Superconducting Properties

  • Zhanguo, Fan;Soh, Dae-Wha
    • 동굴
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    • 제78호
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    • pp.17-22
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    • 2007
  • The melting temperature and critical temperature (Tc) of $YBa_2Cu_3O_x$ with deferent content impurities of PbO and $BaPbO_3$ were studied. When the PbO was used as addition in $YBa_2Cu_3O_x$, although the melting point could be reduced, the superconductivity (the transition wide, ${\Delta}T_c$) became poor. From the XRD pattern of the sintered mixture of $YBa_2Cu_3O_x$ and PbO it was known that there is a reaction between $YBa_2Cu_3O_x$ and PbO, and the product is $BaPbO_3$. In the process of the reaction the superconducting phase of $YBa_2Cu_3O_x$ was decreased and in the sample $BaPbO_3$ became the main phase. Therefore the superconductivity was reduced. $BaPbO_3$ was chosen as the impurity for the comparative study. The single phase $BaPbO_3$ was synthesized by the simple way from both mixtures of $BaCO_3$ and PbO, $BaCO_3$ and $PbO_2$. Deferent contents of $BaPbO_3$ (10%, 20%, 30%) were added in the $YBa_2Cu_3O_x$. By the phase analysis in the XRD patterns it was proved that there were not reactions between $YBa_2Cu_3O_x$ and $BaPbO_3$. When $BaPbO_3$ was used as impurity in $YBa_2Cu_3O_x$ the superconductivity was much better than PbO as impurity in $YBa_2Cu_3O_x$. But the melting point of $YBa_2Cu_3O_x$ with $BaPbO_3$ could not be found when the temperature was lower than $1000^{\circ}C$ in the DTA measurement.

$PbO-B_2O_3$ 계 유리의 상분리에 미치는 $P_2O_5$의 영향 (Effect of $P_2O_5$ on the Phase Separation of $PbO-B_2O_3$ Glasses)

  • 최춘식;김철영
    • 한국세라믹학회지
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    • 제22권4호
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    • pp.47-53
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    • 1985
  • Various amount of $P_2O_5$ were added to $PbO-B_2O_3$ binary glass system to investigate its effect on the phase separation and physical properties of the glass. Experiments such as infrared spectroscopy scanning electron microscopy thermal expansion softening point and microhardnesses were done. Phase separation with $B_2O_3$ rich phase matrix and PbO rich phase droplet was observed for the glasses con-taining less than 10m/o of PbO while the opposite morphology of phase separation for the glasses containing more than 11m/o of PbO. By adding increasing amount of $P_2O_5$ their phase separation region was extended to the glass containing more than 20m/o of PbO. These effects can be interpreted in terms of the inoic field strength difference of each ions in the glasses. The abrupt changes of physical properties such as softening point thermal expansion and microhardness were observed for the glass with around 10m/o of PbO in this system. These changes are by the matrix composition change from TEX>$B_2O_3$ rich phase to PbO rich phase depending on PbO concentration.

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활성슬러지를 이용한 납 이온 제거에 영향을 미치는 인자에 대한 연구 (A Study on the Factors Affecting Pb^{2+}$ Removal by Activated Sludge)

  • 김동석;김미경;서정호
    • 한국환경과학회지
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    • 제7권4호
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    • pp.559-564
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    • 1998
  • The effects of temperature, initial $Pb^{2+}$concentration and initial sludge concentration on the initial $Pb^{2+}$ removal rate and maximal $Pb^{2+}$removal amounts in activated sludge, respectively, were investigated. The removal of $Pb^{2+}$ in activated sludge was proved to be temperature-dependent process. The initial $Pb^{2+}$ removal rate increased from 187.5 to 261.4 mg $Pb^{2+}$/g sludge dry weight min, in response to the promoted temperature from 1$0^{\circ}C$ to 6$0^{\circ}C$, while the maximal $Pb^{2+}$removal amount (78.5 mg $Pb^{2+}$/g sludge dry weight) occurred at 30t . As the initial $Pb^{2+}$concentration increased from 36 to 228 mg $Pb^{2+}$/L at the constant temperature of 30C and initial sludge concentration of 1.5 g sludge dry weight/L, the time to reach an equilibrium state was almost independent of the initial $Pb^{2+}$concentration and the equilibrium $Pb^{2+}$/removal amount was increased Irom 41.9 to 73.6 mg $Pb^{2+}$/g sludge dry weight. On the contrary, the equilbrium $Pb^{2+}$ emoval amount was decreased from 87.7 to 65.3 mg $Pb^{2+}$/g sludge dry weight as the in- crease of initial sludge concentration from 0.22 to 1.76 g sludge dry weight/L.

