• Title/Summary/Keyword: PAAs

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The Minimum Concentrations of Surfactants Inducing Phytotoxicity and Their Symptoms (계면활성제(界面活性劑)의 약해유발농도(藥害誘發濃度)와 그 증상(症狀))

  • Yu, Ju-Hyun;Koo, Suk-Jin;Cho, Kwang-Yun
    • Korean Journal of Environmental Agriculture
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    • v.8 no.2
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    • pp.119-127
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    • 1989
  • The minimum concentrations of nonionic and anionic surfactants inducing phytotoxicity were investigated after spraying or flooding surfactant solutions to annual plants. Of the sufactants tested, LE, NP, SPSS, LN, PAAS and DBC induced phytotoxicity at the lowest concentrations through all treatments and Tween, Span, SP, SC, STPP and CLIS induced the least phytotoxicity even at high concentration. At flooded paddy field tests, anionic surfactants induced phytotoxicity at the lower concentration than nonionic, but showed similar tendencies with other treatments. In pre-emergence treatments of upland and dry paddy field tests, there was little phytotoxicity induced at over 10 percent, while phytotoxicity was induced at the lowest concentration among 6 treatments in flooded paddy field tests.

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$\pi$-A Isotherms and Electrical Properties of Polyamic acid Alkylamine salts(PAAS) Langmuir-Blodgett Films

  • Kim, Tae-Wan;Park, Jun-Su;Cho, Jong-Sun;Kang, Dou-Yol
    • Electrical & Electronic Materials
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    • v.11 no.10
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    • pp.60-65
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    • 1998
  • Deposition conditions, surface morphology, and electrical properties of polyamic acid alkylamine salts (PAAS) Langmuir-Blodgett(LB) films have been investigated through a study of surface pressure-area $\pi$-A isotherms, AFM (atomic force microscopy), and current-voltage characteristics. To obtain the optimum conditions of film deposition, the $\pi$-A isotherms were examined by varying temperature, barrier moving speed, dipping speed, spreading amount of solution etc. The Z-type LB films were made at the surface pressure of 5 mN m-1 and 25 mN m-1 for the AFM study; the former surface pressure forms the gas phase and the latter one forms the solid phase. The LB film made in the gas phase show domains with a size of about 200 A diameter and 70 A height. However, the LB films made in the solid phase show a very smooth surface with 2 A surface roughness. In the current-voltage characteristics measured along the perpendicular direction of the films, ohmic conduction has been observed below 105 V cm-1 and the calculated electrical conductivity is about 10-13 S cm-1. Nonohmic conduction has been observed above = 10-11 V cm and the conduction mechanism can be explained by the Schottky effect.

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An Optical True Time-Delay for Two-Dimensional X-Band Phased Array Antennas (2차원 X-밴드 위상 배열 안테나용 광 실시간 지연선로)

  • Jung, Byung-Min;Kim, Sung-Chul;Shin, Jong-Dug;Kim, Boo-Gyoun
    • Korean Journal of Optics and Photonics
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    • v.16 no.3
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    • pp.287-294
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    • 2005
  • In this paper, an optical true time-delay (TTD) for two-dimensional (2-D) phased array antennas (PAAs), composed of a multi-wavelength optical source and a fiber optic delay line matrix consisting of $2\times2$ optical switches with optical fiber connected between cross ports, has been proposed. A 2-bit $\times4-bit$ optical TTD for 10-GHz 2-D PAAs has been implemented by cascading a wavelength dependent TTD (WD-TTD) and a wavelength independent TTD (WI-TTD). The unit time delay for WD-TTD and WI-TTD have been chosen as ${\Delta}T=12ps$ and $\Delta\tau=6ps$, respectively. Time delay have been measured at all radiation angles. The maximum delay error for WD-TTD was measured to be 3 ps due to jitter incurred from gain switching. For the case of WI-TTD, error was within ${\pm}\;1\;ps$. The proposed optical TTD for a 2-D PAA has the following advantages: 1) higher gain compared to one-dimensional linear PAAs, 2) stabilization of optical power and wavelength by using a multi-wavelength optical source, and 3) fast beam scan and simple operation due to electronic control of the $2\times2$ optical switches matrix on a column-by-column basis.

