• Bulletin of the Korean Chemical Society
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• 제19권10호
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• pp.1084-1090
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• 1998

The oxidation of triphenylphosphine by [(tpy)(phen)RuⅣ(O)]2+ and [(bpy)(p-tert-butylpy)RuⅣ(0)]2+ (tpy is 2,2': 6',2"-terpyridine, phen is 1,10-phenanthroline, bpy is 2,2'-bipyridine, and p-tert-butylpy is para-tertbutylpyridine) in CH3CN has been studied. Experiments using 18O-labeled complex show the oxyl group transfer from [RuⅣ=O]2+ to triphenylphosphine occured quantitatively within experimental error. Kinetic data were fit to a second-order for [RuⅣ=O]2+ and [PPh3]. The initial product, [RuⅡ-OPPh3]2+, was formed as an observable intermediate and then underwent slow solvolysis. The reaction proceeded as endothermic in activation enthalpy and a decrease in activation entropy. The oxidative reactivity of four representative ruthenium mono-oxo oxidants against triphenylphosphine was compared. These systems have been utilized as electrochemical oxidative catalysts.

• 기본간호학회지
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• 제17권1호
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• pp.45-54
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• 2010

Purpose: The purpose of this study was to develop and test an explanatory model of dyspnea in patients with chronic lung disease (CLD). Methods: Participants were 181 patients with CLD, recruited from the outpatient pulmonary clinic of one university hospital in Korea. Data were collected using questionnaires, as well as measurement of 6-minute walking distance (6MWD), oxygen saturation ($SpO_2$), FEV1% predicted, and Body Mass Index (BMI). Results: The results indicated a good fit between the proposed dyspnea model and the collected data [$x^2$=91.27, p= .13, $x^2$/d.f.=1.17, Normal Fit Index= .934]. Oxygenation ($SpO_2$, = -.530), self-efficacy (= -.429), anxiety (= .253), depression (= .224), exercise endurance (6MWD, = -.211), and pulmonary function (FEV1% predicted, = -.178) had a direct effect on dyspnea (all p< .05) and these variables explained 74% of variance in dyspnea. BMI, smoking history, and social support had an indirect effect on dyspnea. Conclusion: The findings of this study suggest that comprehensive nursing interventions should focus on recovery of respiratory health and improvement of emotions, exercise ability, and nutritional status. From this perspective, pulmonary rehabilitation would be an effective strategy for managing dyspnea in patients with CLD.

• 무역상무연구
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• 제56권
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• pp.57-76
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• 2012

As globalization accelerates and the trade environment rapidly changes, a more prepared trade workforce is required for the business world. The trade department is an important educational institution that educates and trains future trade talent. Thus, in the evolving trade environment, their role has significant implications for the economic growth of Korea. The present paper is a comparative study of the importance of the university education system in terms of the trade work force through the Person-Organization fit (P-O fit) perspective. We observe that the American trade education system is more oriented to meet and reflect the needs from the real world. It contains a support structure through various governmental organizations that offer financial incentives as well as educational opportunities through internships and other hands-on experiences. The trade education systems in universities in Korea are still static by comparison and are recommended to implement changes that will give students more practical exposure to trade. The governmental and business sectors are also encouraged to support universities in achieving these goals through building a strong cooperative network with university trade departments.

• 한국가정과학회지
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• 제3권2호
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• pp.112-119
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• 2000

The purpose of this study is to investigate the bodice patterns by analyzing sensory evaluations. Anthropomatric data was collected between April and October of 2000. Total 283 body measurements were collected for this study including both direct and indirect measurements(29 variables from the direct anthropometric data. 5 variables from the indirect anthropometric data). Data were analyzing using percentiles. standard deviation and Anova. The appearance and fit of three kinds of bodice patterns (N. L. H type) were evaluated by expert panel and the subjects. The results of the anthropometric measurements and sensory evaluations are as follows : A significant differences (p$\leq$.001) in the height, width and girth Items was found. The results of the bodice pattern evaluations by expert panel indicates that a significant difference (p${\le}$.05) in the responses to the placement of the waist dart, the fit of the bust area and the placement o( the back shoulder dart for 20's and 30's. The result of the evaluations by subjects indicates that a significant difference (p${\le}$.05) in the responses to the placement of the waist dart for 40's. A significant difference (p${\le}$.05) in the responses to the suitability of the shoulder area among the age groups.

