• 제목/요약/키워드: PARTICLE SIZE

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대기 중 PAHs의 입경별 가스/입자 분배평형에 관한 연구 (Gas/particle Partitioning of PAHs Segregated with Particle Size in Equilibrium States)

  • 박진수;이동수;김종국
    • 대한환경공학회지
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    • 제27권12호
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    • pp.1270-1276
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    • 2005
  • 대기 중 PAHs의 가스/입자 분배반응이 평형상태일 때 가스/입자분배계수($logK_p$)와 각 화합물의 증기압($logP_L^O$)과 선형식의 기울기가 -1이라는 것이 지금까지 알려진 사실이었다. 기러나 실제 대기에서 일어나는 가스/입자 분배와 차이를 보이는 현상에 대한 연구가 진행되면서 대기 입자의 불균일성 및 입자특성의 차이로 평형상태일 때 가스/입자 분배계수와 증기압과 기울기가 -1이 되지 않을 수도 있다는 주장이 제기되었다. 따라서 본 연구에서 이러한 가설을 토대로 대기 입자의 입경 크기에 따라 시료를 채취하여 평형상태일 때 입경의 크기에 따른 가스/입자 분배를 연구하였다. 대기 중 PAHs의 분배평형상태를 추정하기 위해 High-volume air sampler에서 채취된 입자와 가스를 이용하여 분배계수와 증기압을 구하고 이때 기울기가 -1에 가까운 시료를 평형상태에 있는 시료로 간주하였다. 그러나 평형상태에 해당하는 시료 중 같은 날 동시에 채취한 입경별 입자를 이용하여 각 입경 크기에 따라 분배계수와 증기압의 기울기를 계산한 결과에서는 평형상태일지라도 입경크기에 따라 동일한 기울기를 갖지 않고 입자가 커질수록 기울기가 완만해지는 현상을 나타내었다. 이러한 현상을 규명하기 위해 가스/입자 분배 반응의 두 가지 기작에 대하여 평형상태일 때 기울기가 -1이라는 결과를 도출하기 위해 가정했던 조건에 대하여 검토하였다. 그 결과 가스/입자 분배가 흡착이 주 반응이라 가정했을 때 입자의 크기에 따라 탈착엔탈피 변화량에 차이가 있었으며, 흡수인 경우에는 입자간의 활성계수의 차이를 간접적으로 확인할 수 있었다. 이는 평형상태일 경우에도 입자의 크기에 따라 가스/입자 분배평형에 이르는 정도가 다른 것으로 판단된다. 또한 가스/입자 분배반응 현상을 규명하기 위해서는 입자의 크기를 고려함으로써 그 현상을 좀 더 명확히 밝힐 수 있을 것으로 판단된다.

쌍화탕 제조의 생산성 향상에 대한 연구 (Studies on the Productivity in Manufacturing Ssang Wha Tang)

  • 조광연
    • 한국식품영양학회지
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    • 제8권1호
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    • pp.17-22
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    • 1995
  • The effect of particle size of raw material on the field of extract and changes in composition of Ssang Wha Tang was investigated during manufacturing. As the size of particle was decreased the yield was increased. The yield of extract increased as much as double times as the diameter of the particle decreased from 10 m to 1 m. But the composition of extract was not varied much as the diameter of the particle differed. From these results, it is concluded that cutting method affects the productivity of Ssang Wha Tang.

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고온침전반응에 의한 산화아연 제조공정에서 입자의 형상 및 입도분포에 미치는 침전조건의 영향 (The effect of precipitation conditions on the particle size and size distribution of zinc oxide prepared by high temperature precipitation)

  • 주창식
    • 한국인쇄학회지
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    • 제16권2호
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    • pp.11-22
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    • 1998
  • For the purpose of preparation of monodispersed spherical zinc oxide fine particles, an experimental research on the preparation of zinc oxide particles from zinc salts solutions by high temperature precipitation reaction was performed. Zinc oxide particles were precipitated from all the precipitation solutions tested if the precipitation temperature was higher than 60$^{\circ}$. As the precipitation temperature Increased until 80$^{\circ}$, the average particle diameter of zinc oxide particles decreased and the narrower particle size distribution were obtained. Spherical zinc oxide fine particles with relatively narrow particle size distribution were precipitated from the ZnSO$_4$ solutions with NaOH as precipitant. Final pH of precipitation solution had an effect on the amount of zinc oxide precipitated, but had no effect on the their particle size or size distribution.

