• Title/Summary/Keyword: P-P bonding

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A CLINICAL STUDY OF THE EFFECTS OF ORTHODONTIC APPLIANCES ON THE GINGIVAL TISSUE (교정장치가 치간조직에 미치는 영향에 관한 임상적 연구)

  • Jang, Ki-Young
    • The korean journal of orthodontics
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    • v.15 no.2
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    • pp.291-301
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    • 1985
  • Fifty subjects who were to be treated with fixed orhodontic appliances by light wire edgewise technique were selected. Bands with different marginal depth were made in first molar and direct bonding brackets were bonded in second premolar. For determining the effects of fixed orthodontic appliance on the gingival tissue, the changes of clinical crown length, periodontal pocket depth, gingival sulcus fluid were checked. The results were as follows: 1. Gingival condition was deteriorated after wearing the fixed orthodontic appliance, and the deteriorative rate was decreased gradually. 2. The greatest gingival change was occurred in the maxillary first molar among the experimental teeth. 3. The gingival change of maxillary teeth was greater than that of mandibular teeth. $(p\leq0.01)$ 4. The greater gingival change was occurred around subgingivally located band than around supragingivally located band. 5. Comparing the gingival changes of banded teeth with them of bonded teeth, the gingival tissue was more effected by oral hygiene than by type of appliances. 6. In the quantitive changes of gingival crevicular fluid, there was no exact relationship with gingival inflammation.

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Investigation on Adhesive Properties depending on the Environmental Variation of the Steel Plate Adhesive Strengthening Method by the Epoxy Resin (에폭시 수지 접착 강판보강공법의 환경 변화에 따른 부착 특성 검토)

  • Han, Cheon-Goo;Byun, Hang-Yong;Park, Yong-Kyu
    • Journal of the Korea Institute of Building Construction
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    • v.7 no.3
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    • pp.107-113
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    • 2007
  • This study is to investigate adhesive properties depending on the temperature, humidity, and freeze-thraw of the Steel plate adhesive strengthening method by the epoxy resin. The results are summarized as following. For the temperature variation, the debonding failure appear only after 1 cycle of temperature varoation because the coefficient of thermal expansion of the epoxy resin is comparatively large, and the bonding strength is decreased. The deformation properties and ultrasonic pulse velocity on each materials are similar until 4 cycles on the dry and moisture test. As the freeze-thraw test, the epoxy resin is degraded easily subjected to freeze-thaw cycle, comparatively easy, so the debonding failure may occur in short term because of the freeze-thaw repeatition.p

Novel Bumping Material for Solder-on-Pad Technology

  • Choi, Kwang-Seong;Chu, Sun-Woo;Lee, Jong-Jin;Sung, Ki-Jun;Bae, Hyun-Cheol;Lim, Byeong-Ok;Moon, Jong-Tae;Eom, Yong-Sung
    • ETRI Journal
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    • v.33 no.4
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    • pp.637-640
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    • 2011
  • A novel bumping material, which is composed of a resin and Sn3Ag0.5Cu (SAC305) solder power, has been developed for the maskless solder-on-pad technology of the fine-pitch flip-chip bonding. The functions of the resin are carrying solder powder and deoxidizing the oxide layer on the solder power for the bumping on the pad on the substrate. At the same time, it was designed to have minimal chemical reactions within the resin so that the cleaning process after the bumping on the pad can be achieved. With this material, the solder bump array was successfully formed with pitch of 150 ${\mu}m$ in one direction.

Conducting Properties of Polypyrrole Coated Imogolite

  • Lee, Yun-Ha;Kim, Bum-Joong;Yi, Whi-kun;Takahara, Atsushi;Sohn, Dae-Won
    • Bulletin of the Korean Chemical Society
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    • v.27 no.11
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    • pp.1815-1818
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    • 2006
  • Imogolite which has chemical composition, $(HO)_3Al_2O_3SiOH$, was synthesized with orthosilicate acid and aluminium chloride at low pH solution. It has extremely large aspect ratio with an external diameter of 2nm and the length of a few micrometers. The high aspect ratio of the imogolite could make the material as the filler for the high strength fiber and as the wire for the electronic applications. Here, Imogolite that derives considerable microporosity from a nanometer-sized tubular structure has been modified with a conducting polymer, polypyrrole. Its bonding and wiring structure were confirmed by IR and TEM. The measured conductivity after modification with polypyrrole increased with polypyrrole thickness at various voltage conditions.

Modeling of an embedded carbon nanotube based composite strain sensor

  • Boehle, M.;Pianca, P.;Lafdi, K.;Chinesta, F.
    • Advances in aircraft and spacecraft science
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    • v.2 no.3
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    • pp.263-273
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    • 2015
  • Carbon nanotube strain sensors, or so called "fuzzy fiber" sensors have not yet been studied sufficiently. These sensors are composed of a bundle of fiberglass fibers coated with CNT through a thermal chemical vapor deposition process. The characteristics of these fuzzy fiber sensors differ from a conventional nanocomposite in that the CNTs are anchored to a substrate fiber and the CNTs have a preferential orientation due to this bonding to the substrate fiber. A numerical model was constructed to predict the strain response of a composite with embedded fuzzy fiber sensors in order to compare result with the experimental results obtained in an earlier study. A comparison of the numerical and experimental responses was conducted based on this work. The longitudinal sensor output from the model matches nearly perfectly with the experimental results. The transverse and off-axis tests follow the correct trends; however the magnitude of the output does not match well with the experimental data. An explanation of the disparity is proposed based on microstructural interactions between individual nanotubes within the sensor.

