• Title/Summary/Keyword: P-S conversion

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Preparation of High Molecular Weight Atactic Poly(vinyl alcohol) by Photo-induced Bulk Polymerization of Vinyl Acetate

  • Lyoo, Won-Seok;Ha, Wan-Shik
    • Fibers and Polymers
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    • v.2 no.2
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    • pp.108-115
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    • 2001
  • Vinyl acetate was polymerized in ultraviolet-ray initiated bulk system at low temperatures using 2,2-azobis(2,4-dimethylvaleronitrile) (ADMVN) or 2,2-azobis(isobutyronitrile) (AIBN) as the photoinitiator, respectively. High molecular weight (HMW) poly(vinyl alcohol) (PVA) having number-average degree of polymerization ($P_n$) of 3,900-7,800 and syndiotactic diad (S-diad) content of 52.5-54.0% could be prepared by complete saponification of synthesized linear poly(vinyl acetate) (PVAc) having $P_n$ 5,900-9,400 obtained at conversion of below 30%. $P_n$ of PVA using ADMVN was larger than that of PVA using AIBN. On the other hand, conversion of the former was smaller than that of the latter, and it was found that the initiation rate of the ADMVN was lower than that of AIBN. This could be explained by a fact that the rate of photolysis of AIBN is faster than that of ADMVN due to the higher quantum yield or dissociation rate constant of AIBN than that of ADMVN. The $P_n$, syndiotacticity, and whiteness of PVA from PVAc polymerized at lower temperatures were superior to those of PVA from PVAc polymerized at higher temperatures.

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Analysis of Success Factors for Converting Passenger Aircrafts to Freighters Using AHP (AHP 기법을 활용한 여객기의 화물기로의 개조사업 성공요인 분석)

  • Gwang Cho, Cho;Hyun Cheol Lee
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.46 no.3
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    • pp.148-160
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    • 2023
  • The air transport industry is experiencing unprecedented fluctuations in aviation demand through the Covid-19 pandemic, and is more focused than ever on maintaining and generating business profitability. During the pandemic, demand for air cargo has soared, and the conversion business from passenger aircrafts to freighters(P2F) is drawing attention as a new business in the aviation maintenance industry. This study derives important factors to be considered in order to successfully carry out the P2F project through a wide range of cases and related literature, and analyzes the relative importance of each factor using the analytic hierarchy process. Through a survey of 33 aviation maintenance experts with more than 20 years of field experience, the importance of main factors and their sub factors was determined and implications were drawn. As a primary result, in order to succeed in the P2F project, the main factors were identified in the order of skill, finance, and location. The most important sub factors for each main factors were identified in order of securing airframe modification skill, securing infrastructure construction cost, and creating P2F business complex and district. The quantified success factors suggested the critical direction for the successful development of Korea's P2F business, and presented viable and specific business strategies and implementation plans for each factors.

Recommendation of P and K Fertilizers for Crops Based on Soil Testing (토양분석치(土壤分析値)에 의(依)한 작물별(作物別) 인산(燐酸) 및 가리시비량(加里施肥量) 결정법(決定法))

  • Hong, Chong Woon;Kim, Yung Sup;Kim, Yung Koo
    • Korean Journal of Soil Science and Fertilizer
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    • v.6 no.1
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    • pp.29-31
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    • 1973
  • Upon the assumption that the available components in the soil evaluated by present analytical procedures, are as effective as the components applied to the soil as fertilizer, some formulas for the calculation of fertilizer requirements (F. R) for crops are suggested. Basically, the formulas are derived by combining the country average values of soil test data(${\overline{ST}}$) and of the optimum rate of fertilizers (ORF) for crops obtained from N.P.K. trials in farmer's field, as following. $$F.R(kg/10a)={\overline{ST}}(kg/10a)+ORFkg/10a-ST(kg/10a)$$ where, ST denotes the available components tested in the soil under question. Although this formula can be used both for P and K fertilizers, considering the significance of the potassium saturation rate of the soil for the availability of K, for the calculation of K fertilizer requirement, following formula is suggested. $$F.R(kg/10a)=(C.E.C.{\times}B.S.R.K.-KST(me/100g){\times}CF$$ where, B. S. R. K. is the basic potassium saturation rate of the soil and CF is conversion factor for the conversion of K me/100g into $K_2O$ kg/10a. The B. S. R. K. for different crops are obtained from the country average values of soil exchangeable K (${\overline{KST}}$), cation exchange capacity (CEC) and the optimum rates of K fertilizers for crops (ORF $K_2O$). $$B.S.R.K.=\frac{{\overline{KST}}{\times}CF+ORF(K_2O)}{CEC{\times}CF}$$ Using these formulas, equations for P and K fertilizer requirements for rice, barley, wheat, corn, italian millet, soy bean, sweet potato, potato and rape are derived.

