• International Journal of Automotive Technology
• /
• v.6 no.3
• /
• pp.197-203
• /
• 2005

This paper investigates the effect of oxygen composition in mixed fuel on the exhaust emissions for the direct injection diesel engine. These effects were tested to estimate the change in engine performance and exhaust emission characteristics when commercial diesel fuel and oxygenates blended fuels at a certain fuel and mixed ratio are used. Individual hydrocarbons $(C_1-C_6)$ in exhaust gases, as well as the total amount of hydrocarbons, were analyzed by using gas chromatography to find the mechanism by which smoke emission was remarkably reduced for various oxygenated fuels. The chromatograms between a diesel fuel and a diesel fuel blended DGM (diethylene glycol dimethyl ether), MTBE (methyl tert-butyl ether) and EGBE (ethylene glycol mono-n-butyl ether) were compared. The results showed that the number of individual hydrocarbons as well as the total number of hydrocarbons of oxygenated fuel reduced more remarkably than those of diesel fuel.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.10 no.3
• /
• pp.101-110
• /
• 2002

In this paper, the effects of oxygen component in blended fuel on the exhaust emissions have been investigated far direct injection diesel engine. It was tested to estimate change of engine performance and exhaust emission characteristics for th? commercial diesel fuel and oxygenated blended fuels which have three kinds of fuels and various mixed rates. And, it was tried to analyze not only total hydrocarbon but individual hydrocarbons(C$_1$∼ C$\_$6/) in exhaust gases using gas chromatography to seek the reason far remarkable reduction of smoke emission on various oxygenated fuels. This study carried out by comparing the chromatogram with diesel fuel and diesel fuel blended DGM(diethylene glycol dimethyl ether), MTBE(methyl tart-butyl ether) and EGBE(ethylene glycol mono-n-butyl ether). The results of this study show that individual hydrocarbons as well as total hydrocarbon of oxygenated fuel are reduced remarkably compared with commercial diesel fuel.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.11 no.1
• /
• pp.79-86
• /
• 2003

In this paper, the effect of oxygen component in fuel on the exhaust emissions has been investigated fur direct injection diesel engine. It was tested to estimate change of engine performance and exhaust emission characteristics for the commercial diesel fuel and oxygenated blended fuel which has seven kinds of mixed ratio. And, the effects of exhaust gas recirculation(EGR) on the characteristics of NOx emission have been investigated. Ethylene glycol mono-n-butyl ether(EGBE) contains oxygen component 27% in itself, and it is a kind of effective oxygenated fuel of mono-ether group that the smoke emission and unburned hydrocarbons of EGBE is reduced remarkably compared with commercial diesel fuel, that is, it can supply oxygen component sufficiently at higher loads and speeds in diesel engine. It was found that simultaneous reduction of smoke and NOx was achieved with oxygenated fuel and cooled EGR method.

• Journal of the korean Society of Automotive Engineers
• /
• v.13 no.5
• /
• pp.89-94
• /
• 1991

In the quantitative analysis of oxygenated exhaust emissions (unburned methanol, formal- dehyde) from methanol fueled vehicles, the oxygen contained in oxygenated exhaust gases lowers the FID (Flame Ionization Detector) response factor of conventional THC analyzer and leads to erroneous HC reading. For correct measurement of various HCs including oxygenated HCs emitted from FFV(Flexible Fuel Vehicle), first of all, the measurement technique of real HC emissions should be established. GC and HPLC-DNPH measuring methods specified by the EPA are used in this paper to analyze unburned methanol and formaldehyde components in the exhaust emissions. In emission test of FFV, unburned methanol and formaldehyde are emitted mostly during cold transient period, and it is shown that formaldehyde emission level is proportional to engine displacements. In view of the HC emission level, vehicle using M85 has 40% advantage over gasoline-fueled vehicle in OMHCE and has a good potential of a low emission vehicle.

