• Title/Summary/Keyword: P-P bonding

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Synthesis and Bonding Properties of Phenol·Resorcinol·Formaldehyde Resin Adhesives (페놀·레조르시놀 수지의 합성과 접착성능)

  • Roh, Jeang-Kwan
    • Journal of the Korean Wood Science and Technology
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    • v.21 no.1
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    • pp.51-58
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    • 1993
  • The phenol resorcinol formaldehyde resin (PRF) adhesives which are curing at ambient temperature for structural purposes were synthesized. A PRF resin is produced according to the two-stage reaction system. In first stage, a low-condensed resol or methylolated phenol were prepared from phenol by reaction with a formaldehyde in alkaline condition. The molar ratio of phenol to formaldehyde was 1.0~1.4. And in second-stage, resorcinol was added to combine with the methylol group of a low-condensed resol(R/P molar ratio 0.3). The glue-joint strength, pot-life and workability of this synthetic PRF resin were superior to conventional ambient temperature setting adhesives such as oilic urethane or water based polymer-isocyanate resin for wood adhesives.

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Reaction Study of Tannin with Formaldehyde in the Adhesive Containing Condensed Tannin (Condensed Tannin을 포함한 접착제에서 Tannin과 Formaldehyde의 반응에 관한 연구)

  • 정경호
    • Textile Coloration and Finishing
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    • v.4 no.3
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    • pp.116-121
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    • 1992
  • This paper is on for a material to replace the petroleum-based resins used as adhesives for the fiber in rubber composite materials. The study limited to the reaction properties of tannin with formaldehyde. Tannin-formaldehyde(TF) reactions were carried out in aqueous media. Rates of reaction were strongly dependent on concentration, temperature, pH, and the mole ratio of tannin to formaldehyde. Viscosities of reaction mixtures were followed up to gelation. The reactivity of tannin-formaldehyde resins was greater than that of resorcinol-formaldehyde resins. To formulate an adhesive, a styrene-butadiene-vinyl pyridine terpolymer latex(L) was added to the TF. This preliminary results suggest that the condensed tannins have considerable promise as substitutes for resorcinol used in resin formulation for bonding of fiber to rubber.

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Analyses of Densification and Plastic Deformation during Equal Channel Angular Pressing of CNT/Cu Powder Mixtures (CNT/Cu 혼합분말의 ECAP 공정 시 치밀화 및 소성변형 거동 해석)

  • Quang, P.;Yoon, S.C.;Jeong, Y.G.;Kim, H.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2006.05a
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    • pp.123-126
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    • 2006
  • In this study, bottom-up type powder processing and top-down type SPD (severe plastic deformation) approaches were combined in order to achieve full density of carbon nanotube (CNT)/metal matrix composites with superior mechanical properties by improved particle bonding and least grain growth, which were considered as a bottle neck of the bottom-up method using the conventional powder metallurgy of compaction and sintering. ECAP (equal channel angular pressing), the most promising method in SPD, was used for the CNT/Cu powder consolidation. The powder ECAP processing with 1, 2, 4 and 8 route C passes was conducted at room temperature.

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Comparative studies of density functionals in modelling hydrogen bonding energetics of acrylamide dimers

  • Lin, Yi-De;Wang, Yi-Siang;Chao, Sheng D.
    • Coupled systems mechanics
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    • v.6 no.3
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    • pp.369-376
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    • 2017
  • Intermolecular interaction energies and conformer geometries of the hydrogen bonded acrylamide dimers have been studied by using the second-order Møller-Plesset (MP2) perturbation theory and the density functional theory (DFT) with 17 density functionals. Dunning's correlation consistent basis sets (up to aug-cc-pVTZ) have been used to study the basis set effects. The DFT calculated interaction energies are compared to the reference energy data calculated by the MP2 method and the coupled cluster method at the complete basis set (CCSD(T)/CBS) limit in order to determine the relative performance of the studied density functionals. Overall, dispersion-energy-corrected density functionals outperform uncorrected ones. The ${\omega}B97XD$ density functional is particularly effective in terms of both accuracy and computational cost in estimating the reference energy values using small basis sets and is highly recommended for similar calculations for larger systems.

Natural Dyeing with Walnut Hull(II) - Dyeing Properties of Cotton - (호도외피를 이용한 천연염색(II) - 면섬유의 염색성 -)

  • Shin, Youn-Sook
    • Korean Journal of Human Ecology
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    • v.9 no.3
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    • pp.63-68
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    • 2006
  • Walnut colorants were extracted from walnut hull and their dyeing properties on cotton were investigated. Effect of dyeing conditions on dye uptake and effect of mordanting on dye uptake, color change and colorfastness were explored. Walnut colorants showed low affinity to cotton compared with wool and its isotherm adsorption curve was Freundlich type. It was considered that hydrogen bonding and van der Waal's force were involved in the adsorption of walnut colorants onto cotton. The dyed cotton showed YR color and there was no significant color change as pH changed. The dyed cotton showed generally high colorfastness except fastness to washing and light. Mordanting did not improve dye uptake and colorfastness, and not affect color of the dyed cotton significantly.