Optical True Time-Delay Composed of Fiber Brags Gratings and Metal Film-Coated Fibers (광섬유 브래그 격자와 금속 박막이 단면에 증착된 광섬유로 구성된 광 실시간 지연선로)

  • 배덕희;신종덕;김부균
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.28 no.7A
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    • pp.433-439
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    • 2003
  • In this paper, we proposed a novel true time-delay (TTD) feeder for phased array antennas (PAAs) using fiber Bragg gratings (FBGs) and fibers coated with Cr/Au film. This structure requires less number of FBGs than the previously proposed FBG TTD feeders since one FBG is replaced with a metal film reflector in a strand of optical delay line connected to each antenna element and also provides the flexible wavelength selection since the metal film shows wide reflectance spectrum. A TTD for 10 GHz linear PAAs capable of steering beams in three different directions at 0$^{\circ}$and $\pm$30$^{\circ}$has been built. Experimental results on time delays are in good agreement with those calculated at all the steering angles. A 10 GHz linear array antenna with eight antenna elements red from the proposed TTD has been designed and the far-field radiation pattern or this antenna has been obtained by simulation.

Characterization of Colorless and Transparent Polyimide Films Synthesized with Various Amine Monomers (다양한 아민 단량체로 합성한 무색투명 폴리이미드 필름 특성)

  • Choi, Il-Hwan;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.34 no.5
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    • pp.480-484
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    • 2010
  • A series of poly(amic acid)s(PAAs) was prepared by reacting 4,4'-(4,4'-isopropylidenediphenoxy) bis(phthalic anhydride)(BPADA) as the anhydride monomer and 2,2'-bis(trifluoromethyl) benzidine (TFB), bis(3-aminophenyl)sulfone (APS), 4,4'-methylenebis-(2-methylcyclohexylamine) (MMCA), or bis[4-(3-aminophenoxy) phenyl] sulfone (BAPS) as the amine monomer with 5 mol% melamine in N,N-dimethylacetamide (DMAc). Colorless and transparent polyimide (PI) films were obtained by casting the PAAs at various heat treatment temperatures. The thermo-mechanical properties and optical transparency of the PI films were investigated. The thermal properties of the PI films were examined using differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and thermomechanical analysis (TMA), and their optical transparency were measured by spectrophotometry. The coefficient of thermal expansion (CTE) and yellow index (YI) values of all samples were in the range of $48.53-64.24ppm/^{\circ}C$ and < 3.0, respectively.

Variation of Rare Earth Element Patterns during Rock Weathering and Ceramic Processes: A Preliminary Study for Application in Soil Chemistry and Archaeology (암석의 풍화과정 및 도자기 제조과정에 따른 희토류원소 분포도의 변화: 토양화학 및 고고학적 응용을 위한 기초연구)

  • Lee, Seung-Gu;Kim, Kun-Han;Kim, Jin-Kwan
    • The Journal of the Petrological Society of Korea
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    • v.17 no.3
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    • pp.133-143
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    • 2008
  • On the basis of chemical composition of granite, gneiss and their weathering products, in this paper, rare earth elements (REEs) was estimated as tracer for clarifying a geochemical variance of earth surface material during weathering process. The chemical composition of clay, clay ware and pottery also were measured for testifying usefulness of REE geochemistry in clarifying the source material of pottery. It was observed that there was no systematic variation of chemical composition among source rock, weathered rock and soil during weathering process. The chemical composition of clay, clay ware and pottery also did not show systematic variation by baking pottery. However, PAAS (Post Archean Australian Shale)-normalized REE patterns of rock-weathered rock-soil and clay-clay ware-pottery are similar regardless of weathering process or ceramic art. Our results confirm that REE geochemistry is powerful tool for clarifying the source materials of surface sediment or archaeological ceramic products.

