• Title/Summary/Keyword: P&O

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The Effect of Initial pH and Dose of $TiO_2$ on Chloroform Removal in Photocatalytic Process using Compound Parabolic Concentrator Reactor System (CPCs를 이용한 $TiO_2$ 광촉매반응공정에서 초기 pH와 촉매농도가 클로로포름 분해에 미치는 영향)

  • Cho, Sang-Hyun;Cui, Mingcan;Nam, Sang-Geon;Jung, Hee-Suk;Khim, Jee-Hyeong
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.12
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    • pp.1147-1153
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    • 2010
  • To evaluate the solar photocatalytic degradation efficiency of chloroform in a real solar-light driven compound parabolic concentrators (CPCs) system, $TiO_2$ was irradiated with a metalhalide lamp (1000 W), which has a similar wavelength to sunlight. The results were applied to a pilot scale reactor system by converting the data to a standardized illumination time. In addition, the effects of initial pH and the $TiO_2$ dose on the photocatalytic degradation of chloroform were investigated. The results were compared with the specific surface area (S.S.A) and particle size of $TiO_2$, which changed according to the pH, to determine the relationship between the S.S.A, particle size and the photocatalytic degradation of chloroform. The experiment was carried out at pH 4~7 using 0.1, 0.2, 0.4 g/L of $TiO_2$. The particle size and specific surface area of $TiO_2$ were measured. There was no significant difference between the variables. However, pH affects the particle size distribution and specific surface area of $TiO_2$. Inaddition, the activation of a photocatalyst did not show a linear relationship with the specific surface area of $TiO_2$ in the photocatalytic degradation of chloroform.

Antimicrobial Activity of Flos Syzygii Aromatici Extracts against Mice Infected with Escherichia coli O157:H7 (Escherichia coli O157:H7에 감염된 마우스에 대한 정향 추출물의 항균효과)

  • Lee, Soo-Mi;Son, Song Ee;Lee, Hu Jang
    • Journal of Food Hygiene and Safety
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    • v.32 no.4
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    • pp.336-340
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    • 2017
  • The present study evaluated the antibacterial effect of Flos syzygii Aromatici methanolic extracts (FSAE). In addition, the effectiveness of FSAE against Escherichia coli O157:H7 infection was studied using ICR female mice. At 24 h after incubation of E. coli O157:H7, FSAE at the concentration of 0.269 (p < 0.05), 0.538 (p < 0.001) and 1.075 mg/mL (p < 0.001) significantly inhibited the growth of E. coli O157:H7 compared to the control group. After single challenge with E. coli O157:H7, forty female ICR mice were divided into four experimental groups which were orally administered with saline (control), 0.538 (group 1), 1.075 (group 2) and 2.15 mg/mL (group 3) of FSAE, respectively. On the 3rd day, the number of fecal E. coli O157:H7 in group 2 (p < 0.05) and group 3 (p < 0.01) was significantly decreased compared to that in the control group. On the 7th day post-treatment, the number of fecal E. coli O157:H7 in all FSAE-treated groups was significantly decreased compared to that in the control group (group 1, p < 0.05; group 2 and 3, p < 0.001). According to the results of the present study, administration of FSAE to mice can reduce the severity of E. coli O157:H7 infection. Therefore, the current study suggests that FSAE could be a good candidate for the treatment of enteric infections in domestic animals.

Effect of the Melting atmospheres for the $SnO_2-(1-x)P_2O_5-xR_2O_3$ Glass System (SnO-(1-x)$P_2O_5-xR_2O_3$ 계 유리에서 $R_2O_3$ 치환 및 용융분위기의 영향)

  • Lee, Young-Hun;Ji, Mi-Jung;Lee, Hong-Lim
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.206-207
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    • 2005
  • Display 소재로서 유전체나 격벽재 실링재로 사용되고 있는 frit는 PbO를 주성분으로 갖는 유리가 사용되고 있다. PbO 성분이 함유된(50$\sim$85%) 구성소재는 최근 RoHS 나 WEEE 등의 환경규제 실행에 직면해 있으며, 대체재료의 개발을 위한 많은 연구가 진행되고 있다 PbO 성분을 대체할 성분으로는 $Bi_2O_3$ 계, BaO-ZnO 계, $P_2O_5$ 계 등의 성분이 주요성분으로 이루어져 있으며, PbO 성분을 함유한 유리의 저융점, 저유전율, 고 투과율, 내산성, 내전압, 팽창계수 matching 등의 특성들에 부합되는 재료를 개발하기 위해 많은 노력을 기울이고 있다. 본 연구에서는 SnO-$P_2O_5$ 계 유리 조성을 선택하여 $R_2O_3$의 치환 및 용융분위기의 조절에 따른 저융점 유리로서의 특성과 효과에 대하여 고찰하였다.

