• Title/Summary/Keyword: Ozone variation

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Intercomparison and evaluation of satellite-derived tropospheric ozone (인공위성을 이용한 대류권 오존 추정치 비교 및 검증)

  • Kim Jae-Hwan;Na Seon-Mi;M. J. Newchurch
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.123-124
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    • 2003
  • Fishman and Larson (1987) derived tropical tropospheric column ozone by subtracting stratospheric column ozone measured by the Stratospheric Aerosol and Gas Experiment (SAGE) from total column ozone obtained by the Total Ozone Mapping Spectrometer (TOMS). Later, the Convective Cloud Differential (CCD) method (Ziemke et al., 1998) indicated stratospheric ozone is invariant with longitude and concluded the zonal variation of total ozone determines the zonal variation of tropospheric ozone. (omitted)

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Synoptic Weather Patterns and Variation of Ozone Concentrations Association with High Ozone Days at Five Major Cities in Korea (고농도 오존이 발생하는 날의 종관 기상 패턴과 주요 5대 도시별 오존 농도 변화)

  • 김유라;윤일희;김희종
    • Journal of Environmental Science International
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    • v.10 no.6
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    • pp.437-444
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    • 2001
  • The characteristic features of surface ozone concentration and the forecasting procedure of high ozone days have been studied. The ozone concentration was continuously measured during 3 years (1997~1999) at air quality monitoring stations in five major cities in Korea. The diurnal variation of surface ozone concentration on high ozone days is characterized by low ozone concentration at night. The ozone concentration Increases continuously after sunrise, In reach a peak at 1500~1600 LST. Thereafter it decreases steadily to a low concentration at sunset. The diurnal and annual maximum of the surface ozone concentration at Seoul were observed in May and June, respectively. The favorable synoptic condition for the high ozone day is divided into 4 different synoptic weather patterns: a high-pressure system from the Sea of Okhotsk, the Pacific subtropical high extending westward, a moving high-pressure system covering the Korean peninsula. and a synoptic system In front of a typhoon. Most of high ozone days occur under the high pressure system in Korea.

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Monitoring and Long-term Trend of Total Column Ozone from Dobson Spectrophotometer in Seoul (1985~2017) (돕슨 분광광도계를 이용한 서울 상공의 오존층 감시 및 장기변화 경향(1985~2017))

  • Park, Sang Seo;Cho, Hi Ku;Koo, Ja-Ho;Lim, Hyunkwang;Lee, Hana;Kim, Jhoon;Lee, Yun Gon
    • Atmosphere
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    • v.29 no.1
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    • pp.13-20
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    • 2019
  • Since 1985, the Dobson Spectrophotometer has been operated at Yonsei University, and this instrument has monitored the daily representative total ozone in Seoul. Climatological value for total ozone in Seoul is updated by using the daily representative observation data from 1985 to 2017. After updating the daily representative total ozone data, seasonal and inter-annual variation of total ozone in Seoul is also estimated after calculating inter-comparison between ground (Dobson Spectrophotometer) and satellite [Total Ozone Mapping Spectrometer (TOMS) and Ozone Monitoring Instrument (OMI)] observations. The global average of total ozone measured by satellite is 297 DU, and its recent amount is about 3.5% lower than the global amount in 1980s. In Seoul, daily representative total ozone is ranged from 225 DU to 518 DU with longterm mean value of 324.3 DU. In addition, monthly mean total ozone is estimated from 290 DU (October) to 362 DU (March), and yearly average of total ozone have been continuously increased since 1985. For the long-term trend of total ozone in Seoul, this study is considered the seasonal variation, Solar Cycle, and Quasi-Biennial Oscillation. In addition to the natural oscillation effect, this study also considered to the long-term variation of sudden increase of total ozone due to the secondary ozone peak. By considering these natural effects, the long-term total ozone trends from 1985 to 2017 are estimated to be 1.11~1.46%/decade.