Development of Backflow prevented Micropump (역류방지형 유리계 마이크로 펌프 개발)

  • Choi J. P.;Cho K. C.;Kim H. Y.;Kim B. H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.05a
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    • pp.229-232
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    • 2005
  • This paper presents the design and fabrication of backflow prevented Micropump using the metal membrane. The Micropump is consisted of the lower plate, metal membrane, upper plate and the piezoelectric-element. The lower plate includes the micro channel and the inlet, outlet of the Micropump. The upper plate includes the micro channel and connects the piezoelectric-element. These plate are fabricated on the Pyrex glass wafer by sandblasting process. The metal membrane does roll of check valve that is prevented backflow of the Micropump. The metal membrane is fabricated on the stainless steel by laser machining. Piezoelectric-element is actuated the Micropump and controlled flowing of fluid. The Micropump is fabricated by bonding process of these multi-layer.

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The Crystal and Molecular Structure of Phthalylsulfacetamide

  • Shin, Whan-Chul;Kim, Young-Chang;Koo, Chung-Hoe
    • Bulletin of the Korean Chemical Society
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    • v.5 no.1
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    • pp.23-26
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    • 1984
  • The crystal structure of phthalylsulfacetamide, one of the long-acting 'sulfa' drugs, has been determined by the X-ray diffraction methods. The crystal is monoclinic with cell dimensions of a = 7.980(3), b = 12.784(2), c = 18.064(7) ${\AA}$ and ${\beta}$= $112.94(2)^{\circ}$, space group $P2_1$/c and Z = 4. The structure was solved by the direct methods and refined to R = 0.048. The sulfonylacetamide moiety is folded with respect to the central phenyl ring and the benzamide and benzoyl planes are nearly perpendicular to each other. This conformation is consistent with those of the relevant molecules containing the corresponding moieties. All of the molecules in the crystal lattice are connected by a three-dimensional hydrogen bonding network.

The Crystal and Molecular Structure of Phlorizin Dihydrate

  • Shin, Whan-Chul
    • Bulletin of the Korean Chemical Society
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    • v.6 no.1
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    • pp.7-11
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    • 1985
  • The crystal structure of phlorizin, a ${\beta}$ -D-glucopyranoside of a flavonoid dihydrochalcone phloretin, has been determined by single crystal diffraction methods using diffractometer data obtained by the ${\omega}-2{\theta}$ scan technique with Cu $K{\alpha}$ radiation from a crystal with space group symmetry $P2_12_12_1$ and unit cell parameters a = 4.9094 (2), b = 19.109 (1), c = 23.275 (4) $\AA$. The structure was solved by direct methods and refined by full-matrix least-squares to a final R = 0.047 for the 1697 observed reflections. The dihydrochalcone moiety is flat and fully extended. The glucose ring has the $^4C_1$ chair conformation and the conformation of the primary alcohol group is gauche-gauche. The crystal packing is dominated by an extensive hydrogen bonding pattern. There are one strong and two weak intramolecular hydrogen bonds in the phlorizin molecule.

A Structure-Based Activation Model of Phenol-Receptor Protein Interactions

  • 이경희
    • Bulletin of the Korean Chemical Society
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    • v.18 no.1
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    • pp.18-23
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    • 1997
  • Data from structure/activity studies in vir gene induction system have led to evaluate the working hypothesis of interaction between phenolic inducers and phenol binding proteins. The primary specificity in the association of a phenolic inducer with its receptor in our system is hypothesized to be the hydrogen bonding interactions through the ortho methoxy substituents as well as the proton transfer between the inducer and the binding protein. In this paper the proposed working model for phenol-mediating signal transduction was evaluated in several ways. The importance of the general acid-base catalysis was first addressed by the presence of an acidic residue and a basic residue in the phenol binding protein. Series of compounds were tested for vir gene expression activity to confirm the generation of a strong nucleophile by an acidic residue and an involvement of a basic residue as a proton acceptor. An attempt was made to correlate the pKa values of the phenolic compounds with vir gene induction activities as inducers to further support the proposed proton transfer mechanism. Finally, it was also observed that the regioselectively attached methoxy group on phenol compounds is required as the proper hydrogen bond acceptor.

Micellar Effects on Intramolecular Charge Transfer Emission from Biphenylcarboxylic Acids

  • Yoon, Min-Joong;Cho, Dae-Won;Kang, Seong-Gwan;Lee, Min-Yung
    • Bulletin of the Korean Chemical Society
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    • v.14 no.6
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    • pp.704-708
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    • 1993
  • The intramolecular charge transfer (ICT) phenomena of the photoexcited 2-biphenylcarboxylic acid (2BPCA) and 4-biphenylcarboxylic acid (4BPCA) have been investigated in some surfactant micellar solutions. The ICT emission of 4BPCA and 2BPCA in aqueous solution at sufficiently low pH (1-3) has been observed to be markedly quenched and blue-shifted upon addition of a cationic surfactant, cetyltrimethylammonium chloride (CTAC) in contrast to little change in anionic sodium dodecyl sulfate (SDS) and neutral Brij 35. An anionic emission band has been observed to be enhanced at expense of the ICT emission as a function of the concentration of CTAC. These results with the micellar effects on the fluorescence decay kinetics of 4BPCA suggest that formation of the ICT state of the excited acids is inhibited by CTAC-induced proton transfer as well as the decrease in the polarity and/or hydrogen-bonding ability of the micellar microenvironment entrapping the acids.