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Development of Environmental Control Systems for Windowless Pig-housing (II) - Growth Performance of Weaned Piglets and Growing Pigs - (무창돈사의 환경제어 시스템 개발 (II) - 자돈과 육성돈의 사양성적 -)

  • 장동일;장홍희;임영일;박창식;이봉덕;이형석
    • Journal of Biosystems Engineering
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    • v.24 no.5
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    • pp.425-430
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    • 1999
  • Complex environmental control systems were developed, which control properly the pig's environment in windowless pig-housing based on the thermoregulatory behaviors of pigs and concentrations of noxious gases (CO2 and NH3). The this study was conducted to assess the performance of complex environmental control systems by raising weaned piglets and growing pigs under different seasonal conditions. Average daily gain of pigs in the experimental pig-housing was slightly higher than that of pigs in the conventional pig-housing. Average daily gain was not significantly different in winter and spring(P>0.05), but was significantly different in summer(P<0.05). Feed conversion rate of pigs in the experimental pig-housing was smaller than that of pigs in the conventional pig-housing. Feed conversion rate was not significantly different in environment for weaned piglets and growing pigs resulted in the improved daily gain, feed conversion rate, and carcass quality of the finishing pigs. These results showed that the performance of the complex environmental control systems in windowless pig-housing was excellent for weaned piglets and growing pigs.

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Effect of Substitution of Groundnut with Soybean Meal at Varying Fish Meal and Protein Levels on Performance and Egg Quality of Layer Chickens

  • Naulia, Uma;Singh, K.S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.11
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    • pp.1617-1621
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    • 2002
  • Two hundred and sixteen single comb white egg layers of the White Leghorn hens of 24 weeks of age were randomly allocated to 12 groups with three replications of six hens in each. Hens were fed in a factorial arrangement 2${\times}3{\times}$2, on diets containing either 16 or 18% crude protein with 0, 3 or 6% fish meal, replacing groundnut meal with soybean meal. Soybean meal incorporation improved (p<0.05) egg production, feed intake, feed conversion efficiency and egg weights. Egg quality traits of specific gravity, shape index, albumen index, yolk index and shell thickness remained unchanged. Laying performance was significantly (p<0.05) better at 18% than on 16% dietary protein level. Use of fish meal linearly improved egg production and feed conversion efficiency on diets supplemented with groundnut meal and fish meal incorporation showed quadratic improvement on feed conversion efficiency with SBM diets at 16% dietary protein level. Therefore, use of soybean meal as substitute of groundnut meal is recommended in layer diets, at 16% dietary protein level and fish meal incorporation could be beneficial for layers.

Verification of the Reliability and Validity of the Korean Pediatric Patient Classification System and Estimation of Nursing Time Conversion Index (한국형 소아 환자 분류도구의 신뢰도와 타당도 검증 및 간호시간 환산지수 산출 연구)

  • Sim, Mi Young;Park, Ji Sun;Kwon, Mi Kyung;Song, Suk Hee;Kim, Ye Seul;Kang, Min Seo;Lee, Shin Ae;Choi, Eun Seok;Ha, Eun Ju
    • Journal of Korean Clinical Nursing Research
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    • v.28 no.2
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    • pp.185-197
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    • 2022
  • Purpose: This study was performed to verify reliability and validity of the Korean Pediatric Patient Classification System (KPPCS) and estimate nursing time conversion index. Methods: The study was conducted in 9 children's hospital which included various areas and size of bed settings. To verify intraclass correlation reliability and construct validity, staff nurses and nurse managers of 21 wards classified 575 patients according to KPPCS comparing differences by age, days of stay, type of stay and medical department. Direct and indirect nursing time of 575 patients were measured by 284 nursing staffs by stopwatch observation and self reports for 24 hours. Results: KPPCS has 12 categories, 55 nursing activities and 80 criterions. High agreement among nurses (r=.91, p<.001) suggested substantial reliability. Construct validity was verified by comparing differences in age, days of stay, type of stay and medical department (p<.05). The correlation of nursing time and classification score was also statistically significant (r=.59, p<.001). The nursing time conversion index was 10.78 minutes per 1 classification score. The entire patient group were classified to four groups using KPPCS. Conclusion: The findings suggest that KPPCS would be a useful tool for estimating nursing demands related to the complexity of pediatric patients.

Effects of Xylose Reductase Activity on Xylitol Production in Two-Substrate Fermentation of Recombinant Saccharomyces cerevisiae

  • Lee, Woo-Jong;Kim, Myoung-Dong;Yoo, Myung-Sang;Ryu, Yeon-Woo;Seo, Jin-Ho
    • Journal of Microbiology and Biotechnology
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    • v.13 no.5
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    • pp.725-730
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    • 2003
  • Three recombinant Saccharomyces cerevisiae strains showing different levels of xylose reductase activity were constructed to investigate the effects of xylose reductase activity and glucose feed rate on xylitol production. Conversion of xylose to xylitol is catalyzed by xylose reductase of Pichia stipitis with cofactor NAD(P)H. A two-substrate fermentation strategy has been employed where glucose is used as an energy source for NADPH regeneration and xylose as substrate for xylitol production. All recombinant S. cerevisiae strains Yielded similar specific xylitol productivity, indicating that xylitol production in the recombinant S. cerevisiae was more profoundly affected by the glucose supply and concomitant It generation of cofactor than the xylose reductase activity itself. It was confirmed in a continuous culture that the elevation of the glucose feeding level in the xylose-conversion period enhanced the xylitol productivity in the recombinant S. cerevisiae.