• Bulletin of the Korean Chemical Society
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• 제16권12호
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• pp.1218-1222
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• 1995

The pKa values of benzyltetrahydrothiophenium halides 1a-f in water have been estimated by measuring the absorbances of the solution in aqueous hydroxide ion solution. Assuming that the ratios of the activity coefficients remains close to unity, the absorbance of the solution can be expressed as A/[SH]o=(εSH+εS-K[OH-])/(1+K[OH-]), where A, [SH]o, K, εSH, and εS- are the absorbance of solution, the initial concentration of 1a-f, the equilibrium constant, and the extinction coefficients for SH and S-, respectively. The εS- and K values that best fit with this equation were calculated by a nonlinear regression analysis with a large number of absorbance data determined at different [OH-] and [SH]o. The pKa values of the SH were then calculated with the relationship Ka=-log K+14. The validity of this method has been demonstrated by the excellent agreements between the experimental and literature pKa values of three organic acids. The pKa values of 1a-f estimated by this method are in the range of 12.5-15.3 and correlate well with the Hammett equation. The large negative deviation for the pKa values of 1e and 1f from the Hammett plot has been attributed to the extra hydrogen bonding between the phenyl group and water molecules attracted by the hydrophilic substituents.

• 분석과학
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• 제37권1호
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• pp.39-46
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• 2024

Alizarin dye, a persistent and hazardous contaminant in aquatic environments, presents a pressing environmental concern. In the quest for efficient removal methods, adsorption has emerged as a versatile and sustainable approach. This study focuses on the development and application of Zinc Oxide/Nickel Oxide (ZnO/NiO) nano-composites as adsorbents for alizarin dye removal. These semiconducting metal oxide nano-composites exhibit synergistic properties, offering enhanced adsorption capabilities. Key parameters affecting alizarin removal, such as contact time, adsorbent dosage, pH, and temperature, were systematically investigated. Notably, the ZnO/NiO nano-composite demonstrated superior performance, with a maximum alizarin removal percentage of 76.9 % at pH 6. The adsorption process followed a monolayer pattern, as suggested by the Langmuir model. The pseudo-second-order kinetics model provided a good fit to the experimental data. Thermodynamic analysis indicated that the process is endothermic and thermodynamically favorable. These findings underscore the potential of ZnO/NiO nano-composites as effective and sustainable adsorbents for alizarin dye removal, with promising applications in wastewater treatment and environmental remediation.

• 한국마이크로전자및패키징학회:학술대회논문집
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• 한국마이크로전자및패키징학회 2005년도 ISMP
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• pp.111-129
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• 2005

Pop provides OEMs and EMS with a platform to cost effectively expand options for logic + memory 3D integration - Expands device options by simplifying business logistics of stacking - Integration controlled at the system level to best match stacked combinations with system requirements - Eliminates margin stacking and expands technology reuse - Helps manage the huge cost impacts associated with increasing demand for multi media processing and memory. PoP is well timed to enable and leverage: - Mass customization of systems for different use (form, fit and function) requirements o Bband and apps processor + memory stack platforms - Logic transition to flip chip enables PoP size reduction o Area and height reduction. Industry standardization is progressing. Amkor provides full turn-key support for base package, memory package and full system integration.

