• Bulletin of the Korean Chemical Society
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• v.30 no.5
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• pp.1026-1030
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• 2009

A novel Schiff base ligand (N, O system) 5-methoxy-2-phenyliminomethylphenol ($5-CH_3O-PMP$) was synthesized. Using the synthesized ligand as a fluorescent reagent, a fluorometric method was developed for the quantitative analysis of Al(III) ion. The quantitative analysis of Al(III) ion was performed by making the complex compound between Al(III) ion and $5-CH_3O-PMP$ in ethanol-water solution (85/15, v/v, pH 6.2). The excitation wavelength (${\lambda}em$) of the complex compound was 397 nm while the emmision wavelength (${\lambda}em$) was 498 nm. The quantitative analysis of Al(III) ion was carried out by estimating the fluorescence intensity. The various calibration curves were used for the quantitative analysis in the range of 0.27$\sim$27 ng/mL Al(III) ion concentrations. The detection limit was 0.027 ng/mL. Using the fluorometric method developed in this study, satisfying results were obtained from various samples such as tap water, hot spring water, river water, sea water and waste water, which contained considerable amounts of interfering ions.

• Preventive Nutrition and Food Science
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• v.7 no.1
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• pp.12-17
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• 2002

Simultaneous determination of nine water-soluble vitamins contained in multi-nutrient tablets was carried out by reversed phase high-performance liquid chromatography (RP-HPLC) equipped with analytical $C_{18}$ column and UV (270 nm) detector. Those standard vitamins were successfully separated within 23 minutes by gradient elution with solvent A (0.5 M potassium phosphate monobasic) and solvent B (0.25 M potassium phosphate monobasic-methanol, 1:1). Calibration curves showed good linealities with correlation coefficients (> 0.92) in tested ranged respectively. The detection limits were considered to be 2.1 ng for ascorbic acids 60 ng for Vit B$_{6}$ 3 ng for p-aminobenzoic acid, 9 ng for niacinamide, 9 ng for thiamin, 5.0 ng for folic acid and 1.5 ng for riboflavin at 0.05 a.u.f.s. Solid phase extraction through Sep-Pak (C$_{18}$ ) cartridge was successfully applied for purification of water soluble vitamins in commercial multi-nutrient tablets.ts.

• Bulletin of the Korean Chemical Society
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• v.32 no.10
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• pp.3603-3609
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• 2011

A novel sampling method of the headspace poly(dimethylsiloxane) (PDMS) mini-disk extraction (HS-PDE) was developed, optimized, validated and applied for the GC/MS analysis of spices flavors. A prototype PDMS mini-disk (8 mm outer diameter, 0.157 mm thickness, 9.4 mg weight) has been designed and fabricated as a sorption device. The technique uses a small PDMS mini-disk and very small volume of organic solvent and less sample size than the solvent extraction. This new HS-PDE method is very simple to use, inexpensive, rapid, requires less labor. Linearities of calibration curves for ${\alpha}$-pinene, ${\beta}$-pinene, limonene and ${\gamma}$-terpinene by HS-PDE combined with GC/MS were excellent having $r^2$ values greater than 0.99 at the dynamic range of 6.06~3500 ng/mL. The limit of detection (LOD) and the limit of quantitation (LOQ) showed very low values. This method exhibited good precision and accuracy. The overall extraction efficiency of this method was evaluated by using partition coefficients ($K_p$) and concentration factors (CF) for several characteristic components from nutmeg and mace. Partition coefficients were in the range from $2.04{\times}10^4$ to $4.42{\times}10^5$, while CF values were 0.88-15.03. HS-PDE was applied successfully for the analysis of flavors compositions from nutmeg, mace and cumin. The HS-PDE method is a very promising sampling technique for the characterization of volatile flavors.

• Bulletin of the Korean Chemical Society
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• v.33 no.7
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• pp.2224-2228
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• 2012

This study describes the ability of capillary electrochromatography (CEC) for the determination of imidacloprid and carbendazim in tomato samples. A novel liquid crystal crown ether modified hybrid silica monolithic column was synthesized, characterized and developed as separation column for the first time. Baseline separation of imidacloprid and carbendazim could be achieved using a mobile phase containing 90% (v/v) 20 mmol/L phosphate buffer (pH 7.0) and 10% (v/v) acetonitrile. The matrix matched calibration curves were linear with correlation coefficient $r^2$ > 0.9998 in the range of 0.20-10.00 mg/L. The limits of detection for imidacloprid and carbendazim were 0.061 and 0.15 mg/kg, respectively, which were below the maximum residue limits established by the European Union as well as Codex Alimentarius. Average recoveries for imidacloprid and carbendazim varied from 101.6-108.0% with relative standard deviations lower than 6.3%. This method was applied to the analysis of tomatoes collected from local markets.

• The Transactions of the Korean Institute of Electrical Engineers B
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• v.49 no.11
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• pp.729-736
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• 2000

This paper deals with the characteristic analysis of magnetizer for convergence purity magnet by the finite element method. The analysis utilizes combined method of the time-stepped finite element analysis and the Preisach model with hysteresis phenomena. In the finite element analysis, the non-linearity and the eddy current of the magnetizing fixure and permanent-magnet are taken account. The magnetization distribution in the permanent magnet is determined by using Preisach model which are composed of Everett function table and the first order transition curves is obtained by the Vibrating Sample Magnetometer. The calculated flux density values on the surface of the permanent magnet are led to the approximated gauss density values measured by the gauss meter. As a result, winding current, copper loss, eddy current loss of the magnetizing yoke, flux plot, surface gauss plot, temperature rise of the coil and resistor variation, vector diagram of magnetization distribution are shown.

