• 제목/요약/키워드: Oxygen gas ratio

검색결과 431건 처리시간 0.025초

매립지가스(LFG)로부터 합성가스 제조를 위한 개질반응 연구 (A Study on Reforming Reaction for Preparation of Synthesis Gas from Land-Fill Gas)

  • 조욱상;윤중섭;박성규;모용기;백영순
    • 한국수소및신에너지학회논문집
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    • 제25권6호
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    • pp.570-576
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    • 2014
  • LFG (Land-Fill Gas) includes components of $CH_4$, $CO_2$, $O_2$, $N_2$, and water. The preparation of synthesis gas from LFG as a DME (Dimethyl Ether) feedstock was studied by methane reforming of $CO_2$, $O_2$ and steam over NiO-MgO-$CeO_2$/$Al_2O_3$ catalyst. Our experiments were performed to investigate the effects of methane conversion and syngas ratio on the amount of LFG components over NiO-MgO-$CeO_2$/$Al_2O_3$ catalyst. Results were obtained through the activity reaction experiments at the temperature of $900^{\circ}C$ and GHSV of 4,000. The results were as following; it has generally shown that methane conversion rate increased with the increase of oxygen and carbon dioxide amounts. Highly methane conversion of 92~93% and syngas ratio of approximately 1.0 were obtained in the feed of gas composition flow-rate of 243ml/min of $CH_4$, 241ml/min of $CO_2$, 195ml/min of $O_2$, 48ml/min of $N_2$, and 360ml/min of water, respectively, under reactor pressure of 15 bar for 50 hrs of reaction time. Also, it was shown that catalyst deactivation by coke formation was reduced by excessively adding oxygen and steam as an oxidizer of the methane reforming.

Off-gas Column Test를 이용한 하수처리장 심층포기시스템의 산소전달 매개변수(α와 F)의 산정 (Evaluation of the Oxygen Transfer Parameters (α and F) of a Coarse Bubble Aeration System by Off-gas Column Test)

  • 김철웅;임세호;신동록;이지영;박재한;안윤희;고광백
    • 한국물환경학회지
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    • 제22권6호
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    • pp.1119-1122
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    • 2006
  • Aeration by using diffusers usually requires approximately 50~90% of the total electricity needed to operate WWTP (WasteWater Treatment Plant)s. Accurate evaluation of the oxygen transfer efficiency for an aeration system, and recommendation of a better alternative may help saving WWTP operational costs. Appropriate techniques and methods to achieve this purpose have not been introduced in Korea. In this study, in-process analysis was performed for a coarse bubble aeration system by the off-gas method to evaluate its applicability in Korea. To accomplish this analysis, an off-gas test, unsteady-state clean water test and steady-state off-gas column test was conducted and comparisons to other aeration systems were made. The ${\alpha}$ and the F estimated from the results of the unsteady-state clean water test and the steady-state off-gas column test were 0.61 and 0.90 respectively in a coarse bubble aeration system. The comparison of P.E tube diffusers laid out single spiral roll and ceramic dome diffusers laid out full floor coverage showed that the oxygen transfer efficiency of the coarse bubble aeration system was less than or similar to other aeration systems. But, airflow rates per unit area were 4~5 times greater than other aeration systems. In regards to the oxygen transfer efficiency for airflow rates per unit area, a retrofit to higher efficiency diffusers was urgently needed. This study showed proved that off-gas methods can apply to evaluate diffuser performances to estimate operating factors and to compare other aeration systems in Korea.

A Study on Effect of Intake Mixture Temperature upon Fuel Economy and Exhaust Emissions in Diesel Engines with a Scrubber EGR System

  • Bae, Myung--Whan;Ryu, Chang-Seong;Yoshihiro Mochimaru;Jeon, Hyo-Joong
    • Journal of Advanced Marine Engineering and Technology
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    • 제28권2호
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    • pp.315-331
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    • 2004
  • The effects of intake mixture temperature on performance and exhaust emissions under four kinds of engine loads were experimentally investigated by using a four-cycle. four-cylinder. swirl chamber type. water-cooled diesel engine with scrubber EGR system operating at three kinds of engine speeds. The purpose of this study is to develop the scrubber exhaust gas Recirculation (EGR) control system for reducing $\textrm{NO}_{x}$ and soot emissions simultaneously in diesel engines. The EGR system is used to reduce $\textrm{NO}_{x}$ emissions. And a novel diesel soot-removal device of cylinder-type scrubber with five water injection nozzles is specially designed and manufactured to reduce soot contents in the recirculated exhaust gas to the intake system of the engine. The influences of cooled EGR and water injection. however. would be included within those of scrubber EGR system. In order to survey the effects of cooled EGR and moisture on $\textrm{NO}_{x}$ and soot emissions. the intake mixtures of fresh air and recirculated exhaust gas are heated up using a heater with five heating coils equipped in a steel drum. It is found that intake and exhaust oxygen concentrations are decreased, especially at higher loads. as EGR rate and intake mixture temperature are increased at the same conditions of engine speed and load. and that $\textrm{NO}_{x}$ emissions are decreased. while soot emissions are increased owing to the decrease in intake and exhaust oxygen concentrations and the increase in equivalence ratio. Thus ond can conclude that $\textrm{NO}_{x}$ and soot emissions are considerably influenced by the cooled EGR.