Characteristics of Ozone Generation by Diameter and Polarity Variation of Corona Wire Electrode (코로나 선전극의 직경과 극성변화에 따른 오존발생특성)

  • Jung, Jae-Seung;Kim, Jin-Gyu
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.26 no.5
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    • pp.85-90
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    • 2012
  • In this paper, it was investigated experimentally that diameter and polarity variation of corona wire electrode affected to ozone generation of the ozone generator using a wire-to-plate type electrode. The change in the diameter(D) of the corona wire electrode has a great effect upon ozone generation, higher influence appears in the positive corona discharge than the negative corona discharge. In the case of D=0.50[mm], maximum ozone generation and power efficiency could be obtained. However, in the case of smaller D than this, the ozone generation and efficiency decreases slowly and in the case of larger D, the ozone generation decreases rapidly. It means performance decline as an ozone generator. Therefore, ozone generation and power efficiency would increase through simple optimization of the corona electrode specification.

A Study on the Characteristics of Rural and Urban Surface Ozone Conentrations (청정지역과 도시지역의 오존농도 특성 연구)

  • 서명석;박경윤;이호근;장광미;강창희;허철구;김영준
    • Journal of Korean Society for Atmospheric Environment
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    • v.11 no.3
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    • pp.253-262
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    • 1995
  • A study has been performed on the characteristics of rural and urban surface ozone concentration for the period of March 1992 to February 1993. The monitoring station of rural ozone is located at Kosan, Cheju and other urban monitoring stations are located at Seoul, Pusan and Kwangju. Rural's and urban's ozone data exhibit a distinct features in many ways. First, annual mean of rural ozone concentration os very high(42 ppbv) but urban's are very low(10 .sim.15 ppbv). Second, rural ozone data shows a seasonal variation with it's maximum in spring, and minimum in summer, but urban's show a seasonal variation with it's maximum in spring, and minimum in winter. Third, diurnal variation of rural data is very small but that of urban's are very large. Fourth, urban's data are extremely low(< 3 ppbv) and have no seasonal variations.

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Characteristics of Diurnal Variation of the Atmospheric Pollutants Concentration in High-Ozone Episode day in Daegu (대구시 고농도 오존 사례일인 경우 대기 오염물질 농도의 일변화 특성)

  • 손임영;윤일희;김희종
    • Journal of Environmental Science International
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    • v.11 no.12
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    • pp.1253-1259
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    • 2002
  • This study analyzes the surface ozone, NO and $NO_2$ concentration data from 1997 to 1999 in Daegu. It investigates effect on precursor during high-ozone episode days. The high-ozone episode is defined when a daily maximum ozone concentration is higher than 100 ppb(ambient air quality standard of Korea) in at least one station among six air quality monitoring stations. The frequency of episodes is 13 days(33 hours). The frequency is the highest in May and September, and the area with the highest frequency is Nowondong and Manchondong. The average value of daily maximum ozone concentration with high ozone episode is 81.6 ppb, and that of 8-hour average ozone concentration is 58.6 ppb. It means that ozone pollution is continuous and wide-ranging in Daegu. The daily variation of NO, $NO_2$ and $O_3$ in high-ozone episodes are inversely proportional one another. Nowondong an industrial area, is affected by pollutants that are emitted from the primary sources, while Manchondong a residential area, is affected by the advection of $O_3$ or by the primary pollutants like VOCs.

Studies on the Behaviour of Ozone Concentration and the Influencing Factors (오존농도의 動態 및 影響因子에 關한 硏究)

  • 金旻永;姜熙坤;李完宗;李相七;張鳳勳;朴聖培
    • Journal of Korean Society for Atmospheric Environment
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    • v.5 no.2
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    • pp.55-71
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    • 1989
  • This study was carried out to determine the ozone concentration to behaviour and the factors to be influenced the variation of its concentration in the ambient air in Seoul. Measurements of ozone concentrations were made at 10 monitoring station to take care of SIHE (Seoul Institute of Health & Environment) during December 1987 to November 1988, also measured the hourly average concentration of sulfur dioxide, total suspended particulate, nitrogen oxide $(NO & NO_2)$, carbon monoxide, hydro carbon $(n-CH_4 & THC)$ and meteorological factors, that is, temperature, humidity, wind velocity wind direction and ultraviolet intensity etc, for the same period at same place. The basis of the data obtained were analyzed statistically along with the various data. The results were as follows; 1. The annually arithmetic mean concentration of ozone for the 10 sites during one years was 10.0 ppb and ranged from 3.1 $\pm$ 4.5ppb at the Kuro industrial complex to 17.2 $\pm$ 18.7 ppb at the Ssangmun site. 2. The frequency of hours on which oxidant concentrations exceeded the present short term standard of ozone (100 ppb) were 78 times. 3. The diurnal patterns of hourly ozone concentrations in Seoul area was a typical bi-modal variation which have 4 to 5 a.m. peak and 3. to 4 p.m peak. 4. The time ozone of highest ozone concentration in a whole day and hight was 1 to 5 p.m and 90.9 percent of appearence rate. 5. The diurnal patterns of hourly ozone concentrations in Seoul were on the whole the order of daytime from 5.8ppb to 28.7 ppb evening from 1.7 to 18.7 ppb night time from 1.9 to 9.3 ppb daybreak from 1.4ppb according to measuring sites, and the highest that observed at the Ssangmun area while the lowest was the Kuro industrial complex monitor sites. 6. The weekly variation of ozone concentration was the higher level ozone concentration in the day of the week occured sunday-monday and weekend but the decrease were observed from wednesday to thursday.

