• 제목/요약/키워드: Oxygen consumption method

검색결과 97건 처리시간 0.029초

직접분사식 디젤기관에서 바이오디젤유와 함산소성분 혼합연료 적용시 배기배출물 특성 및 EGR의 적용 연구 (A Study on Emission Charncteristics and EGR Application of Blending Fuels with Biodiesel Fuel and Oxygenate Component in a D.I. Diesel Engine)

  • 최승훈;오영택
    • 한국자동차공학회논문집
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    • 제16권2호
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    • pp.43-48
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    • 2008
  • The exhaust emissions of diesel engine are recognized as a major cause influencing environment strongly. In this study, the possibility of biodiesel fuel and oxygenated fuel(dimethoxy methane; DMM) was investigated as an alternative fuel for a naturally aspirated direct injection diesel engine. The smoke emission of blending fuel(biodiesel fuel 90vol-%+DMM 10vol-%) was reduced approximately 70% at 2500rpm, full load, in comparison with the diesel fuel. But, power, torque and brake specific energy consumption showed no significant differences. But, NOx emission of biodiesel fuel and DMM blended fuel increased compared with commercial diesel fuel due to the oxygen component in the fuel. It was needed a NOx reduction counterplan that EGR method was used as a countermeasure for NOx reduction. It was found that simultaneous reduction of smoke and NOx emission was achieved with BDF(95 vol-%) and DMM(5 vol-%) blended fuel and cooled EGR method(15%).

알칼리형 연료전지에서 산소환원에 미치는 촉매 특성 연구 I. La0.6Sr0.4Co1-xFexO3의 합성과 산소환원반응 (A Study on the Catalytic Characteristics of Oxygen Reduction in an Alkaline Fuel Cell I. Synthesis of La0.6Sr0.4Co1-xFexO3 and Reduction Reaction of Oxygen)

  • 문형대;이호인
    • 공업화학
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    • 제7권3호
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    • pp.543-553
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    • 1996
  • 산소전극 촉매로서 페롭스카이트형 산화물을 사용하여 알칼리형 연료전지에서의 산소환원반응에 관하여 연구하였다. 능금산(malic acid)을 사용하여 고표면적의 페롭스카이트형 $La_{0.6}Sr_{0.4}Co_{1-x}Fe_xO_3$(x=0.00, 0.01, 0.10, 0.20, 0.35 및 0.50) 산화물을 제조하였으며, Fe 치환량과 암모니아수 첨가량에 따른 XRD 구조와 비표면적의 변화를 고찰하여 Fe와 암모니아간에 생성되어지는 착화합물이 페롭스카이트로의 구조안정화와 비표면적 증대의 주요임을 알았다. 그리고 페롭스카이트 단일상을 얻기 위해서는 다단계 승온처리가 필요했으며, XRD 실험결과 단순 정입방체상이 형성됨을 확인하였다. $La_{0.6}Sr_{0.4}Co_{1-x}Fe_xO_3$ 산화물을 촉매로 사용한 알칼리형 연료전지용 산소전극의 산소환원반응활성을 측정하기 위하여 순환 전압-전류법, 정전압-전류법, 전류단절법 등을 이용하였다. $La_{0.6}Sr_{0.4}Co_{1-x}Fe_xO_3$ 산화물에서 Fe의 치환비가 증가함에 따라, x=0.01에서 최소, x=0.20와 0.35 사이에서 최대의 산소환원활성(전류밀도)을 보였으며, 이와 같은 경향은 표면적의 변화와 무관하였다.

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Nicotinamide에 의한 종양내 산소 분압의 증가에 있어서 혈류 또는 산소 소모의 역할 (Role of Blood Flow vs. $O_{2}$ Consumption in Nicotinamide-induced Increase $pO_{2}$ in a Murine Tumor)

  • 이인태;;조문준
    • Radiation Oncology Journal
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    • 제12권1호
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    • pp.17-25
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    • 1994
  • Nicotinamide(NA)에 의한 종양내 산소 분압의 증가가 세포내 신진 대사의 변화 또는 산소 접근성의 변화에 기인하는지 규명하고자 NA의 세포내 산소 소모와 신진 대사에 미치는 영향을 다음과 같이 실험하여 보았다. 즉 시험관에서는 Adenylate Phosphates와 $NAD^{+}$의 변화를 동시에 생체에서는 혈류의 변화를 통하여 측정하였다. 세포 배양전 30분간 4mM(=500mg/kg) NA 처리시 세포내 산소 소모에는 영향이 없었다. 또는 4mM NA에서 세포내 Adenylate phophates와 $NAD^{+}$치의 변화도 없었다. 종양내 혈류의 변화(적혈구 흐름)로 생체내에서 NA가 산소의 접근성의 증가를 가져오는지 평가하였다. 레이저 도플러로 적혈구 흐름의 변화를 측정하였는데, 종양의 크기와 비례해서, 150$mm^{3}$ 크기의 종양에서 적혈구 흐름이 35$\% $증가하였으며 500$mm^{3}$종양에서 75$\% $증가하였다. 결론적으로 이상의 관찰에서 FSaII 생쥐 종양 모델에서 NA에 의한 종양내 산소 분압의 증가는 국소적 산소 소모의 감소에 의한 것이 아니며, 국소 종양내 혈류의 증가가 종양내 산소 분압 증가의 주 기전으로 사료된다.

