• 제목/요약/키워드: Oxygen membrane

검색결과 888건 처리시간 0.03초

고분자 전해질형 연료전지 자동차의 급기 시스템의 동적 모델링 및 분석 (Dyamic Modeling and Analysis of Air Supply System for Vehicular PEM Fuel Cell)

  • 장현탁
    • 한국수소및신에너지학회논문집
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    • 제15권3호
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    • pp.175-186
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    • 2004
  • In this paper, we developed the dynamic model of a fuel cell system suitable for controller design and system operation. The transient phenomena captured in the model include the flow characteristics and inertia dynamics of the compressor, the intake manifold filling dynamics, oxygen partial pressures and membrane humidity on the fuel cell voltage. In the simulations, we paid attention to the transient behavior of stack voltage and compressor pressure, stoichiometric ratio. Simulation results are presented to demonstrate the model capability. For load current following, stack voltage dynamic characteristics are plotted to understand the Electro-chemistry involved with the fuel cell system. Compressor pressure and stoichiometric ratio are strongly coupled, and independent parameters may interfere with each other, dynamic response, undershoot and overshoot.

Role of tea catechins in prevention of aging and age-related disorders

  • Khanna, Arjun;Maurya, Pawan Kumar
    • 셀메드
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    • 제2권1호
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    • pp.2.1-2.11
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    • 2012
  • Tea polyphenols especially catechins have long been studied for their antioxidant and radical scavenging properties. Scientists throughout the world have investigated the usefulness of the regular green tea consumption in several disease conditions. In-vitro and in-vivo experiments on catechins especially epigallocatechingallate have revealed a significant role in many ways. Reactive oxygen species have been increasingly implicated in the pathogenesis of many diseases and important biological processes. Toxic effects of these oxidants, commonly referred to as oxidative stress, can cause cellular damage by oxidizing nucleic acids, proteins, and membrane lipids. Oxidative stress has been related to aging and age related disorders. It is found that in a wide variety of pathological processes, including cancer, atherosclerosis, neurological degeneration, Alzheimer's disease, ageing and autoimmune disorders, oxidative stress has its implications. Catechins have been reported to be useful in combating aging and age related disorders like cancer, cardiovascular disorders and neurodegenerative diseases. In this mini review we will discuss such studies done across the globe.

Simultaneous Utilization of Two Different Pathways in Degradation of 2,4,6-Trinitrotoluene by White Rot Fungus Irpex lacteus

  • 김현영;송홍규
    • 미생물학회지
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    • 제38권4호
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    • pp.250-250
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    • 2002
  • This study confirmed that white rot fungus Irpex lacteus was able to metabolize 2,4,6-trinitrotoluene (TNT) with two different initial transformations. In one metabolic pathway of TNT a nitro group was removed from the aromatic ring of TNT. Hydride-Meisenheimer complexes of TNT (H/sup -/-TNT), colored dark redo were confirmed as the intermediate in this transformation by comparison with the synthetic compounds. 2,4-Dinitrotoluene as a following metabolic product was detected, and nitrite produced by denitration of $H^-$-TNT supported this transformation. In the other TNT pathway, nitro groups in TNT were successively reduced to amino groups via hydroxylamines. Hydroxylamino-dinitrotoluenes and amino-dinitrotoluenes were identified as the intermediates. The activity of a membrane-associated aromatic nitroreductase was detected in the cell-free extract of I. lacteus. This enzyme catalyzed the nitro group reduction of TNT with NADPH as a cofactor, Enzyme activity was not observed in the presence of molecular oxygen.

Xylene Induces Oxidative Stress and Mitochondria Damage in Isolated Human Lymphocytes

  • Salimi, Ahmad;Talatappe, Behnaz Shoja;Pourahmad, Jalal
    • Toxicological Research
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    • 제33권3호
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    • pp.233-238
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    • 2017
  • Xylene is a cyclic hydrocarbon and an environmental pollutant. It is also used in medical technology, paints, dyes, polishes and in many industries as a solvent; therefore, an understanding of the interaction between xylene and human lymphocytes is of significant interest. Biochemical assessment was used to demonstrate that exposure of lymphocytes to xylene induces cytotoxicity (at 6 hr), generates intracellular reactive oxygen species, collapse of mitochondrial membrane potential, lysosomal injury, lipid peroxidation and depletion of glutathione (at 3 hr). The findings show that xylene triggers oxidative stress and organelle damage in lymphocytes. The results of our study suggest that the use of antioxidant, mitochondrial and lysosomal protective agents can be helpful for individuals subject to chronic exposure to xylene.

모바일용 연료전지 개발 (The development of mobile fuel cell)

  • 이강인;박민수;조용훈;조윤환;성영은;주종남
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2006년도 춘계학술대회 논문집
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    • pp.549-550
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    • 2006
  • Mobile fuel cell is highlighted in these days because mobile fuel cell can contain more energy than existing batteries. Nowadays mobile devices like cellular phone, PMP(portable multi-media player), notebook, and etc. need more energy, But existing batteries like Li-ion or Ni-MH batteries are not going to satisfy such demands. In this paper, mobile fuel cell is developed. Its size is 50*70*8mm and it is made of aluminium plates. The fuel cell type is PEM and the fuel is pure hydrogen and oxygen.