Power Factor improvement of Power Conversion Equipment for High Pressure Sodium Lamps (고압 나트륨 램프 구동용 전력변환장치의 역률 개선)

  • Lee, S.H.;Suh, K.Y.;Lee, H.W.;Lee, S.H.;Mun, S.P.
    • Proceedings of the KIEE Conference
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    • 2002.04a
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    • pp.147-150
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    • 2002
  • HPSL(High Pressure Sodium lamp)have attracted much attention in recent years, because they offer high luminous efficiency and very long life. Recently, AC-DC converters have been widely as power factor improvement circuits in the power conversion equipment An application of the ZVT-PWM(Zero Voltage Transition Pulse Width Modulation) boost converter, which has great advantage on miniaturization and high power density, to the power factor improvement circuit of the HPSL inverter are described to identify the power factor correction characteristics of the inverter. In this paper the series-parallel resonant inverter(electronic ballast) for driving a HPS lamp is discussed. Finally, a power factor corrector is cascaded in front of the electronic ballast. Consequently, a high power factor above 0.99 and low THD on the line current can be achieved.

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The Fabrication of $n^+-p^+$ InP Solar Cells by the Diffusion of Sulphur (S확산에 의한 $n^+-p^+$ InP 태양전지의 제작)

  • Jung, Ki-Ung;Kim, Seon-Tai;Moon, Dong-Chan
    • Solar Energy
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    • v.10 no.3
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    • pp.60-65
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    • 1990
  • [ $n^+-p^+$ ] InP homojunction solar cells were fabricated by thermal diffusion of sulphur into a $p^+$-InP wafer($p=4{\times}10^{18}cm^{-3}$), and a SiO film($600{\AA}$ thick) was coated on the $n^+$ layer as an antireflection(AR) coating by an e-beam evaporator. The volume of the cells were $5{\times}5{\times}0.3mm^3$. The front contact grids of the cells with 16 finger pattern of which width and space were $20{\mu}m$ and $300{\mu}m$ respectively, were formed by photo-lithography technique. The junction depth of sulphur were as shallow as about 0.4r m We found out the fabricated solar cells that, with increasing the diffusion time, short circuit current densities($J_{sc}$), series resistances($R_s$) and energy conversion efficiencies(${\eta}$) were increased. The cells show good spectral responses in the region of $5,000-9,000{\AA}$. The short circuit current density, the open circuit voltage( $V_{oc}$), the fill factor(F.F) and the energy conversion efficiency of the cell were $13.16mA/cm^2$, 0.38V, 53.74% and 10.1% respectively.

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A COMPARATIVE STUDY BETWEEN DEGREE OF CONVERSION AND FLEXURAL STRENGTH OF COMPOSITE RESINS

  • Lee Seong-Hee;Pae Ahran;Kim Sung-Hun
    • The Journal of Korean Academy of Prosthodontics
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    • v.44 no.3
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    • pp.333-342
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    • 2006
  • Statement of problem. Although many studies have been carried out to investigate the correlation between the degree of conversion and the flexural strength of composite resins, there is minimal information in the literature attempting to compare degree of conversion, flexural strength and their correlation between restorative composite resins and flowable composite resins. Purpose. The purposes of this study were to measure the degree of conversion and flexural strength of composite resins with different rheological behavior and to correlate the two properties. Materials and methods. Four restorative (Vit-1-escence, Z-250, Tetric ceram, Esthet-X) and four flowable (Aeliteflo, Admiraflow, Permaflo, Revolution) light-curing composite resins were investigated. The degree of conversion(DC) was analyzed with Fourier transfer infra-red spectroscopy(FTIR) spectrum by a potassium bromide(KBr) pellet transmission method. The spectrum of the unpolymerized specimen had been measured before the specimen was irradiated for 60s with a visible light curing unit. The Poiymerized specimen was scanned for its in spectrum. The flexural strength(FS) was measured with 3-point bending test according to ISO 4049 after storage in water at $37^{\circ}C$ for 24 hours. The data were statistically analyzed by an independent sample t-test and one-way ANOVA at the significance level of 0.05. The dependence of flexural strength on the degree of conversion was also analyzed by regression analysis. Results. Mean DC and FS values ranged from 43% to 61% and from 84.7MPa to 156.7MPa respectively. DC values of the flowable composite resins were significantly higher than those of restorative composite resins (P < 0.05). The FS values of restorative composite resins were greater than those of flowable composite resins. No statistically significant correlation was observed between the DC and the FS tested in any of the composites. The dependence of FS on DC in restorative or flowable composite resins was not significant. Conclusion. It can be concluded that radical polymerization of the organic matrix is not a major factor in determining flexural strength of the commercially available composite resins.