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FDS 열분해 모델을 이용한 콘칼로리미터(ISO 5660) 화재 시뮬레이션 (Fire Simulation by Pyrolysis Method of FDS for the Small Cone Calorimeter (ISO 5660))

  • 양성진;장정훈;강찬용
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2009년도 춘계학술대회 논문집
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    • pp.206-212
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    • 2009
  • Chemical behaviors of each surface material for interior facilities affect to fire initiation and growth in general fire situation. These chemical behaviors were characterized by thermal properties (Heat release rate, Pyrolysis rate, specific heat, etc) which could be derived from experimental test. Especially, Heat release rate which indicates aspect of fire size is one of the most important property to asses fire hazard and protection needs. The cone calorimeter test (ISO 5660) has recently assumed to a dominant role in bench scale fire testing to obtain the Heat release rate of materials. This value could be calculated by the 'Oxygen Consumption Method' under various producing irradiances to each surface of materials. In this study, Process of the cone calorimeter test was simulated by Pyrolysis model of FDS (Fire Dynamics Simulator by NIST) base on the ISO 5660 international standard. Then, we could estimate the simulation method of FDS in case of single materials through the comparative study with test results.

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한냉에 노출된 인체의 냉각과 총지방량 및 S/V 비율 사이의 관계 (Relationship between Total Body Fat and S/V Ratio and Body Cooling for Two Hours at $15^{\circ}C$)

  • 정관옥;남기용
    • The Korean Journal of Physiology
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    • 제3권1호
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    • pp.19-28
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    • 1969
  • Skin temperatures on 10 sites and rectal temperature at every 10 minutes, oxygen consumption at every 20 minutes were measured on 18 male subjects (ages between 14 and 47 years) after exposure to cold air at $15^{\circ}C$ for two hours in a climatic room. Total body fat measured by means of a skinfold method and ratio of body surface area (S) to body volume (V), S/V, were utilized as basis of observations. Surface area was calculated after DuBois equation and body volume was calculated by our original formula. In influencing on the heat loss from the body core to the cold environment, % fat showed inverse relations, whereas, S/V ratio showed direct relations. Thus these two factors acted antagonistically on the body heat loss. Local skin temperatures showed negative correlations with skinfold thickness on the same site, nemaly, on chest, r=-.567; on back, r=-.507; and on upper arm, r=-.353. The other 7 skin sites showed low correlations with % fat. Minimum mean weighted skin temperature (MWST) showed a negative correlation (r=-.443) with % fat, and showed no correlation with S/V ratio. Oxygen consumption in the cold air at $15^{\circ}C$ increased from the first measurement at 20 minutes after exposure and maintained the same increasing trend up to 120 minutes. ${\Delta}T_R$ was greater in tile lean subjects who showed a greater % change in oxygen consumption. The antagonistic actions of % fat and S/V ratio on the heat loss were manifested by observations as follows: minimum rectal temperature was higher In fat subjects (r=.600) and lower in subjects with a greater S/V ratio (=-.582), ${\Delta}T_R$ was smaller in fat subjects (r=-.738) and greater in subjects with a greater S/V ratio (r=.618). Temperature difference between body core and skin surface (minimum rectal temperature minus minimum MWST) showed a positive correlation with % fat (r=.600) and a negative correlation with S/V ratio (r=-.881). Decrease in the mean body temperature and heat debt, respectively, showed negative correlations with % fat and positive correlations with S/V ratio.

