• Title/Summary/Keyword: Oxygen Minimum Zone

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Microstructure and Hardness of Surface Melting Hardened Zone of Mold Steel, SM45C using Yb:YAG Disk Laser

  • Lee, Kwang-Hyeon;Choi, Seong-Won;Yoon, Tae-Jin;Kang, Chung-Yun
    • Journal of Welding and Joining
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    • v.34 no.1
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    • pp.75-81
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    • 2016
  • This study applied laser surface melting process using CW(Continuous wave) Yb:YAG laser and cold-work die steel SM45C and investigated microstructure and hardness. Laser beam speed, power and beam interval are fixed at 70 mm/sec, 2.8 kW and $800{\mu}m$ respectively. Depth of Hardening layer(Melting zone) was a minimum of 0.8 mm and a maximum of 1.0 mm that exceeds the limit of minimum depth 0.5 mm applying trimming die. In all weld zone, macrostructure was dendrite structure. At the dendrite boundary, Mn, Al, S and O was segregated and MnS and Al oxide existed. However, this inclusion didn't observe in the heat-affected zone (HAZ). As a result of interpreting phase transformation of binary diagram, MnS crystallizes from liquid. Also, it estimated that Al oxide forms by reacting with oxygen in the atmosphere. The hardness of the melting zone was from 650 Hv to 660 Hv regardless of the location that higher 60 Hv than the hardness of the HAZ that had maximum 600 Hv. In comparison with the size of microstructure using electron backscatter diffraction(EBSD), the size of microstructure in the melting zone was smaller than HAZ. Because it estimated that cooling rate of laser surface melting process is faster than water quenching.

Analysis on Residential Micro Climate of the Urban Heat Island and Oxygen Concentration in Winter (겨울철 열섬 및 산소농도의 측정을 통한 주거지별 국지기후의 특성분석)

  • Hwang Jee Wook;Kim So Chong
    • Journal of Environmental Science International
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    • v.13 no.12
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    • pp.1023-1032
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    • 2004
  • Rapid progress in urbanization has resulted in a change of the micro climate, especially in the urban area. In order to investigate the phenomenon of the heat island in the residential micro climate, a field survey was carried out by 4 sets of the residential type in Jeonju under typical winter synoptic condition. As analytic methode, it is used the comparison on the relation of the Land-to-Coverage Rate to Heat Island and Oxygen Concentration. And as a key question it is asked how stable characteristics of the micro climate will result from the survey of the Heat Island and the Oxygen Concentration, used as indicator. To ensure the trustworthy result of research, it is calculated the critical influence of the wind velocity and the Land-to-Covearage Rate. As a result of comparative analysis, it could be confirmed that the local temperatures in all sets of the residential type were higher than the average temperature in Jeonju. But the housing type A 'exclusive use for housing zone' has relativly the most stable and best living condition. On the contrary the residential type B and D has the worst toward the oxygen concentration in the time zone 9-12 a.m., which didn't reach the minimum of the oxygen concentration $20.5{\%}.$ It means that the higer the development and population density is, the worse is the situation of the Quality of Life in the residential types in accordance with the heat island and oxygon con­centration.

A study on an intermittent aeration membrane bioreactor system using ammonia sensor to decrease energy consumption and sludge concentration by tubular membrane (암모니아 센서를 이용한 간헐폭기 Membrane bioreactor공정에서의 전력비 저감과 관형막을 이용한 슬러지 농축에 관한 연구)

  • Kang, Heeseok;Lee, Euijong;Kim, Hyungsoo;Jang, Am
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.2
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    • pp.161-170
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    • 2014
  • It is essential to decrease energy consumption and excess sludge to economically operate sewage treatment plant. This becomes more important along with a ban on sea dumping and exhaustion of resource. Therefore, many researchers have been study on energy consumption reduction and strategies for minimization of excess sludge production from the activated sludge process. The aeration cost account for a high proportion of maintenance cost because sufficient air is necessary to keep nitrifying bacteria activity of which the oxygen affinity is inferior to that of heterotrophic bacteria. Also, additional costs are incurred to stabilize excess sludge and decrease the volume of sludge. There were anoxic, aerobic, membrane, deairation and concentration zone in this MBR process. Continuous aeration was provided to prevent membrane fouling in membrane zone and intermittent aeration was provided in aerobic zone through ammonia sensor. So, there was the minimum oxygen to remove $NH_4-N$ below limited quantity that could be eliminated in membrane zone. As the result of this control, energy consumption of aeration system declined by between 10.4 % and 19.1 %. Besides, we could maintain high MLSS concentration in concentration zone and this induced the microorganisms to be in starved condition. Consequentially, the amount of excess sludge decrease by about 15 %.