• Applied Biological Chemistry
• /
• v.34 no.4
• /
• pp.312-317
• /
• 1991

The volatile components of Korean and Chinese Inulae flos were identified. It is made of dried Inulae flos from the components were collected by simultaneous steam distillation extract method. Those were analyzed by combined gas chromatography(GC) and gas chromatography-mass spectrometrt(GC/MS). Sixty two components, including 10 hydrocarbons, 7 aldehydes, 18 alcohols, 3 ketones, 5 esters, 13 acids and 6 miscellaneous components were identified. Volatile components in Inulae flos were fractinated into one hydrocarbon fraction and two oxygenated hydrocarbon fractions by using silica gel column chromatography. The volatile components consisted of 16.85% hydrocarbon and 83.15% oxygenated hydrocarbons in Korean Inulae flos, 23.46% hydrocarbon and 76.53% oxygenated hydrocarbons in Chinese Inulae flos.

• Applied Biological Chemistry
• /
• v.37 no.1
• /
• pp.1-8
• /
• 1994

This study was carried out to investigate the changes in volatile constituents concerning with the flavor of the green ginger (Zingiber officinale Roscoe) during storage in underground pit ($15^{\circ}C$, RH 95%). And the constituents of essential oil of etiolated shoots formed on the mother rhizomes during the five months storage in the dark under same conditions were compared with those of mother rhizomes. The essential oils of Korean domestic ginger (Bong-dong cultivar) were isolated by simultaneous steam distillation and extraction method (SDE). Then the compositions of the essential oils were analysed by GC and GC-MS spectrometry. The major compounds of essential oil from the fresh rhizomes were zingiberene, $citronellol+{\beta}-sesquiphellandrene$, ${\beta}-phellandrene$, camphene, geranial, ${\gamma}-bisabolene$, ar-curcumene+geranyl acetate, ${\alpha}-pinene$, ${\beta}-gurjunene$, limonene and neral. The content of monoterpene hydrocarbons increased with a concomitant lowering in the amounts of sesquiterpene hrdrocarbons and oxygenated sesquiterpenes during storage of rhizomes although contents of the oxygenated monoterpens changed little or slightly during the storage. During the storage the content of such monoterpenes as camphene, ${\beta}-phellandrene$ and citral (neral and geranial) increased whereas the content of such sesquiterpenes as zingiberene and $citronellol+{\beta}-sesquiphellandrene$ decreased. The composition of shoot oil differed from that of mother rhizome oil in having higher content of terpene hydrocarbons and also in the higher content of bornyl acetate, ${\beta}-gurjunene$ and ar-curcumene+geranyl acetate and lower in citral (neral and geranial).

• Transactions of the Korean Society of Automotive Engineers
• /
• v.11 no.3
• /
• pp.85-91
• /
• 2003

In this study, the potential possibility of oxygenated fuel such as Methyl tertiary butyl ether (MTBE) was investigated for the sake of exhausted smoke reduction from diesel engine. MTBE has been used as a fuel additive blended into unleaded gasoline to improve octane number, but the study of application for diesel engine was incomplete. Because MTBE includes oxygen content approximately 18%, it is a kind of oxygenated fuel that the smoke emission of MTBE is reduced remarkably compared with commercial diesel fuel. But, the NOx emission of MTBE blended fuel is increased compared with commercial diesel fuel. And, it was tried to analyze not only total hydrocarbon but individual hydrocarbon components from $C_1$ to $C_6$ in exhaust gas using gas chromatography to seek the reason for remarkable reduction of smoke emission. Individual hydrocarbons($C_1$~$C_6$) as well as total hydrocarbon of oxygenated fuel are reduced remarkably compared with diesel fuel. And, the effects of exhaust gas recirculation(EGR) on the characteristics of NOx emission has been investigated, too. It was found that simultaneous reduction of smoke and NOx was achieved with oxygenated fuel and cooled EGR method.

• Applied Biological Chemistry
• /
• v.41 no.1
• /
• pp.84-88
• /
• 1998

Composition of volatile flavor components of chestnut flower sand honey were investigated by GC and GC-MS. A total of 64 components including 14 aromatic compounds, 13 hydrocarbons, 7 fatty acids, 4 terpenes, 12 oxygenated hydrocarbons, and 7 misellaneous compounds and a total 41 components including 7 aromatic compounds, 16 hydrocarbons, 12 fatty acids, 1 terpene, 2 oxygenated hydrocarbons, and 3 misellaneous compounds were identified from total volatile concentrates of chestnut flower and honey respectively. The main components of flower volatile were 2-phenyl ethyl alcohol, 1-phenyl ethyl alcohol and benzyl alcohol which comprise 49.02% of this volatiles The main components of flower volatile were 2-phenyl ethyl alcohol, 1-phenyl ethyl alcohol and benzyl alcohol which comprise 49.02% of this volatiles. Aromatic compounds such as 2-phenyl ethyl alcohol, benzyl alcohol, 1-phenyl ethyl alcohol, 1-(2-aminophenyl) ethanone act as major contributor to the characteristic honey-like flavor of chestnut honey.