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뽕잎차에 의한 음용수중 Cd과 Pb의 제거효과 (Effect of Mulberry Leaf Tea for the Removal on Cd and Pb in drinking water)

  • 김현복;이완주
    • 한국잠사곤충학회지
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    • 제40권1호
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    • pp.17-22
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    • 1998
  • To investigate the detoxificative effect of tea, five kinds of tea(mulberry, anaerobic treated mulberry, green, barly tea and corm tea) were selected and determined their dotoxication activities for Cd and Pb in drinking water. The effect of tea on the removal of Cd and Pb were increased proportionally to the contents of teas. Anaerobic treated mulberry leaf tea showed stronger detoxication activity than the others. In drinking water contaminated with Cd, the removal effect of Cd was high 27% by anaerobic treated mulberry leaf tea and 14% by mulberry leaf tea as compared to green tea. Also, in drinking water with Pb, the removal effect of anaerobic treated mulberry leaf tea was the best among five kinds of tea. Pretreatment method on the removal effect of Cd was better than post-treatment method in the treatment method.

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식이내 섬유질의 종류가 성장기 흰쥐의 납 흡수 및 체내대사에 미치는 영향 (Effect of dietary fiber on lead absorption and metabolic changes in growing rats)

  • 김미경
    • Journal of Nutrition and Health
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    • 제22권6호
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    • pp.485-496
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    • 1989
  • This study was performed to investigate nutritional effect of various dietary fibers on lead absorption and metabolism of protein and lipid in growing rats. Forty eight male rats of Sprague-Dawley strain weighing 75.7$\pm$0.7g were blocked into six groups according to body weight and fed six kinds of diet different with fiber source(non-fiber, cellulose, pectin) and lead level(0%, 1% ) for 4 weeks. Results are summerized as follows: 1) Food intake, weight gain, FER and PER were remarkably decreased in lead(Pb) added groups, and FER and PER in Pb-added pectin group were significantly lower than those in Pb-added non-fiber group. 2) Weight of liver, kidney and epididymal fat pad, bone weight and length, hematocrit, and hemoglobin content were decreased in Pb-added groups. 3) Total protein content in serum was tended to be decreased in Pb-added groups, but total lipid and cholesterol contents in serum were not different with dietary Pb level and fiber source. 4) Nitrogen, lipid and cholesterol content in liver were tended to be deceased in Pb-added groups, and especially those of the Pb-added pectin group were the lowest among groups. 5) Daily urinary and fecal excretions of nitrogen, lipid and cholesterol were decreased in Pb-added groups. Especially fecal excretions of nitrogen, lipid and cholesterol in Pb-free groups were significantly increased by dietary cellulose and pectin. 6) Pb content in blood was significantly increased in Pb-added pectin group. There was no significant decrease in Pb contents of liver, kidney and tibia, and increase in excretion of Pb by feeding dietary fibers. In conculsion, dietary fibers had no effect on the absorption of Pb, and dietary pectin seemed to increase Pb poisoning by decreasing bioavailibility of protein, lipid and other nutrients in the diet.

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납 오염 논토양의 원위치 세척을 위한 FeCl3의 Bench-scale 적용성 평가: 세척전후 토양 특성변화 (Characteristics of Agricultural Paddy Soil Contaminated by Lead after Bench-scale In-situ Washing with FeCl3)

  • 고일하;김지숙;장윤영;양재규;문덕현;최유림;고명수;지원현
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제22권1호
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    • pp.18-26
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    • 2017
  • In a previous study, we assessed the feasibility of ferric chloride ($FeCl_3$) as a washing agent in bench-scale in-situ soil washing to remove Pb from agricultural paddy soil. Herein is a subsequent study to evaluate variations in soil properties after $FeCl_3$ soil washing in terms of fractionation and bioavailability of Pb and chemical properties of the soil. After soil washing, the soil pH decreased from 4.8 to 2.6 and the exchangeable fractions of Pb in the soil increased from 12 mg/kg to 15 mg/kg. Variations in the Pb fractionation of the soil increased Pb bioavailability by almost three-fold; however,the base saturation decreased by 75%. The concentrations of total nitrogen and available phosphate were similar before and after soil washing. The available silicate concentration significantly increased after soil washing but was two times lower than that of soil washed with HCl, which is widely used as a washing agent. This indicates that $FeCl_3$ can be an acceptable washing agent that protects the soil clay structure. The results suggest that soil amendment, such as liming, is needed to recover soil pH, reduce mobility of Pb, and provide exchangeable bases of Ca, Mg, and K as essential elements for the healthy growth of rice plants in reused soil that has been washed.