• Title/Summary/Keyword: P-Doped Silicon

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다공성 실리콘을 이용한 암호화된 광학이미지 제작 (Fabrication of Optically Encoded Images on Porous Silicon)

  • 고영대;김성진;김종현;류성옥;방현석;정윤식;박보경;손홍래
    • 한국진공학회지
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    • 제17권1호
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    • pp.46-50
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    • 2008
  • Febry-Perot 프린지 패턴의 광 반사성을 가지고 있는 다공성 실리콘을 이용하여 암호화된 광학 이미지를 제작하였다. 암호화된 광학이미지 다공성 실리콘 샘플은 p-type 실리콘 웨이퍼 (boron-doped,<100> orientation, resistivity $0.8{\sim}1.2m{\Omega}-cm$)를 이용하여 빔 프로젝트의 광원과 전기화학적 식각을 통하여 만들어 졌다. 광학 이미지 다공성 실리콘 샘플은 전기화학적 식각과정에 빔 프로젝트의 광원에 의하여 톡특한 Febry-Perot 프린지 패턴을 나타낸다. 실리콘 웨이퍼의 광 반사성의 프린지 패턴을 퓨리에 변환을 통하여 유효광학두께를 측정하고 실리콘웨이퍼에 암호화 시킨 광학이미지를 제작하였다.

Effect of Oxygen and Diborane Gas Ratio on P-type Amorphous Silicon Oxide films and Its Application to Amorphous Silicon Solar Cells

  • Park, Jin-Joo;Kim, Young-Kuk;Lee, Sun-Wha;Lee, Youn-Jung;Yi, Jun-Sin;Hussain, Shahzada Qamar;Balaji, Nagarajan
    • Transactions on Electrical and Electronic Materials
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    • 제13권4호
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    • pp.192-195
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    • 2012
  • We reported diborane ($B_2H_6$) doped wide bandgap hydrogenated amorphous silicon oxide (p-type a-SiOx:H) films prepared by using silane ($SiH_4$) hydrogen ($H_2$) and nitrous oxide ($N_2O$) in a radio frequency (RF) plasma enhanced chemical vapor deposition (PECVD) system. We improved the $E_{opt}$ and conductivity of p-type a-SiOx:H films with various $N_2O$ and $B_2H_6$ ratios and applied those films in regards to the a-Si thin film solar cells. For the single layer p-type a-SiOx:H films, we achieved an optical band gap energy ($E_{opt}$) of 1.91 and 1.99 eV, electrical conductivity of approximately $10^{-7}$ S/cm and activation energy ($E_a$) of 0.57 to 0.52 eV with various $N_2O$ and $B_2H_6$ ratios. We applied those films for the a-Si thin film solar cell and the current-voltage characteristics are as given as: $V_{oc}$ = 853 and 842 mV, $J_{sc}$ = 13.87 and 15.13 $mA/cm^2$. FF = 0.645 and 0.656 and ${\eta}$ = 7.54 and 8.36% with $B_2H_6$ ratios of 0.5 and 1% respectively.

X선 회절법을 이용한 $p^+$ 실리콘 내 잔류응력의 깊이 방향 분포 추정 (Determination of the Residual Stress Distribution along the Depth of Silicon by XRD $p^+$ Method)

  • 정옥찬;양의혁;양상식
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1995년도 추계학술대회 논문집 학회본부
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    • pp.593-595
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    • 1995
  • X-Ray Diffraction method that gives direct information about the deformation of crystal lattice is used for the determination of profiles of the residual stress along the depth of heavily boron doped silicon. The residual stress distribution is obtained by XRD method as measuring the deformation of the front surface of the $p^+$ silicon layer fabricated through different etch time. It is determined that the compressive residual stress exists in the most region except the font surface.