• Journal of The Korean Society of Agricultural Engineers
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• v.52 no.6
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• pp.19-26
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• 2010

Batch experiments were conducted to investigate growth and nutrient removal performance of microalgae Chlorella vulgaris by using piggery wastewater in different concentration of pollutants and the common growth models (logistic, Gompertz and Richards) were applied to compare microalgal growth parameters. Removal of nitrogen (N) and phosphorus (P) by Chlorella vulgaris showed correlation with biomass increase, implying nutrient uptake coupled with microalgae growth. The higher the levels of suspended solids (SS), COD and ammonia nitrogen were in the wastewater, the worse growth of Chlorella vulgaris was observed, showing the occurrence of growth inhibition in higher concentration of those pollutants. The growth parameters were estimated by non-linear regression of three growth curves for comparative analyses. Determination of growth parameters were more accurate with population as a variable than the logarithm of population in terms of R square. Richards model represented better fit comparing with logistic and Gompertz model. However, Richards model showed some complexity and sensitivity in calculation. In the cases tested, both logistic and Gompertz equation were proper to describe the growth of microalgae on piggery wastewater as well as easy to application.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.7
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• pp.826-833
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• 2004

Cascade impactors are widely used to collect size classified aerosol. A major disadvantage of this instrument is the required long sampling time. Electrical low pressure impactor has been developed to overcome this disadvantage and to achieve real-time measurements on the particle size distribution. The instrument consists primarily of a corona charger, low pressure cascade impactor and multi channel electrometer. We designed and evaluated the performance of a potable 3-stage low pressure impactor using an electrical method. For the calibration of the impactor, monodispersed particles were generated using evaporation-condensation method followed by electrostatic classification using a DMA(Differential Mobility Analyzer). The collection efficiency curves of the stages can be determined by analysing the fraction of particles collected by each stage.

• Steel and Composite Structures
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• v.25 no.6
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• pp.727-734
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• 2017

This paper describes a quasi-static finite element analysis, which uses the explicit integration method, of the apex joint of a cold-formed steel portal frame. Such cold-formed steel joints are semi-rigid as a result of bolt-hole elongation. Furthermore, the channel-sections that are being connected have a reduced moment capacity as a result of a bimoment. In the finite element model described, the bolt-holes and bolt shanks are all physically modelled, with contact defined between them. The force-displacement curves obtained from the quasi-static analysis are shown to be similar to those of the experimental test results, both in terms of stiffness as well as failure load. It is demonstrated that quasi-static finite element analysis can be used to predict the behavior of cold-formed steel portal frame joints and overcome convergence issues experienced in static finite element analysis.

• Current Optics and Photonics
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• v.4 no.4
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• pp.273-276
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• 2020

We report on the relationship between output current for quadrant photodetector (QPD) and bias voltage in silicon-based p-i-n (positive-intrinsic-negative) QPD examined using millisecond pulse laser (ms pulse laser) irradiation. The mechanism governing the relationship was further studied experimentally. The output current curves were obtained by carrying out QPD under different bias voltages (0-40 V) irradiated by ms pulse laser. Compared to other photodetectors, the relaxation was created in the output current for QPD which is never present in other photodetectors, such as PIN and avalanche photodetector (APD), and the maximum value of relaxation was from 6.8 to 38.0 ㎂, the amplitude of relaxation increases with bias value. The mechanism behind this relaxation phenomenon can be ascribed to the bias voltage induced Joule heating effect. With bias voltage increasing, the temperature in a QPD device will increase accordingly, which makes carriers in a QPD move more dramatically, and thus leads to the formation of such relaxation.

• Earthquakes and Structures
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• v.22 no.3
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• pp.319-330
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• 2022

Retrofit of soft-story buildings due to seismic loads using Gap-Inclined-Brace (GIB) system is considered a new retrofit technique that aims to maintain both strength and stiffness of structure. In addition, it provides more ductility and less P-delta effect, and subsequently better performance is observed. In this paper, the effect of the eccentricity between GIB and the retrofitted column due to installation on the efficiency of the retrofitting system is studied. In addition, a modification in the determination method of GIB properties is introduced to reduce the eccentricity effect. Also, the effect of GIB system on the seismic response of mid-rise buildings with different heights considering soft-story at various heights has been studied. A numerical model is developed to study the impact of such system on the response of retrofitted soft-story buildings under the action of seismic loads. To achieve that goal, this model is used to perform a numerical investigation, by considering five case study scenarios represent several locations of soft-story of two mid-rise reinforced concrete buildings. At first, Non-linear static pushover analysis was carried out to develop the capacity curves for case studies. Then, Non-linear time history analyses using ten earthquake records with five peak ground accelerations is performed for each case study scenario before and after retrofitting with GIB. The results show that large GIB eccentricity reduce the ultimate lateral resistance and deformation capacity of the retrofitting system. Moreover, the higher the retrofitted building, the more deformation capacity is observed but without significant increase in ultimate lateral resistance.