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Feed Gas Dependent Nonthermal Plasma Interaction with Bio-organisms

  • Baik, Ku-Youn;Park, Gyung-Soon;Kim, Yong-Hee;Yoo, Young-Hyo;Lee, Jin-Young;Choi, Eun-Ha
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.174-174
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    • 2012
  • The nature of feed gas is essential for the active species formed in the nonthermal plasma jets, which would induce various biological phenomena. We investigated the different physiological effects of atmospheric pressure soft-plasma jets on Esherichia coli and blood cells according to the feed gas. Cell death rate, growth curve, membrane molecular changes and induced genes were examined. The relationship between cellular reactions and active species generated by discharge will be discussed.

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고순도 산소제조용 ITM 및 공정개발 (Development of ITM material and process for producing high purity oxygen)

  • 김종기;성부용;박정훈
    • 한국에너지공학회:학술대회논문집
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    • 한국에너지공학회 2003년도 춘계 학술발표회 논문집
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    • pp.365-369
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    • 2003
  • 이산화탄소 규제 대응 전략으로, 배출되는 온실가스를 분리, 회수, 처리하는 연구가 지속적으로 진행되고 있다. 현재 이산화탄소 저감 연구는 공정개발 초기부터 이산화탄소 배출을 방지하거나 분리하기 쉬운 형태로 설계하는 방식으로 전환되고 있다. 그 예로 고온 순산소 연소 시스템이 제안되었다. 이는 $CO_2$를 가장 효과적으로 저감시키는 방법 중의 하나로 연소에 사용되는 산화제로 순산소를 사용하여 원료를 절감할 수 있고 산소를 사용하기 때문에 배가스 중에 질소분율이 감소하여 배가스에 의한 현열손실을 줄일 수 있으며 또한 배가스 현열을 회수하여 산소를 고온으로 예열시켜 에너지를 추가적으로 절감할 수 있다. 이를 위해 산소를 선택적으로 투과시켜 고순도 산소를 제조할 수 있을 뿐만 아니라 산소제조 장치비를 절감할 수 있는 ITM (Ion Transport Membrane) 신소재 및 산소 투과 공정을 개발하고자 한다.

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First Principles Computational Study of Surface Reactions Toward Design Concepts of High Functional Electrocatalysts for Oxygen Reduction Reaction in a Fuel Cell System

  • Hwang, Jeemin;Noh, Seunghyo;Kang, Joonhee;Han, Byungchan
    • 한국표면공학회지
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    • 제50권1호
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    • pp.1-9
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    • 2017
  • Design of novel materials in renewable energy systems plays a key role in powering transportation vehicles and portable electronics. This review introduces the research work of first principles-based computational design for the materials over the last decade to accomplish the goal with less financial and temporal cost beyond the conventional approach, especially, focusing on electrocatalyst toward a proton exchange membrane fuel cell (PEMFC). It is proposed that the new method combined with experimental validation, can provide fundamental descriptors and mechanical understanding for optimal efficiency control of a whole system. Advancing these methods can even realize a computational platform of the materials genome, which can substantially reduce the time period from discovery to commercialization into markets of new materials.

2-Chloro-3-(p-carboxyanilino)-1, 4-naphthoquinone 유도체의 용혈기전에 관한 연구 (Studies on the hemolytic mechanism of the 2-Chloro-3-(p-carboxyanilino) -1, 4-naphthoquinone derivatives)

  • 최병기;조정희;배경아;정세영
    • Environmental Analysis Health and Toxicology
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    • 제8권3_4호
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    • pp.13-21
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    • 1993
  • In order to evaluate the anticancer activity of 1,4-naphthoquinone derivatives, several 1,4-naphthoquinone derivatives were newly synthesized and subjected to mouse leukemia p-388 cell line by MTT cytotoxicity assay. Among the several 1,4-naphtho-quinone derivatives, YC-001 has showed the most potent anticancer activity. To determine the safety of YC-001, hematotoxicity was tested. YC-001 induced hemolysis increased with both concentration and time dependent manner. The mechanism of hemolysis considered to be the generation of oxygen free radicals and lipid peroxydation of erythrocyte membrane which composed of phospholipids. Also methemoglobin, oxidized form of hemoglobin, was formed by YC-001.

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Fabrication and Evaluation of a New High-Temperature pH Sensor for Use in PWR Nuclear Power Plants

  • Jung, Yong-Ju;Yeon, Jei-Won
    • Bulletin of the Korean Chemical Society
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    • 제31권10호
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    • pp.2939-2942
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    • 2010
  • A new high-temperature pH sensor has been successfully developed by reforming the internal reference systems of the pH sensors based on oxygen-ion conducting ceramic membrane. The conventional internal reference system, a mixture of Ni and NiO, has been replaced with partially oxidized Ni powders, where Ni and NiO coexist on the surface of particles, in order to avoid the cumbersome mixing step of Ni and NiO particles. The partially oxidized Ni particles were made by oxidizing Ni under air atmosphere at $600^{\circ}C$ and characterized by X-ray diffraction (XRD) and FTIR spectroscopy. The viability of the pH sensor developed was assessed in boric acid (1000 ppm-B)/ lithium hydroxide (1 to 3 ppm-Li) buffer solutions at $280^{\circ}C$. The pH sensor showed excellent accuracy with a small error less than ${\pm}0.2$ pH units.