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A Study on Blister Formation and Electrical Characteristics with Varied Annealing Condition of P-doped Amorphous Silicon

  • 최성진;김가현;강민구;이정인;김동환;송희은
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.346.2-346.2
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    • 2016
  • The rear side contact recombination in the crystalline silicon solar cell could be reduced by back surface field. We formed polycrystalline silicon as a back surface field through crystallization of amorphous silicon. A thin silicon oxide applied to the passivation layer. We used quasi-steady-state photoconductance measurement to analyze electrical properties with various annealing condition. And, blister formed on surface of wafer during the annealing process. We observed the blister after varied annealing process with wafer of various surface. Shape and density of blister is influenced by various annealing temperature and process time. As the annealing temperature became higher, the average diameter of blister is decreased and total number of blister is increased. The sample with the $600^{\circ}C$ annealing temperature and 1 min annealing time exhibited the highest implied open circuit voltage and lifetime. We predicted that the various shape and density of blister affects the lifetime and implied open circuit voltage.

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Fabrication and Characterization of Optically Encoded Porous Silicon Smart Particles

  • Sohn, Honglae
    • 통합자연과학논문집
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    • 제7권4호
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    • pp.221-226
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    • 2014
  • Optically encoded porous silicon smart particles were successfully fabricated from the free-standing porous silicon thin films using ultrasono-method. DBR PSi was prepared by an electrochemical etch of heavily doped $p^{{+}{+}}$-type silicon wafer. DBR PSi was prepared by using a periodic pseudo-square wave current. The surface-modified DBR PSi was prepared by either thermal oxidation or thermal hydrosilylation. Free-standing DBR PSi films were generated by lift-off from the silicon wafer substrate using an electropolishing current. Free-standing DBR PSi films were ultrasonicated to create DBR-structured porous smart particles. Optical characteristics of porous smart particles were measured by FT-IR spectroscopy. The surface morphology of porous smart particles was determined by FE-SEM.

비정질 실리콘 박막의 알루미늄 직접 가열 유도 결정화 공정 (Direct-Aluminum-Heating-Induced Crystallization of Amorphous Silicon Thin Film)

  • 박지용;이대건;문승재
    • 대한기계학회논문집B
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    • 제36권10호
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    • pp.1019-1023
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    • 2012
  • 본 연구에서는 새로운 알루미늄 유도 결정화 공정을 제안하였다. 알루미늄 박막에 직접 3 A의 정전류를 인가하여 $1cm{\times}1cm$ 넓이의 두께 200 nm 비정질 실리콘 박막을 수십 초 내에 결정화하는 방법이다. 결정화된 다결정 실리콘 박막은 520 $cm^{-1}$ 에서의 라만 분광 피크를 통해 확인할 수 있었다. 공정 후, 알루미늄이 식각된 다결정 실리콘 박막은 다공성 구조임을 SEM 을 통하여 확인할 수 있었다. 또 한, 이차이온질량분석(secondary ion mass spectroscopy)에서 알루미늄 농도가 $10^{21}cm^{-3}$으로 헤비 도핑된 것을 확인 할 수 있었으며, 실시간으로 측정된 열화상 카메라의 결과를 통해 결정화는 820 K 근처에서 일어나는 것을 확인할 수 있었다.

Analysis of wet chemical tunnel oxide layer characteristics capped with phosphorous doped amorphous silicon for high efficiency crystalline Si solar cell application

  • Kang, Ji-yoon;Jeon, Minhan;Oh, Donghyun;Shim, Gyeongbae;Park, Cheolmin;Ahn, Shihyun;Balaji, Nagarajan;Yi, Junsin
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.406-406
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    • 2016
  • To get high efficiency n-type crystalline silicon solar cells, passivation is one of the key factor. Tunnel oxide (SiO2) reduce surface recombination as a passivation layer and it does not constrict the majority carrier flow. In this work, the passivation quality enhanced by different chemical solution such as HNO3, H2SO4:H2O2 and DI-water to make thin tunnel oxide layer on n-type crystalline silicon wafer and changes of characteristics by subsequent annealing process and firing process after phosphorus doped amorphous silicon (a-Si:H) deposition. The tunneling of carrier through oxide layer is checked through I-V measurement when the voltage is from -1 V to 1 V and interface state density also be calculated about $1{\times}1012cm-2eV-1$ using MIS (Metal-Insulator-Semiconductor) structure . Tunnel oxide produced by 68 wt% HNO3 for 5 min on $100^{\circ}C$, H2SO4:H2O2 for 5 min on $100^{\circ}C$ and DI-water for 60 min on $95^{\circ}C$. The oxide layer is measured thickness about 1.4~2.2 nm by spectral ellipsometry (SE) and properties as passivation layer by QSSPC (Quasi-Steady-state Photo Conductance). Tunnel oxide layer is capped with phosphorus doped amorphous silicon on both sides and additional annealing process improve lifetime from $3.25{\mu}s$ to $397{\mu}s$ and implied Voc from 544 mV to 690 mV after P-doped a-Si deposition, respectively. It will be expected that amorphous silicon is changed to poly silicon phase. Furthermore, lifetime and implied Voc were recovered by forming gas annealing (FGA) after firing process from $192{\mu}s$ to $786{\mu}s$. It is shown that the tunnel oxide layer is thermally stable.