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대동맥 차단시 저온 산소화 심정지액이 심근보호에 미치는 영향 (An Experimental Study on the Effect of Hypothermic Oxygenated Cardioplegic Solution on Myocardial Protection during Prolonged Aortic Cross-clamping)

  • 왕영필;이홍균
    • Journal of Chest Surgery
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    • 제18권4호
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    • pp.759-770
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    • 1985
  • This study was experimentally undertaken to evaluate the effect of hypothermic oxygenated cardioplegic solution on myocardial protection during prolonged aortic cross clamping under cardiopulmonary bypass. Dogs were divided into two groups control group [received hypothermic unoxygenated cardioplegic solution] and experimental group [received hypothermic oxygenated cardioplegic solution]. Coronary sinus effluent was obtained at once and 30, 60, 90 minutes after cross-clamping for the determination of pH, PCO2,PO2 and lactate level during the infusion of cardioplegic solution and myocardial biopsies were obtained after cessation of 90 minutes of aortic cross-clamping. The results obtained were as follows: 1. There was no significant differences in the pH and PCO2 between the oxygenated and unoxygenated cardioplegic solution but the PO2 of the oxygenated solution was 4 times greater than unoxygenated solution, and also the oxygenated solution had a significantly greater oxygen content [2.020.05 ml 02/min] and had much more oxygen delivery than unoxygenated solution. 2. The myocardial oxygen consumption and the myocardial oxygen extraction in oxygenated group were 1.63 ml 02/100 ml and 67.32% respectively, which was greater than those in unoxygenated group. 3. Regarding to pH and PCO2 of coronary sinus effluent, there was no significant differences between two groups in early period of infusion of cardioplegic solution, but the pH shifted to acidosis from 60 minutes, PCO2 increased from 90 minutes of aortic cross-clamping, and PO2 markedly decreased from 90 minutes of aortic cross-clamping in unoxygenated group. 4. The lactate concentration of coronary sinus effluent revealed relatively normal in both groups, but showed slight increase up to 27.54.56 mg/100 ml at 90 minutes of aortic cross-clamping in unoxygenated group. 5. On electron microscopic study, the ultrastructural integrity of myocardial cells in oxygenated group was well preserved within 90 minutes. Slight swelling and deformity of mitochondria, interfibrillar widening, and disarrangement of myofibrils were observed at 90 minutes after aortic cross-clamping in unoxygenated group. From these results, the use of hypothermic oxygenated cardioplegic solution seemed to be effective and better method for the preservation of ischemic myocardium during the prolonged aortic cross-clamping.

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인체에서 Pick 원리 및 열희석법에 의한 심박출량 측정의 비교 연구 (Comparison of Cardiac Output Determination by Direct Fick and Thermodilution Method in Man)

  • 장병철
    • Journal of Chest Surgery
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    • 제14권3호
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    • pp.228-234
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    • 1981
  • Measurement of cardiac output by thermodilution method is easy to perform and can be repeated at very short intervals and offers a number of theoretical and practical advantages. The purpose of this paper is to reevaluate the accuracy and reproducibility of the thermodilution cardiac output by comparing the results with those obtained by the direct Fick technique. From January through April 1981 [4 months], 26 simultaneous cardiac output measurements were made using thermodilution and direct Fick methods in 12 patients in the intensive care unit of Severance Hospital following open heart surgery. The average age of the patients was $34.8{\pm}12.0$ [SD] years [range; 17-57 years]. For cardiac output determination by thermodilution technique [$CO_TD$], a Swan-Ganz Thermodilution Catheter, Model 93A-131-7F [Edwards Laboratories], a Cardiac Output Computer, Model 9520A, and Strip Chart Recorder, Model 9810 [Edwards Laboratories] were used. For the determination of cardiac output by direct Fick principle [$CO_Fick$], a Van Slyke Manometric Apparatus [Thomas] for the measurements of arteriovenous oxygen content difference and a Collin`s Respirometer with Kymograph for the measurement of oxygen consumption were used. The correlation between the simultaneously measured $CO_TD$ and $CO_Fick$ was found to be $CO_Fick$ = 0.95.$CO_TD$ + 0.1073, [r= 0.9777, P < 0.001 ]. For 26 double or triple determinations of $CO_TD$, the values ranged from 1.77 L/min to 6.66 L/min, with a reproducibility of 2.18%. The maximum difference of $CO_TD$ for $CO_Fick$ was between +11.99% and -12,99% [$Mean{\pm}SD$ = $6.07{\pm}3.97$%]. Measurement of cardiac output by thermodilution method provides a simple, rapid, reproducible and highly accurate method for multiple cardiac output measurements suitable for use at the bedside. Comparison of Cardiac Output Determination by Direct Fick and Thermodilution Method in Man.