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Grinding Characteristic of Hard Disk Glass by Glass by ELLD Grinding

  • Kim, Gyung-Nyun;Hitoshi Ohmori
    • International Journal of Precision Engineering and Manufacturing
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    • v.1 no.2
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    • pp.61-66
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    • 2000
  • In this paper, we discuss the machining characteristics of HDD glass. Glass is now being used globally as a data storage device, Such glasses are usually machined by lapping by this technique requires a long machining time, resulting in low productivity, For this reason, we examine the possibility of EILD grinding in HDD glass workpieces, A move to ELID grinding may result in substantial cost reduction. Our purpose is to investigate the grinding characteristics of HDD glass in ELID grinding. The bonding materials for fixing the abrasives of cast iron, cobalt and bronze are applied, and grinding conditions such as rotation speed and feeding are varied. Results show that with the use of ELID, mirror surfaces can be achieved with high efficiency.

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A Study on Microstructures and Mechanical Properties of A356/coated SiC Composites Fabricated by Squeeze Casting (Squeeze Casting법에 의해 제조된 A356/coated SiC복합재료의 미세조직과 기계적 특성에 관한 연구)

  • Lee, Kyung-Ku;Lee, Doh-Jae
    • Journal of Korea Foundry Society
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    • v.14 no.5
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    • pp.429-437
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    • 1994
  • Influence of interfacial structure between matrix and particle in A356/coated SiC composite fabricated by squeeze casting method was studied. Experimental variables are types of coated metallic film on SiC particles such as Cu, Ni-P, and applied pressure for squeeze casting. It was found that coating treatment on SiC particles improves the wetting of liquid A356 alloy on SiC particles. SiC particle distribution is very homogeneous in A356 matrix alloy which is fabricated by squeeze casting. Analysing the surface morphology of fractured A356/coated SiC, it was concluded that metallic thin film by coating treatment on SiC particle improves the interfacial bonding between particle and matrix, and so does on mechanical properties such as tensile strength. However, there was on significant difference in hardness between those composite made of as-received SiC particle and coated SiC particle.

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Effect of Ni plating and surface roughness on the bonding strength of thermoelectric module (열전 모듈의 접합강도에 미치는 Ni 도금 및 표면 거칠기의 영향)

  • Kim, Seong-Sun;Go, Byeong-Man;Son, In-Jun;Park, Gwan-Ho;Jo, Sang-Heum
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.347-348
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    • 2015
  • Ni 도금 및 표면 거칠기에 따른 열전모듈의 접합강도 특성을 알아보기 위해 Bi-Te 소재 위에 Sand-blasting 방법을 사용하여 표면 거칠기를 조절하고, Ni-P 무전해 도금을 수행하였다. 접합강도 측정 및 표면 성분을 분석하기 위해 전단응력 측정기, FE-SEM을 이용하였다. Sand-blasting과 Ni 도금을 실시한 시편이 sand-blasting과 도금을 미실시한 대조군보다 전단응력이 높았고, 큰 방 수의 sand로 sand-blasting 한 시편일수록 전단응력이 더 높은 경향성을 보였다.

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Conductive Characterization of DLC Thin Films Fabricated by Radio-Frequency Magnetron Sputtering

  • Cao, Nguyen Van;Kim, Tae-Gyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.290-290
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    • 2011
  • In this study Diamond-like carbon (DLC) films were deposited on p-type Si substrates using a Radio-Frequency magnetron Sputtering system. The DLC film was deposited by bombarding graphite target with a N2/Ar plasma mixture with various conditions: substrate, pressure, deposition time, temperature of substrate, power and ratio of gas mixture. The effect on the conduction and hardness of DLC thin films were investigated. The conduction of DLC films were measured by I-V measurement. In addition, Raman analysis was performed to study the chemical bonding structure. The hardness was measured by Nano indentation. Atomic Force Microscopy was used for determined surface morphology of DLC film.

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Preparation of Silicon Nitride-silicon Carbide Composites from Abrasive SiC Powders

  • Kasuriya, S.;Thavorniti, P.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1091-1092
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    • 2006
  • Silicon nitride - silicon carbide composite was developed by using an abrasive SiC powders as a raw material. The composites were prepared by mixing abrasive SiC powder with silicon, pressing and sintering at $1400^{\circ}C$ under nitrogen atmosphere in atmosphere controlled vacuum furnace. The proportion of silicon in the initial mixtures varied from 20 to 50 wt%. After sintering, crystalline phases and microstructure were characterized. All composites consisted of ${\alpha}-Si_3N_4$ and ${\beta}-Si_3N_4$ as the bonding phases in SiC matrix. Their physical and mechanical properties were also determined. It was found that the density of the obtained composites increased with an increase in the $Si_3N_4$ content formed in the reaction.

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