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도우핑된 비정질 실리콘의 온도에 따른 광학적 특성 (Temperature Effects on the Optical Properties of Doped Amorphous Silicon)

  • 박진석;한민구;이정한
    • 대한전자공학회논문지
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    • 제23권4호
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    • pp.506-514
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    • 1986
  • Experimental results are reported concerning temperture effects from room temperature to 100\ulcorner on the optical properties of N-and P-type hydrogenated amorphous silicon films prepared by RF glow discharege. Optical absorption coefficient and optical bandgap have been measured and analyzed as a function of temperature. Optical absorption coefficient increase monotonically with temperature, while the optical bandgape of doped amorphous silicons decrease linearly by about 4-7x10**-4 [ev/k].

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위성체의 동력원으로서의 GaAs 태양전지 (GaAs solar cells for a satellite application)

  • 이승기;한민구
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1988년도 한국자동제어학술회의논문집(국내학술편); 한국전력공사연수원, 서울; 21-22 Oct. 1988
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    • pp.620-626
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    • 1988
  • GaAs solar cells may be the most attractive and efficient power source of a satellite. GaAs is more radiation tolerant and less temperature sensitive than widely used silicon. $Al_{x}$ Ga$_{1-x}$ As/GaAs solar cells have been designed and fabricated by Liquid Phase Epitaxial method. GaAs solar cells, of which structure is about 0.2 .mu.m p$^{+}$ - window layer, 0.6-1.O .mu.m Ge-doped p-layer. 3.mu.m n-GaAs layer and n$^{+}$ - buffer layer, have been characterized as a function of operating temperature from 25 .deg.C to 130 .deg.C. Open circuit voltage decreases linearly with increasing temperature by 1.4-1.51 mV/ .deg.C while degradation of silicon solar cells is about 2.2-2.5 mV/ .deg.C, short circuit current does not increase much with increasing temperature. Relative efficiency decreases with increasing of temperature by about 0.21-0.29 %/ .deg.C. Efficiency degradation of silicon solar cells with temperature is known to be about 0.5%/ .deg.C and our results show GaAs solar cells may be an excellent candidate for concentrated solar cells.ells.

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보론 도우핑된 비정질 실리콘을 이용한 쌍극 박막 트랜지스터의 전기적 특성 (Electrical Properties of Boron-Doped Amorphous Silicon Ambipolar Thin Film Transistor)

  • 추혜용;장진
    • 대한전자공학회논문지
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    • 제26권5호
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    • pp.38-45
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    • 1989
  • 보론이 100ppm으로 도우핑된 비정질 실리콘을 이용한 쌍극 박막 트랜지스터를 CVD 방법으로 제작하여 전기적 특성을 조사하였다. 쌍극 박막 트랜지스터에 인가한 트레인 전압이 증가하면 정공채널의 드레인 전류는 전자와 정공의 주입에 의해 크게 증가한다. 또한 게이트 전압의 인가 시간에 따른 드레인 전류는 streched exponential로 감소하는데, 이는 전자축적층에 의해 생기는 댕글린 본드 밀도의 변화가 수소의 확산과 동일한 시간 의존성을 갖는 것을 의미한다. 이러한 실험 결과로 부터 보론이 도우핑된 수소화된 비정질 실리콘에 게이트 전압을 인가하거나, 빛 조사시 도우핑 효율이 변화함을 알 수 있다.

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