플라즈마 실리콘 OXYNITRIDE막의 구조적 특성에 관한 고찰 (A Study on the Structure Properties of Plasma Silicon Oxynitride Film)

  • 성영권;이철진;최복길
    • 대한전기학회논문지
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    • 제41권5호
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    • pp.483-491
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    • 1992
  • Plasma silicon oxynitride film has been applied as a final passivation layer for semiconductor devices, because it has high resistance to humidity and prevents from alkali ion's penetration, and has low film stress. Structure properties of plasma silicon oxynitride film have been studied experimentally by the use of FT-IR, AES, stress gauge and ellipsometry. In this experiment,Si-N bonds increase as NS12TO/(NS12TO+NHS13T) gas ratio increases. Peaks of Si-N bond, Si-H bond and N-H bond were shifted to high wavenumber according to NS12TO/(NS12TO+NHS13T) gas ratio increase. Absorption peaks of Si-H bond were decreased by furnace anneal at 90$0^{\circ}C$. The atomic composition of film represents that oxygen atoms increase as NS12TO/(NS12TO+NHS13T) gas ratio increases, to the contrary, nitrogen atoms decrease.

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The Association between Mortality and the Oxygen Saturation and Fraction of Inhaled Oxygen in Patients Requiring Oxygen Therapy due to COVID-19-Associated Pneumonia

  • Choi, Keum-Ju;Hong, Hyo-Lim;Kim, Eun Jin
    • Tuberculosis and Respiratory Diseases
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    • 제84권2호
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    • pp.125-133
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    • 2021
  • Background: The coronavirus disease (COVID-19) can manifest in a range of symptoms, including both asymptomatic systems which appear nearly non-existent to the patient, all the way to the development of acute respiratory distress syndrome (ARDS). Specifically, COVID-19-associated pneumonia develops into ARDS due to the rapid progression of hypoxia, and although arterial blood gas analysis can assist in halting this deterioration, the current environment provided by the COVID-19 pandemic, which has led to an overall lack of medical resources or equipment, has made it difficult to administer such tests in a widespread manner. As a result, this study was conducted in order to determine whether the levels of oxygen saturation (SpO2) and the fraction of inhaled oxygen (FiO2) (SF ratio) can also serve as predictors of ARDS and the patient's risk of mortality. Methods: This was a retrospective cohort study conducted from February 2020 to Mary 2020, with the study's subjects consisting of COVID-19 pneumonia patients who had reached a state of deterioration that required the use of oxygen therapy. Of the 100 COVID-19 pneumonia cases, we compared 59 pneumonia patients who required oxygen therapy, divided into ARDS and non-ARDS pneumonia patients who required oxygen, and then investigated the different factors which affected their mortality. Results: At the time of admission, the ratios of SpO2, FiO2, and SF for the ARDS group differed significantly from those of the non-ARDS pneumonia support group who required oxygen (p<0.001). With respect to the predicting of the occurrence of ARDS, the SF ratio on admission and the SF ratio at exacerbation had an area under the curve which measured to be around 85.7% and 88.8% (p<0.001). Multivariate Cox regression analysis identified that the SF ratio at exacerbation (hazard ratio [HR], 0.916; 95% confidence interval [CI], 0.846-0.991; p=0.029) and National Early Warning Score (NEWS) (HR, 1.277; 95% CI, 1.010-1.615; p=0.041) were significant predictors of mortality. Conclusion: The SF ratio on admission and the SF ratio at exacerbation were strong predictors of the occurrence of ARDS, and the SF ratio at exacerbation and NEWS held a significant effect on mortality.

디스플레이용 ITO 투명전도막의 저온 제작 (Preparation of ITO Transparent Conductive thin film for Display at Room Temperature)

  • 김경환;김현웅
    • 반도체디스플레이기술학회지
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    • 제4권4호
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    • pp.5-8
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    • 2005
  • In this study, we prepared the ITO thin film for TOLED(Top-emitting OLED) or flexible display at room temperature using the FTS(Facing Targets Sputtering Apparatus). We observed characteristics of deposited thin films as a function of sputtering conditions. XRD patterns were independence trom oxygen gas flow and input current. But electrical and optical properties were strongly dependence. In the results, we could prepare good properties of ITO thin films resistivity of $4.27X10^{-4}[\Omega-cm]$, transmittance of over 80% at working gas pressure 1[mTorr], input current 0.6[A], oxygen gas ratio 0.3[sccm], at room temperature.