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메칠, 에칠 알콜의 연소속도 (Burning Rate of Methyl and Ethyl Alcohols)

  • 우인성
    • 한국화재소방학회논문지
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    • 제10권1호
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    • pp.44-48
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    • 1996
  • Burning rate of immobilized methyl and ethyl alcohols on ceramic balls was studied. Experiments were performed by burning methyl, ethyl alcohols immobilized on sands (particle size 0.35mm) and ceramic balls (particle size 1-5mm) to measure mass burning rate, height burning rate and combustion temperature. The longer time from ignition to extinguishment was resulted from the larger particle size of ceramic balls and the smaller size of ceramic balls exhibited the higher mass burning rate. Of alcohols tested the relative magnitude of facilitation of combustion was methyl > ethyl. Combustion temperature of alcohols, without regard to the types of alcohols, was not increased with smaller ceramic balls(up to 3mm of particle size). However, with larger ceramic balls, combustion temperatare of alcohols was increased by 40-50$^{\circ}$ and the highest combustion temperatare was obtained with sands (particle size 0.35mm).

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입자경과 분쇄소비동력의 고찰에 의한 교반볼밀 분쇄특성의 정량적 연구 (A Quantitative Study of Grinding Characteristics on Particle Size and Grinding Consumption Energy by Stirred Ball Mill)

  • 최희규;왕림
    • 한국재료학회지
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    • 제17권10호
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    • pp.532-537
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    • 2007
  • A series of wet grinding experiments have been carried out using a stirred ball mill to systematically investigate consideration of grinding characteristics. The particle size distribution and median diameter of the grinding consumption power for a given grinding time were considered. Also, the effect of grinding aids on particle size and grinding consumption energy defined as the summation of grinding power was investigated. The grinding aids had influence on the smaller products size and decrease grinding consumption energy because the function of grinding aids were to be attribute to the prevention of agglomeration and ball and grinding chamber wall coating of sample powder. The grinding process seemed to be controlled by the force of agglomeration of the ground products. It was demonstrated that the particle size and grinding consumption energy could be more decreased by the addition of grinding aids.

졸-겔 법에 의한 단분산 구형 실리카 입자의 성장과 특성에 관한 연구 (Growth and Characteristics of Monodispersed Spherical Silica Particles by Sol-Gel Method)

  • 윤호성;박형상
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1997년도 Proceedings of the 13th KACG Technical Meeting `97 Industrial Crystallization Symposium(ICS)-Doosan Resort, Chunchon, October 30-31, 1997
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    • pp.13-19
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    • 1997
  • From the formation of the monodispersed silica particle which is a valuable for the industry by Sol-Gel process, the effects of the parameters participated in the process, the growth mechanism and the characteristics of silica particles for each rection conditions are investigated. To investigate about the formation of final silica particles, the suspension which performs the polymerization is reacted with molybdic acid, and the evolutions of TEOS and silica particle size are investigated in the reaction time ? 새 the characteristics of molybdic acid with the suspension. From the results, a constant number of silica particle is formed at early reaction stage. Silica particles grow through the aggregation of smaller particles and nucleation is rate-limiting step for the growth of particles. In the conditions of this study, spherical silica particles are formed, [NH$_3$] and [$H_2O$] concentration increase the particle size but particle size decrease with [$H_2O$] concentration which is a certain above region. Average particle sizes are 187.4~483.3 nm and standard deviations in the average particle size are 1.7~2.9% with each experimental condition. From the BET results, specific surface area is 5.5~23.4 $m^2$/g and these values decrease with increase size. The average pore size is 50~70$\AA$.

