• 한국지하수토양환경학회지:지하수토양환경
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• 제15권2호
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• pp.34-39
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• 2010

In this study, the remediation of diesel contaminated soil was attempted with ozone treatment and Fenton reaction. About 10% of initial diesel concentration was removed by the ozone saturated solution. The pseudo-first order decomposition constant of diesel contaminated soil in the presence of 5% of hydrogen peroxide with 1.82, 2.82, 4.82, 6.82, and 11.82% of iron contents was 0.0228, 0.0308, 0.0482, 0.0471, and 0.0592 $min^{-1}$ respectively. The decomposition constant of the diesel was 0.0064 $min^{-1}$ with the addition of ozone saturated solution only. On the addition of ozone saturated solution in the presence of 5% hydrogen peroxide and 5% iron, the decomposition constant of the diesel was 0.0850 $min^{-1}$. These results indicated that the decomposition rate was 190% faster than without the addition of ozone saturated solution. Thus, the application of both ozone and the fenton reaction is promising for the remediation of the diesel contaminated soil.

• 한국염색가공학회지
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• 제30권1호
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• pp.51-61
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• 2018

In this study, effluent water was produced through Submerged Membrane Bio-Reactor(SMBR) process, which is a simple system and decomposes organic matter contained in wastewater with biological treatment process and performs solid-liquid separation, Especially, ozone oxidation treatment process is applied to effluent water containing fluorescent whitening agent, which is a trace pollutant which is not removed by biological treatment, and influences the quality of reused water. The concentration of $COD_{Cr}$ in the SMBR was $449.3mg/{\ell}-COD_{Cr}$, and the concentration of permeate water was $100.3mg/{\ell}-COD_{Cr}$. The removal efficiency was about 70.1%. The amount of ozone required for the removal of the fluorescent whitening agent in the permeated water in SMBR was $6.67g-O_3/min$, and the amount of ozone required to remove $COD_{Mn}$ relative to the permeate water was calculated to remove $0.997mg-COD_{Mn}$ for 1mg of $O_3$.

• Asian-Australasian Journal of Animal Sciences
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• 제32권6호
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• pp.874-880
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• 2019

Objective: Ozone is considered a strong antimicrobial agent with numerous potential applications in the food industry. However, its high oxidizing potential can induce alterations in foods by acting on the unsaturated fatty acids. The aim of this study was to investigate the effect of ozonation on the oxidative stability of chicken breast meat obtained from animals subjected to different feeding strategies. Methods: Samples were obtained from commercial hybrid chickens (ROSS 508), some of which were nourished with a feed enriched with fats of animal origin, while the lipid source was vegetal for the remaining birds. Samples of meat belonging to both groups were treated with ozone and then analysis was performed to evaluate alterations in physical properties, lipid content, fatty acid profile, and oxidation stability. Results: Ozone induced a significant reduction in drip loss in meat samples obtained from animals nourished with vegetable fats; this nutritional strategy also produced meats leaner and richer in polyunsaturated fatty acids. Thiobarbituric acid reactive substances, useful for the assessment of lipid oxidation, were higher in samples obtained from animals fed with vegetable fats with respect to diet based on the addition of animal fats. Conclusion: The ozone treatment improved the physical parameters of meat samples obtained from animals fed with vegetable fats, however the same samples showed a higher lipid oxidation compared to what observed in the case of the dietary intake of animal fats, probably as a consequence of the marked increase in polyunsaturated fatty acids which are more susceptible to peroxidation.

• Environmental Engineering Research
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• 제16권2호
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• pp.97-102
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• 2011

This study investigates the treatment of pigment wastewater using a sequential batch reactor (SBR) followed by dissolved ozone flotation-pressurized ozone oxidation treatement (DOF-$PO_2$). The process efficiency has been evaluated at the lab scale on the basis of water quality parameters. In addition, the effect of pure oxygen and air was investigated on the removal of COD, BOD, and TN in the SBR process. It was observed that under comparable conditions the removal efficiencies of these water quality parameters using pure oxygen and air were similar. The effect of the recycle rate was also investigated for its impact on the water quality parameters using different ozone dissolving pressures in a DOF process in order to optimise conditions. The results conclude that the use of an SBR and ozone contact by DOF-$PO_2$ is a highly effective treatment for pigment wastewater and aids in the achievement of effluent discharge criteria.

• 한국환경보건학회지
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• 제35권6호
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• pp.532-537
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• 2009

The tropospheric ozone production mechanism for the gas phase additive oxidation reaction of hydroxyl radical (OH) with isoprene (2-methyl-1,3-butadiene) has been studied using cavity ring-down spectroscopy (CRDS) at total pressure of 50 Torr and 298 K. The applicability of CRDS was confirmed by monitoring the shorter (~4%) ringdown time in the presence of hydroxyl radical than the ring-down time without the photolysis of hydrogen peroxide. The reaction rate constant, $(9.8{\pm}0.1){\times}10^{-11}molecule^{-1}cm^3s^{-1}$, for the addition of OH to isoprene is in good agreement with previous studies. In the presence of $O_2$ and NO, hydroxyl radical cycling has been monitored and the simulation using the recommended elementary reaction rate constants as the basis to OH cycling curve gives reasonable fit to the data.