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축소형 가스발생기 연소시험에서의 유량계수 특성 (Discharge Coefficient Characteristics in Hot-firing Tests of a Subscale Gas Generator)

  • 김문기;임병직;강동혁;안규복;김종규;최환석
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2011년도 제36회 춘계학술대회논문집
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    • pp.73-76
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    • 2011
  • 축소형 가스발생기를 제작하여 연소시험을 성공적으로 수행하였으며 분사기의 형상 변화에 따른 유량계수의 영향을 파악하였다. 연소시험 결과 연료 및 산화제 분사기의 유량계수는 혼합비와 연소압에 상관없이 거의 일정하였으며, 특히 산화제 분사기의 유량계수는 이전 결과보다 크게 향상되었다.

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산소부화 압축착화기관을 이용한 메탄으로부터 수소 생산 (Hydrogen Gas Production from Methane Reforming Using Oxygen Enriched Compression Ignition Engine)

  • 임문섭;홍성인;홍명석;전영남
    • 한국대기환경학회지
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    • 제23권5호
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    • pp.557-562
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    • 2007
  • The purpose of this paper is to investigate the reforming characteristics and maximum operating condition for the hydrogen production by methane reforming using the compression ignition engine induced partial oxidation. An dedicated compression engine used for methane reforming was decided operating range. The partial oxidation reforming was investigated with oxygen enrichment which can improve hydrogen production, compared to general reforming. Parametric screening studies were achieved as $O_2/CH_4$ ratio, total flow rate, and intake temperature. When the variations of $O_2/CH_4$ ratio, total flow rate, and intake temperature were 1.24, 208.4 L/min, and $400^{\circ}C$, respectively, the maximum operating conditions were produced hydrogen and carbon monoxide. Under the condition mentioned above, synthetic gas were $H_2\;22.77{\sim}29.22%,\;CO\;21.11{\sim}23.59%$.

후열처리에 따른 Indium Zinc Oxide(IZO) 박막의 특성변화 (Effect of annealing on the properties of zinc doped indium oxide(IZO) films)

  • 김대현;김상모;최형욱;김경환
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.260-261
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    • 2008
  • In this study, we investigated the properties of Indium Zinc Oxide (IZO) films prepared in facing targets sputtering (FTS) system at room temperature as function of oxygen contents. As as-deposited films were rapidly thermal annealing on air atmosphere of $400^{\circ}C$ for 30s. As a result, the transmittance of IZO films increased with increasing oxygen flow in the visible range. After rapidly thermal annealing to films, the optical properties of films improved than films deposited at R.T, but the electrical properties decreased. Before RTA treatment, the lowest resistivity IZO is $5.4\times10^{-4}[\Omega{\cdot}cm]$ at oxygen gas flow. But, after RTA treatment, IZO films have the value of lowest resistivity at the lower oxygen gas ratio in compare with before RTA treatment. The resistivity of IZO films is $7.29\times10^{-4}[\Omega{\cdot}cm]$ at pure argon atmosphere.

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산소부화연소에서 Co2 첨가에 대한 연소 특성 (Characteristics for Effects of Co2 Addition to Oxygen-Enriched Combustion)

  • 김한석;김호근;안국영;김용모
    • 대한기계학회논문집B
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    • 제28권1호
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    • pp.9-15
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    • 2004
  • $CO_2$ is a well-known green house gas as well as the major source of global warming. Many researchers have studied to reduce $CO_2$ emission in combustion processes. Among the method for reducing $CO_2$ emission, oxygen-enriched combustion has been proposed. Because its adiabatic flame temperature is relatively too high, existing facilities must be changed or the flame temperature in the combustion zone should be reduced. The combustion characteristics, composition in the flame zone, temperature profile and emission gases were investigated experimentally for the various oxygen-enriched ratios(OER) by the addition of $CO_2$, under constant $O_2$ flow rate. Results showed that the reaction zone was quenched and broadened as the addition of $CO_2$ was increased. The emission of NOx in flue gas was decreased as decreasing temperature in reaction zone. It was also shown that the reaction was delayed by the cooling effect. As the addition of $CO_2$ was increased, the composition of CO in the flame zone was increased due to the increase of reaction rate by increasing mixing effect of oxidant/fuel at OER=0%, but the composition of CO was decreased by quenching effect at OER=50% and 100%.