A Study on the Molecular Orientation and the Surface Mophology of polyimide precursor ultrathin film (폴리이미드 전구체 초박막의 분자배향과 표면상태에 관한 연구)

  • Jeong, Soon-Wook
    • Journal of the Korean Applied Science and Technology
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    • v.22 no.3
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    • pp.228-233
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    • 2005
  • Langmuir-Blodgett(LB) technique can speak the best candidate of the future molecular electronic devices. But, precursor as molecular ultrathin film devices require the bulk property that are influenced by the molecular orientation. So, this device is one of current interest in molecular electronic device development of new materials. In this study, quantitative evaluation of molecular orientation in LB films of polyamic acid alkylamine salt was performed analysis experiment comparing the absorption or transmission intensity of the FT-IR spectrometer and reflection or absorption spectra with UV-visible absorption spectra. It could find that the polar angle(${\theta}$) of the dipole moment appears in about $68^{\circ}$ and the tilting angle of the alkyl chain is about $11.5^{\circ}$.

A Study on the Preparation of Polyamic Acid Alkylamine Salt Langmuir-Biodgett Films (Polyamic Acid 알킬아민 염의 랭뮤어-블로젯막 제작에 관한 연구)

  • Jeong, Soon-Wook;Lim, Hyun-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.4
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    • pp.226-232
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    • 2000
  • Polyimide is a well-known organic dielectric material, which has not only high chemical and thermal stability but also good electrical insulating and mechanical properties. In this research, we have synthesized a polyamic acid(PAA), which is a precursor of the polyimide. To obtain the optimum conditions of polyamic acid alkylamine salt(PAAS) Langmuir-Blodgett(LB) film deposition, the ${\pi}-A$ isotherms were examined by varying subphase temperature, barrier moving speed and spreading amount of solution. Film formation was verified by measuring transfer ratio, absorption of UV/vis spectra and scanning electron microscope(SEM) images.

한강 수계에서의 희토류원소 분포도의 유역별/계절별 분포도 변화

  • Lee Seung-Gu;Lee Gwang-Sik;Lee Dong-Ho;Kim Yong-Je
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.263-265
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    • 2006
  • 희토류원소 분포도를 이용하여 하천본류의 화학조성에 미치는 각 지류 및 주변 암석들의 영향을 조사하기 위해 한강본류, 남한강, 북한강의 상류 및 하류에서 하천수를 계절별로 채취하여 분석하였다. 한강수내 희토류원소 자료를 PAAS (Post Archean Australian Shale)로 규격화한 분포도 특성은 다음과 같이 요약된다. 첫째, 한강의 모든 물시료는 Eu의 정(+)의 이상과 Ce의 부(-)의 이상을 갖고 있다. 둘째 절대농도에 있어서 하기에 채취된 모든 한강 시료는 다른 절기의 시료들보다. 함량이 높다. 셋째로 전반적으로 중희토류(HREE)가 경희토류(LREE)보다. 부화되어 있다. Eu의 이상을 가지고 비교해 볼 때, 한강 본류는 남한강쪽보다는 북한강쪽의 영향을 더 많이 받는 것으로 나타났다. 본 연구결과, 하천의 본류에 보다. 많은 영향을 주는 지류를 판단함에 있어서 희토류원소의 분포도자 유용하게 활용될 수 있음을 확인할 수 있었다.

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A Study on Deposition Conditions for a Manufacture of Polyimide LB Films (폴리이미드 LB막 제작을 위한 누적 조건 연구)

  • Park, J.S.;Choi, J.S.;Kim, Y.K.;Kim, T.W.;Kang, D.Y.
    • Proceedings of the KIEE Conference
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    • 1994.11a
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    • pp.222-224
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    • 1994
  • This paper describes the optimum conditions for depositing PAAS(polyamic acid alkylamine salts) Langmuir-Blodgett (LB) films, which are a precursor of polyimide LB films. The optimum conditions were studied by $\pi$-A isotherma with a varication of temperatures, spreading amounts or solution, compression speeds, and etc. Transfer ratio was also measured depending on the type of LB films.

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