• 산업기술연구
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• 제27권A호
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• pp.25-29
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• 2007

Ozone alone, Ozone/GAC, Ozone/$H_2O_2$ and Ozone/GAC/$H_2O_2$ processes were introduced for treatment of humic acid, which is a representative refractory organic compound. $H_2O_2$ and GAC used as catalysts for experiment. The treatment efficiencies of humic acid in each process were analyzed for pH variation, DOC removal, and $UV_{254}$ decrease. $UV_{254}$ decrease in Ozone/GAC and Ozone/GAC/$H_2O_2$ processes were the highest with about 93%, and Ozone alone and Ozone/$H_2O_2$ processes were 88%. DOC removal in Ozone/GAC/$H_2O_2$ process was the highest with 71%. Removal by Ozone/GAC, Ozone alone, and Ozone/$H_2O_2$ processes were 66%, 39%, and 47%, respectively.

• 한국토양환경학회지
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• 제5권3호
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• pp.3-15
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• 2001

본 연구에서는 증류수와 인공지하수, 그리고 지하수를 대상으로 오존의 분해거동(오존의 자가분해, pH의 영향, 용해도)과 오존산화공정에 의한 디젤의 분해(디젤의 분해, TCE와 PCE의 분해, 수산화라디칼 scavenger의 영향, pH의 영향, 오존/과산화수소의 영향)를 조사하였다. 증류수와 지하수내에서 오존의 자가분해는 모두 2차 반응속도식을 보였고, 증류수(반감기 37.5 분)에서보다 지하수(반감기 14.7분)에서 훨씬 빠르게 오존이 분해되었으며, 알칼리성 조건하에서 두 액상에서 모두 오존의 분해는 촉진되었다. 또한 오존산화공정의 사용은 TCE와 PCE, 그리고 디젤에 대해 높은 산화처리속도를 나타내었다. 비록 지하수내에 존재하는 hydroxyl radical scavenger는 디젤의 분해에서 억제제로 작용하였지만, 높은 pH조건과 과산화수소의 첨가는 지하수내에서 디젤을 분해시키는 데 중요한 촉진제로서 작용하였다. 그러므로 오존산화공정은 디젤로 오염된 지하수를 처리하는 데 효과적으로 적용될 것이라 판단된다.

• 한국염색가공학회지
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• 제19권3호
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• pp.26-36
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• 2007

This study was carried out to treat the aqueous solutions containing reactive dyes(RB19, RR120 and RY179) by the Ozone demand flask method and adsorption process using activated carbon fiber(ACF) which are one of the main pollutants in dye wastewater. Ozone oxidation of three kinds of the reactive dyes was examined to investigate the reactivity of dyes with ozone, competition reaction and ozone utilization on various conditions for single- and multi-solute dye solution. Concentration of dyes was decreased continuously with increasing ozone dosage in the single-solute dye solutions. Competition quotient values were calculated to investigate the preferential oxidation of individual dyes in multi-solute dye solutions. Competition quotients(CQi) and values of the overall utilization efficiency, ${\eta}O_3$, were increased at 40mg/l of ozone dosage in multi-solute dye solutions. ACF(A-15) has much larger specific surface area$(1,584m^2/g-ACF)$ in comparison with granular activated carbon adsorbent (F400, $1,125m^2/g-GAC$), which is commonly used, and most of pores were found to be micropores with pore radius of 2nm and below. It was found that RB19 was most easily adsorbed among the dyes in this study. In the case of PCP (p-chlorophenol) and sucrose, which are single component adsorbate, adsorption capacities of ACF(A-15) were in good agreement with the batch adsorption measurement, and saturation time predicted of ACF columns for these components was also well agreed with practically measured time. But in the case of reactive dyes, which have relatively high molecular weight and aggregated with multi-components, adsorption capacities or saturation time predicted were not agreed with practically measured values.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 제5회 학술대회 논문집 일렉트렛트 및 응용기술연구회
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• pp.25-28
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• 2003

Ozone is a strong and useful oxidizing gas for the fabrication of oxide thin films. In order to obtain high quality oxide thin films, higher ozone concentration is necessary. In this paper an ozone condensation system was evaluated from the viewpoint of an ozone supplier for oxide thin film growth. Ozone was condensed by an adsorption method and the ozone concentration reached 8.5 mol% in 2.5 h after the beginning of the ozone condensation process, indicating high effectiveness of the condensation process. Ozone was continuously desorbed from the silica gel by the negative pressure. We found the decomposition in the ozone concentration negligible if the condensed ozone is transferred from the ozone condensation system to the film growth chamber within a few minutes.

• 환경위생공학
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• 제6권1호
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• pp.103-108
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• 1991

Visibility studies are conducted in oxidizing organic compounds with ozone to investigate the oxidation in the waste and sewage water. While the ozone has been used as one of the major oxidation of the waste and sewage water, it is not effective to distroy the polluted organic compounds with the practical concentration in waste water treatment. The result are shown follows ; 1. Upon oxidizing organic compound with ozone, the former is much oxidized under three meters and the latter under the ABS waste water. 2. In case of being oxidized organics waste water with ozone codis, much removed under medicine and chemical waste water than anothers of primary treatment process. 3. The final treated waste water of oxidizing organics is higher than that of filtered water or sedimented water. Specially in organics waste water the colority after oxidizing decrease from 95% to 99.9% this suggests that any organic compounds produced during ozonation night be dissdved in the final treated waste water.