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Characteristics on the Variations of the Total Ozone over Pohang (1994-2004) using the Brewer Spectrophotometer and TOMS

  • Hong Gi-Man;Choi Byoung-Cheol;Goo Tae-Young;Lim Jae-Chul;Lim Byung-Sook;Baek Moon-Hee
    • Proceedings of the KSRS Conference
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    • 2005.10a
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    • pp.388-391
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    • 2005
  • The characteristics of the total ozone variations measured by the ground-based Brewer Ozone Spectrophotometer and the Total Ozone Mapping Spectrometer (TOMS) over Pohang are statistically examined from January 1994 to December 2004. First of all, in the correlation analysis of the total ozone measured from the Brewer Ozone Spectrophotometer and the TOMS, the correlation coefficient was 0.88 and the used data were 2190. The annual mean value of the total ozone is 311 DU with the standard deviation of 13 DU. The maximum and the minimum value were found in March (343 DU) and in September (282 DU), respectively. It was also revealed that the longest seasonal variation is in Spring (341 DU) and the smallest is in Autumn (283 DU). The time series data of the total ozone indicates that the annual variation is significant and the variations for three months and six months are relatively weak. Finally, the annual mean total ozones in Pohang (Brewer), Seoul (Brewer) and Busan (TOMS) are 312 DU, 324 DU and 304 DU, respectively.

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A fundamental study on ozone oxidation of humic substances (휴믹물질의 오존산화에 관한 기초연구)

  • 김은호;김영웅;손희종;장성호
    • Journal of environmental and Sanitary engineering
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    • v.14 no.3
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    • pp.10-21
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    • 1999
  • The purpose of study were to research the characteristics of water variation adding humic acids to distilled water after ozonation. Upon investigating pH variation with contact time after providing distilled water+air, distilled water+ozone and distilled water-humic acid-air in reactor, it reduced after 60 minute in inletting air and in spite of short contact time did suddenly in inletting ozone. TOC and UV-254 continued to increase with contact time of ozone and humic acids. $NH^{4+}-N$ did slowly increase or decrease after constant contact time of ozone, because $NH^{4+}-N$ was converted into $No^3-N$ by ozone. T-N did suddenly increase after 90minute, but T-P did rarely fluctuate for total experiment. Total 30 species of organic matter were detected by GS/MSD, but 14 species did really tend to increase except for matter identified in distilled water and blank test. Humic acids generated $aliphatic{\cdot}aromatic$ hydrocarbon, alcohol and amine etc., and did various matters without inflow course of contaminants.

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Trend Analysis for Stratospheric Ozone Concentration in the Middle Latitude Northern Hemisphere Using HALOE Data (HALOE 자료를 이용한 중위도 지역의 오존농도 추이분석)

  • Ka, Soo-Hyun;Kwon, Mi-Ra;Oh, Jung-Jin
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.4
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    • pp.413-422
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    • 2005
  • The ozone concentration measured by HALOE (Ver 19) from Oct. 1991 to Dec. 2003 is used for analyzing the variation of ozone concentration. The HALOE loaded in UARS is observing several gases in the atmosphere, from 10km to 80km. Fourier analysis of these data in the middle latitude northern hemisphere is reported in this paper. To detect any possible long term trends, the fourier transformed time series was back transformed after removing signals with time periods of less than 6 months. Although the results clearly show the strong annual cycle, it is difficult to show any long term trends from the fourier series. We also compared the ozone volume mixing ratio's from HALOE with that from the ground-based radiometry to evaluate the accuracy of microwave observation at Sookmyung Women's University.