• 마이크로전자및패키징학회지
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• 제11권2호
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• pp.17-22
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• 2004

본 연구에서는 마이크로파용 유전재료로서 널리 사용되고 있는 BNT($BaO-Nd_{2}O_3-TiO_2$)계 세라믹스를 기본조성으로 하고, 저융점의 phoshpate계 유리 프릿의 첨가를 통해 LTCC(Low Temperature Cofired Ceramic)에 적용 가능한 유전율을 가진 조성을 개발 하고자 $70P_{2}O_5-5B_{2}O_3-(25-x)BaO-xNa_{2}O$ 유리를 제조 및 특성을 평가하였다 또한, BNT계 세라믹스에 글래스 프릿을 $5 - 15\;wt\%$ 범위에서 첨가하고, 800 - $950^{\circ}C$의 온도범위에서 소결하여 제조된 유리-세라믹 복합체의 소결수축율은 글래스 프릿의 함량이 증가함에 따라 증가하였으며, 유전율은 10-40의 범위를 보였다.

• Advances in environmental research
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• 제5권3호
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• pp.189-200
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• 2016

This study aimed at advanced oxidation of hetero tri-functional reactive dye Acid orange 7 using photo-Fenton conditions in a lab-scale experiment. Decolourisation of Acid Orange 7 dye by Fenton's process was dependent on concentration of Hydrogen peroxide, Ferrous sulphate, pH, and contact time. A $2^3$ factorial design was used to evaluate the effects of these key factors: pH, Fe(II), and $H_2O_2$ concentration, for a dye concentration of 50 mg/L with COD of 340 mg/L at pH 3.0. The response function was removal of colour under optimised conditions; pH 3.0, [Fe(II)] 40.83 mg/L, [$H_2O_2$] 4.97 mmol/L; 13.6 min. of treatment resulting in 100% colour removal. The final COD of treated wastewater was nil suggesting that AOP is a potentially useful process of color removal and dye degradation/mineralisation of effluent having AO7. Minimum contact time for complete decolourisation was at 5 mmol/l $H_2O_2$ concentration. Increase in $FeSO_4$ (mg/l) concentration resulted in decrease of time for complete decolourisation. Box-Behnken Design was used to optimize the process variables. Maximum and minimum levels of pH (3-5), $H_2O_2$ (4-6 mmol/l), $FeSO_4$ (30-46 mg/l) and contact time (5-15 minutes) were used. The statistical analysis revealed a value of 0.88 for coefficient of regression ($R^2$) indicating a good fit of model. Calculated F-value was found higher than the tabulated value confirming to significance of the model. Based on student's t-test, Ferrous sulphate, pH, and contact time have a positive effect on the percent decolourisation of Acid Orange 7.

• 한국인터넷방송통신학회논문지
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• 제22권4호
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• pp.95-102
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• 2022

본 논문은 NP-완전으로 다항시간 알고리즘이 알려져 있지 않은 3-분할 문제(TPP)에 대한 선형시간 알고리즘을 제안하였다. 본 논문은 기존에 알려진 다항시간 알고리즘인 최대-최소치와 제3의 숫자 합을 이용하는 MM법이 갖고 있는 해를 구하지 못하는 문제점을 개선한 역추적 법을 제안하였으며, 또한 역추적 법을 적용한 MM의 문제점도 개선하였다. 제안된 알고리즘은 내림차순 정렬된 S 집합을 3-분할하여 순방향, 역방향과 최대 여유량 순서인 최적합 배정 법으로 배정한 결과 10개 데이터 중 5개 데이터인 50.00%에 대해서는 최적 해를 찾을 수 있었다. 나머지 5개 데이터에 대해서도 최소 1회, 최대 7회의 잉여 상자와 부족 상자 간 숫자 교환으로 최적 해를 찾을 수 있는 성능을 보였다. 제안된 알고리즘은 n개 데이터를 3-분할한 m=n/3 보다도 적은 O(k)의 선형시간 수행 복잡도로 단순 배정과 교환 최적화를 수행하는 알고리즘으로 TPP가 NP-완전이 아닌 P-문제인 다항시간 알고리즘이 존재할 수 있음을 보였다.