• Korean journal of food and cookery science
• /
• v.26 no.6
• /
• pp.840-847
• /
• 2010

In this study, we identified the volatile compounds of Artemisia princeps Pampan. cv. ssajuari (ssajuarissuk) essential oils and analyzed changes in the contents of volatile compounds under four different storage conditions, such as exposure to air at $20^{\circ}C$ and $40^{\circ}C$. Sixty-five volatile compounds consisting of 6 monoterpene hydrocarbons, 23 oxygenated monoterpenes, 16 sesquiterpene hydrocarbons, 6 oxygenated sesquiterpenes, 1 diterpene, 6 benzene derivatives, and 7 non-isoprenoid compounds were identified on the basis of their mass spectra characteristics and retention indices from original ssajuarissuk essential oils. Identified compounds constituted 90.56% of the total peak area. Borneol (10.29%) was the most abundant compound in the original ssajuarissuk essential oils, followed by 1,8-cineole (9.06%), viridiflorol (8.99%), spathulenol (8.73%), $\alpha$-thujone (5.28%), and camphor (4.39%). After six months storage at $40^{\circ}C$ with the cap opened for 3 min everyday, the total amount of volatile compounds in essential oil as determined by the percentage peak area decreased by 84.93%. The total levels of cis-sabinene hydrate, camphor, 4-terpineol, humulene oxide, $\beta$-caryophyllene oxide, and caryophyllene alcohol increased significantly. For ssajuarissuk essential oils stored under experimental conditions, changes in the contents of volatile compounds in essential oils were accelerated by temperature and contact with the atmosphere.

• Applied Biological Chemistry
• /
• v.45 no.2
• /
• pp.101-107
• /
• 2002

The essential oils isolated from leaves, flowers, stems, and fruits of Vitex rotundifolia by steam distillation and extraction (SDE) method were analyzed by gas chromatography (GC) and gas chromatography-mass spectrometry (GC-MS). A total of 76 components detected by GC, 42 components were identified positively by GC-MS and GC co-injection with authentic standards, and 34 components were identified tentatively by mass spectral data only. They included 16 monoterpene hydrocarbons, 30 oxygenated hydrocarbons, 10 sesquiterpene hydrocarbons, 8 oxygenated sesquiterpenes, 3 diterpenes, and 9 miscellaneous components. The major components in the oil from the leaves were ${\alpha}-pinene$ (30.25%), 1,8-cineole (19.89%), sabinene (9.56%), ${\alpha}-terpineol$ (7.94%), ${\beta}-pinene$ (5.69%), and terpinen-4-ol (2.37%), and those in the flower oil were ${\alpha}-pinene$ (25.47%), 1,8-cineole (7.69%), manoyl oxide (6.21%), ${\beta}-pinene$ (4.20%), ${\alpha}-te.pineol$ (3.76%), and sabinene (2.78%). The major components in the oil from the stems were ${\alpha}-pinene$ (13.24%), ${\alpha}-terpineol$ (10.64%), 1,8-cineole (4.40%), manoyl oxide (4.02%), ${\beta}-pinene$ (2.39%), and terpinen-4-ol (2.21%) while those in the oil from the fruits were ${\alpha}-pinene$ (20.24%), 1,8-cineole (11.47%), ${\beta}P-pinene$ (9.79%), ${\alpha}-terpineol$ (7.08%), sabinene (3.68%), and limonene (2.77%). The percentage composition of monoterpenes in the oils from the leaves and the fruits were higher than in those from the flowers and the stems, whereas the oil from the flowers and the stems were characterized by a large content of sesquiterpenes, diterpenes and other unknown high molecular weight components.