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Crystallization and Conductivity of $CuO-P_{2}O_{5}-Nb_{2}O_{5}-V_{2}O_{5}$ Glasses ($CuO-P_{2}O_{5}-Nb_{2}O_{5}-V_{2}O_{5}$ 유리의 결정화와 전기전도도)

  • 손명모;이헌수;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.291-294
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    • 2000
  • The crystallization behavior and dc Conductivities of CuO-P$_2$O$_{5}$ -Nb$_2$O$_{5}$ -V$_2$O$_{5}$ glasses prepared by quenching on the copper plate were investigated. The conductivities of the glasses were range from 10$^{-5}$ s.$cm^{-1}$ / at room temperature, but the conductivities of the glass-ceramics were 10$^{-3}$ s.$cm^{-1}$ / increased by 10$^2$order. The crystalline product in the glass-ceramics was CuV$_2$O$_{6}$ . The linear relationship between in($\sigma$T) and T$^{-1}$ suggested that the electrical conduction in the present glass-ceramics would be due to a small polaron hopping mechanism.

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Flexible nanogenerators용 p-type Li:Cu2O 박막의 특성 연구

  • Jo, Gyeong-Su;Kim, Du-Hui;Jeong, Gwon-Beom;Na, Jeong-Hyo;Kim, Han-Gi
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.399.1-399.1
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    • 2016
  • p-type 반도체 물질로 알려진 $Cu_2O$에 Li 이온을 doping하면 Cu 이온 자리에 Li이온이 치환되어 p-type의 특성이 더욱 강하게 나타내는 것으로 알려져 있다. 이에 본 연구에서는 RF magnetron sputtering방법으로 성막한 p-type형 $Li:Cu_2O$박막의 특성을 연구하고 이를 $Li:Cu_2O-ZnO$ pn 접합 유연 나노제너레이터에 적용하였다. $Li:Cu_2O$ 성막시 $O_2$ 분압을 변수로 100nm 두께의 $Li:Cu_2O$ 박막을 성막하여 전기적, 광학적, 구조적, 표면 특성을 분석하였다. Hall measurement 측정 결과 $Li:Cu_2O$ 박막은 정공을 Major Carrier로 갖는 p-type 반도체임을 확인하였고, $O_2$의 분압이 증가할수록 Mobility 및 Carrier Concentration이 증가함을 확인하였다. 최적조건에서 광학적 투과도는 약 45%를 보였으며, 투과도를 통해 계산한 band gap은 약 2.03eV로써 일반적인 산화물 반도체의 작은 밴드갭을 가지고 있음을 알 수 있었다. 또한 Ellipsometer분석을 통해 $Ar:O_2$ 비가 $Li:Cu_2O$ 굴절률 및 흡광도에 미치는 영향을 연구하였으며, FE-SEM(Field Emission Scanning Electron Microscope)을 통해 표면을 분석하였다. 또한 XRD(X-ray diffractometer), TEM(Transmission Electron Microscope) 분석을 통하여 상온에서 성막한 $Li:Cu_2O$ 박막의 미세구조를 연구하였다. UPS(Ultraviolet Photoelectron Spectroscopy) 분석을 통해 일함수를 측정하였다. 이렇게 제작된 p 타입 $Li:Cu_2O$ 박막을 이용하여 $Li:Cu_2O-ZnO$ pn 접합을 구현하고 이를 이용해 유연 나노제너레이터를 제작하였다. 다양한 특성 분석을 통해p-type을 이용한 산화물 박막 기반 유연 나노 제너레이터 특성 향상 메커니즘을 제시하였다.

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Effects of Substituting B2O3 for P2O5 on the Structure and Properties of SnO-P2O5 Glass Systems (SnO-P2O5계 유리에서 P2O5를 B2O3로 치환시 구조와 물성에 미치는 영향)

  • Kim, Dong-Hwan;Hwang, Cha-Won;Kim, Nam-Jin;Im, Sang-Hyeok;Gwoo, Dong-Gun;Kim, Tae-Hee;Cha, Jae-Min;Ryu, Bong-Ki
    • Journal of the Korean Ceramic Society
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    • v.48 no.1
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    • pp.63-68
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    • 2011
  • The investigation is directed to lead free (Pb-free) frits that can be used for organic light emitting diode, plasma display screen devices and other sealing materials. $P_2O_5$-SnO system glasses have been prepared for Pb-free low temperature glass frit. Structure and properties of the glasses with the composition SnO-$xB_2O_3-(60-x)P_2O_5$ (x=0, 5, 10, 15, 20, 25, 30, 35, 40 mol%) were characterized by infrared spectra (IR), X-ray diffraction(XRD), Density, Molar volume, Thermo mechanical analysis(TMA) and weight loss after immersion test. Glass transition temperature($T_g$), dilatometric softening temperature($T_d$) and chemical durability increased, and coefficient of thermal expansion($\alpha$) decrease with the substitution of $B_2O_3$ for $P_2O_5$ in the range of 0~25 mol%.