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Alcohol oxidase 효소센서를 이용한 알코올 음료 중의 에탄올 정량 (Determination of Ethanol in Alcoholic Beverages by Alcohol Oxidase Sensor)

  • 이옥경;김태진;노봉수
    • 한국식품과학회지
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    • 제27권2호
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    • pp.266-269
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    • 1995
  • 알코올 함량을 보다 신속하고 정확하게 측정하고자, 알코올 센서를 사용하였다. Alcohol oxidase를 glutaraldehyde로 nylon net에 고정화시킨 다음 산소전극에 연결하여 기질과의 반응에서 소모되는 용존산소 소비량의 변화를 용존산소측정기로 측정하여 알코올을 정량하였다. 알코올 센서의 최적조건에서 시판되는 각종 주류를 측정해 본 결과, 각각 맥주는 $4{\sim}5%$, 저알코올성 음료는 0.71%, 포도주는 10.06%, 청주는 16.12%, 소주는 25.71%, 탁주는 6.18%로 정량되었으며, 이는 가스 크로마토그래피로 측정한 값과 좋은 상관관계를 가졌다.

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Effects of oral caffeine and capsaicin administration on energy expenditure and energy substrates utilization in resting rats

  • Kim, Jisu;Jeon, Yerim;Hwang, Hyejung;Suh, Heajung;Lim, Kiwon
    • 운동영양학회지
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    • 제15권4호
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    • pp.183-189
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    • 2011
  • Caffeine and capsaicin increase resting energy metabolism. However, most measurements have been conducted in short-term studies. Therefore, we investigated the effects of caffeine and capsaicin on energy expenditure and energy substrate utilization in resting rats for 6 h. The caffeine (Experiment 1) experiment included four male rats aged 5 weeks and measured the effects of oral administration of caffeine (10 or 50 mg/kg) on respiratory gas, energy expenditure, and energy substrate oxidation for 6 h. Experiment 2 included four male rats aged 6 weeks to measure the effects of capsaicin (10 mg/kg) using the same method as in Experiment 1. The results of Experiment 1 indicated that O2 uptake and carbohydrate oxidation after caffeine administration for 2 h was higher in the 10 mg trial than that in the 50 mg or placebo trials (P < 0.05). However fat oxidation was not significantly different. In contrast, capsaicin (Experiment 2) observed no differences between the placebo and the capsaicin trials. In conclusion, caffeine initially increased the resting energy consumption for 2 h, and this energy expenditure was due to carbohydrate oxidation. Capsaicin did not change oxygen uptake, respiratory exchange ratio, fat oxidation, or carbohydrate oxidation.

해수중에서 유처리제 및 유처리제/Bunker-C유 혼합물의 생분해도와 용존산소소비에 관한 연구(I) - 유처리제의 생분해도와 용존산소소비 - (Study on the Biodegradability of Dispersants and Dispersant/Bunker-C Oil Mixtures and the Dissolved Oxygen Consumption in the Seawater(I) - The Biodegradability of Dispersants and the Dissolved Oxygen Consumption in the Seawater -)

  • 김광수;박청길;유선재
    • 한국수산과학회지
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    • 제26권5호
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    • pp.493-501
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    • 1993
  • 유처리제의 생분해도와 유처리제가 해수중의 용존산소에 미치는 영향을 구명하기 위해서 세 제품의 유처리제(SG, GL, WC)와 비이온 계면활성제(OA-5)에 대한 TOD분석, 원소분석 및 해수중에서의 생분해 실험을 행한 결과를 요약하면 다음과 같다. 1. 1mg의 유처리제는 $2.37{\sim}2.80mg$의 TOD, 1mg의 비이온 계면활성제는 2.45mg의 TOD를 나타내었다. 2. 유처리제는 탄소가 $67.6{\sim}76.5\%$, 수소가 $10.2{\sim}12.3\%$였고, 비이온 계면활성제는 탄소가 $65.3\%$, 수소가 $10.3\%$였으며 어느 것에서도 질소는 검출되지 않았다. 3. 유처리제는 생분해시 제품에 따라 다소 차이가 있었으나 1mg의 유처리제가 $0.403{\sim}0.595mg$$BOD_5$$0.703{\sim}0.855mg$$BOD_{20}$를 유발하였다. 또한 1mg의 비이온 계면활성제는 0.50mg의 $BOD_5$ 및 0.97mg의 $BOD_{20}$를 나타내었다. 4. 해수중에서 탈산소계수($K_1$)는 유처리제(4.0mg/l)의 경우 $0.121{\sim}0.171/day$, 비이온 계면활성제(2.0mg/l)의 경우 0.181/day로 나타났다. 또한 유처리제 1mg의 최종산소요구량($L_o$)은 $0.789{\sim}0.953mg$로서 계면활성제 1mg의 최종산소요구량 0.956mg과 비슷하였으며, Glucose 1mg의 TOD값 1.07mg에 접근하는 값이었다. 5. 해수 중의 생분해도($BOD_5/TOD$)에 있어서, 유처리제는 $17{\sim}21\%$, 비이온 계면활성제는 약 $20\%$로서 모두 중간 분해군에 속하였다.

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