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입자 크기에 따른 난황죽의 이화학적 및 영양학적 특성 (Effect of Particle Size on the Physicochemical and Nutritional Properties of Egg Yolk Porridge)

  • 김혜란;김미리
    • 동아시아식생활학회지
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    • 제20권1호
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    • pp.77-83
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    • 2010
  • The study was conducted to investigate the effect of particle size on the physicochemical properties of egg yolk-rice porridge. The pH of egg yolk-rice porridge was decreased when compared to that of the control, while the lightness and yellowness was increased as the rice particle size increased. The viscosity of whole particle egg yolk porridge was highest among the three porridges at $40^{\circ}C$. The protein content of the egg yolk-rice porridge was increased three-fold, when compared to that of the rice porridges. The total amino acid content of egg yolk-rice porridge was 1,500.6 mg/100 g, while that of rice was 1,147.5 mg/100 g. The Lys and Thr content of the amino acid content of egg yolk-rice porridge were also increased. Sensory evaluation results revealed that the half particle size rice egg yolk-rice porridge had the highest scores in color, taste and over-all preference. Based on these results, the half particle size egg yolk-porridge had good quality with respect to both the physicochemical and nutritional properties.

고형성분이 포함된 전단희석 유체의 선형(扇形) 분무노즐을 통한 미립화 (Atomization of Shear-Thinning Liquid Slurry Discharging from Fan Spray Nozzles)

  • 안상모;류성욱;이상용
    • 한국분무공학회지
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    • 제13권1호
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    • pp.42-50
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    • 2008
  • In the present work, atomization characteristics of shear-thinning liquid slurry discharging from fan spray nozzles were studied experimentally for spray painting applications. The effects of solid particle size and concentration on the properties (especially on the viscosity) of suspensions and mean drop size were examined by using model fluids. In the range of low particle concentration (below 3 wt%), the fluid viscosity was primarily determined by the particle size. On the other hand, in the range of high particle concentration (higher than 10 wt%), the agglomeration phenomenon and the oil absorption capability of solid particles played major roles in determining the fluid viscosity. In the high concentration region, which most of the paints belong to, the fluid became more viscous and the shear thinning behavior appeared more prominent as the particle concentration was increased. In this region, mean drop size(SMD) decreased more rapidly with the increase of the injection pressure. Also, SMD became larger with the higher particle concentration and the larger particle size.

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EVALUATION OF SHEAR BEHAVIOR OF LARGE GRANULAR MATERIALS WITH DIFFERENT PARTICLE SIZES BY TRIAXIAL TEST AND NUMERICAL SIMULATION

  • Kim, Bum-Joo;Sagong, Myung
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2010년도 추계 학술발표회 3차
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    • pp.55-60
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    • 2010
  • Rockfill zones in CFRD consist typically of large granular materials, usually the maximum particle size up to several meters, which makes laboratory testing to determine the mechanical properties of rockfill difficult. Commonly, the design strength of the rockfills is obtained by scaling down the original rockfill materials and performing laboratory strength tests for the reduced size materials. The objective of the present study is to investigate the effect of particle size on the shear behavior and the strength for granular materials. A series of large-scale triaxial tests was conducted on large granular materials with the maximum particle size varying from 20 to 50mm. The test results showed that overall shear behaviors were similar between the samples with different particle sizes while there were slight differences in the magnitudes of the peak shear stress between the samples. In addition, a simulation of the granular material with the max. particle size of 20mm was performed using DEM code, $PFC^{2D}$, and compared with the test results. The deviatoric stress versus strain behaviors of experimental and numerical tests were found to be matched well up to the peak stress state.

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입자 크기별 가공부산물로 제조된 벌크흑연의 기계적 성질 (Mechanical Properties of Bulk Graphite using Artificial Graphite Scrap as a Function of Particle Size)

  • 이상혜;이상민;장원표;노재승
    • 한국분말재료학회지
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    • 제28권1호
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    • pp.13-19
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    • 2021
  • Bulk graphite is manufactured using graphite scrap as the filler and phenolic resin as the binder. Graphite scrap, which is the by-product of processing the final graphite product, is pulverized and sieved by particle size. The relationship between the density and porosity is analyzed by measuring the mechanical properties of bulk graphite. The filler materials are sieved into mean particle sizes of 10.62, 23.38, 54.09, 84.29, and 126.64 ㎛. The bulk graphite density using the filler powder with a particle size of 54.09 ㎛ is 1.38 g/㎤, which is the highest value in this study. The compressive strength tends to increase as the bulk graphite density increases. The highest compressive strength of 43.14 MPa is achieved with the 54.09 ㎛ powder. The highest flexural strength of 23.08 MPa is achieved using the 10.62 ㎛ powder, having the smallest average particle size. The compressive strength is affected by the density of bulk graphite, and the flexural strength is affected by the filler particle size of bulk graphite.