Characteristics of Nano-Sized, α-2ZrO2·P2O5 Powder Prepared by Polyvinyl Alcohol Solution Method (Polyvinyl Alcohol 용액법에 의해 제조된 나노크기 α-2ZrO2·P2O5 분말의 특성 연구)

  • Ma, Chung-Il;Lee, Sang-Jin
    • Korean Journal of Materials Research
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    • v.27 no.4
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    • pp.179-183
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    • 2017
  • $2ZrO_2{\cdot}P_2O_5$ powder, which is not synthesized by solid reaction method, was successfully synthesized through PVA solution method. In this process, the firing temperature and the PVA content strongly affected the crystallization behavior and final particle size. A stable ${\alpha}$-phase $2ZrO_2{\cdot}P_2O_5$ was synthesized at a firing temperature of $1200^{\circ}C$ and holding time of 4 h. ${\beta}$-phase $2ZrO_2{\cdot}P_2O_5$ was observed, with un-reacted $ZrO_2$ phases, for firing temperatures lower than $1200^{\circ}C$. In terms of the PVA content effect, the powder prepared with a PVA mixing ratio of 12:1 showed stable ${\alpha}$-phase $2ZrO_2{\cdot}P_2O_5$; however, the ${\beta}$-phase was found to co-exist at relatively higher PVA content. The synthesized ${\alpha}$-phase $2ZrO_2{\cdot}P_2O_5$ powder showed an average particle size of 100~250 nm and an average thermal expansion coefficient of $-2.5{\times}10^{-6}/^{\circ}C$ in the range of room temp. ${\sim}800^{\circ}C$.

Time and Space Efficient Search with Suffix Arrays (접미사 배열을 이용한 시간과 공간 효율적인 검색)

  • Choi, Yong-Wook;Sim, Jeong-Seop;Park, Kun-Soo
    • Journal of KIISE:Computer Systems and Theory
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    • v.32 no.5
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    • pp.260-267
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    • 2005
  • To search efficiently a text T of length n for a pattern P over an alphabet 5, suffix trees and suffix arrays are widely used. In case of a large text, suffix arrays are preferred to suffix trees because suffix ways take less space than suffix trees. Recently, O(${\mid}P{\mid}{\codt}{\mid}{\Sigma}{\mid}$-time and O(${\mid}P{\mid}P{\cdot}log{\mid}{\Sigma}{\mid}$)-time search algorithms in suffix ways were developed. In this paper we present time and space efficient search algorithms in suffix arrays. One algorithm runs in O(${\mid}P{\mid}$) time using O($n{\cdot}{\mid}{\Sigma}{\mid}$)-bits space, and the other runs in O($n{\cdot}{\mid}{\Sigma}{\mid}$ time using O($nlog{\mid}{\Sigma}{\mid}+{\mid}{\Sigma}{\mid}{\cdot}$nlog log n/logn)-bits space, which is more space efficient and still fast. Experiments show that our algorithms are efficient in both time and space when compared to previous algorithms.

Relationship between the Micellization of TTAB and the Solubilization of p-Bromophenol in TTAB Solution (TTAB 용액에서 p-브로모페놀의 가용화와 TTAB의 미셀화와의 상관관계에 대한 연구)

  • Lee, Byung-Hwan
    • Journal of the Korean Chemical Society
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    • v.57 no.6
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    • pp.665-671
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    • 2013
  • The solubilization of p-bromophenol by the micellar system of TTAB(tetradecyltrimethylammonium bromide) and the micellization of TTAB were studied by the UV-vis spectrophotometric method simultaneously. And the effects of temperature on these properties have been measured for the thermodynamic study. The results show that the ${\Delta}G_s{^o}$ and ${\Delta}H_s{^o}$ values are negative and the ${\Delta}S_s{^o}$ values are positive for the solubilization of p-bromophenol within the measured range. On the other hand, the ${\Delta}G_m{^o}$ values are negative and the ${\Delta}H_m{^o}$ and ${\Delta}S_m{^o}$ values are positive for the micellization of TTAB. The effects of additives such as n-butanol and NaCl have been studied also for both properties and the relationship between these two properties has been also studied. From the results, we can postulate the solubilization site of p-bromophenol in the micelle.