Evaluation of Similarity of Water Column Properties and Sinking Particles between Impact and Preserved Sites for Environmental Impact Assessment in the Korea Contracted Area for Manganese Nodule Development, NE Pacific (북동태평양 한국 망간단괴 광구해역에서 환경충격 시험지역과 보존지역간의 수층환경 및 침강입자 플럭스 유사성 비교)

  • Son, Juwon;Kim, Kyeong Hong;Kim, Hyung Jeek;Ju, Se-Jong;Yoo, Chan Min
    • Ocean and Polar Research
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    • v.36 no.4
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    • pp.423-435
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    • 2014
  • Verifying the similarity of environmental characteristics between an artificial impact site and a preserved or reference site is necessary to quantitatively and qualitatively evaluate the environmental impact of mining activity. Although an impact site (BIS station) and a preserved site (called KOMO station) that have been selected in the Korea manganese nodule contract area may share similar environmental characteristics, similarities in terms of the water column environment between both sites has not been investigated. In this study, we compared the chemical properties of the water columns and sinking particle fluxes between BIS and KOMO stations through two observations (August 2011 and September 2012). Additionally, we observed particle fluxes at the KOMO station for five years (July 2003~July 2008) to understand long-term natural variability. Vertical distributions of water column properties such as dissolved oxygen, inorganic nutrients (N, P, Si), total organic carbon below surface layer (within the depth range of 200 m) were not considerably different between the two sites. Especially, values of water column parameters in the abyssopelagic zone from 4000 m to bottom layer (~5000 m) were very similar between the BIS and KOMO sites. Sinking particle fluxes from the two sites also showed similar seasonality. However, natural variation of particle flux at the KOMO site varied from 3.5 to $129.9mg\;m^{-2}day^{-1}$, with a distinct temporal variation originating from ENSO events (almost forty times higher than a minimum value). These results could provide valuable information to more exactly evaluate the environmental impact of mining activity on water columns.

Effects of Various Bioreactors on Growth and Ginsenoside Accumulation in Ginseng Adventitious Root Cultures(Panax ginseng C.A. Meyer) (다양한 생물반응기 형태가 인삼(Panax ginseng C.A. Meyer) 부정근의 생장과 Ginsenoside 생산에 미치는 영향)

  • Kim, Yun-Soo;Hahn, Eun-Joo;Paek, Kee-Yoeup
    • Journal of Plant Biotechnology
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    • v.31 no.3
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    • pp.249-253
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    • 2004
  • The type of air lift bioreactor affected the root growth in ginseng adventitious root cultures. Among bioreactors used in this experiment, bulb type bubble bioreactor (BU) was the best to increase root growth (41.92 g dry weight). The kLa value representing the oxygen transfer capacity from medium to explants (6.98 h$^{-1}$ ) in BU with 5 cm bubble column was higher than other bioreactors. On the other hand, cylindric tube bioreactor (CT) without bubble column resulted in minimum root growth (38.55 g dry weight) and kLa value (5.25 h$^{-1}$ ). Furthermore, the root growth (50.30 g dry weight) in BU with 10 cm bubble column more increased than 5 cm bubble column. However, the kLa value do not affected the secondary metabolite such as ginsenosides. These results show that the bubble column in air lift bioreactor increase kLa value and increased kLa value stimulate the growth of ginseng adventitious roots.

Dynamic Characteristics of Water Column Properties based on the Behavior of Water Mass and Inorganic Nutrients in the Western Pacific Seamount Area (서태평양 해저산 해역에서 수괴와 무기영양염 거동에 기초한 동적 수층환경 특성)

  • Son, Juwon;Shin, Hong-Ryeol;Mo, Ahra;Son, Seung-Kyu;Moon, Jai-Woon;Kim, Kyeong-Hong
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.18 no.3
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    • pp.143-156
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    • 2015
  • In order to understand the dynamic characteristics of water column environments in the Western Pacific seamount area (approximately $150.2^{\circ}E$, $20^{\circ}N$), we investigated the water mass and the behavior of water column parameters such as dissolved oxygen, inorganic nutrients (N, P), and chlorophyll-a. Physico-chemical properties of water column were obtained by CTD system at the nine stations which were selected along the east-west and south-north direction around the seamount (OSM14-2) in October 2014. From the temperature-salinity diagram, the main water masses were separated into North Pacific Tropical Water and Thermocline Water in the surface layer, North Pacific Intermediate Water in the intermediate layer, and North Pacific Deep Water in the bottom layer, respectively. Oxygen minimum zone (OMZ, mean $O_2$ $73.26{\mu}M$), known as dysoxic condition ($O_2<90{\mu}M$), was distributed in the depth range of 700~1,200 m throughout the study area. Inorganic nutrients typified by nitrite + nitrate and phosphate showed the lowest concentration in the surface mixed layer and then gradually increased downward with representing the maximum concentration in the OMZ, with lower N:P ratio (13.7), indicating that the nitrogen is regarded as limiting factor for primary production. Vertical distribution of water column parameters along the east-west and south-north station line around the seamount showed the effect of bottom water inflowing at around 500 m deep in the western and southern region, and concentrations of water column parameters in the bottom layer (below 2,500 m deep) of the western and southern region were differently distributed comparing to those of the other side regions (eastern and northern). The value of Excess N calculated from Redfield ratio (N:P=16:1) represented the negative value throughout the study area, which indicated the nitrogen sink dominant environments, and relative higher value of Excess N observed in the bottom layer of western and southern region. These observations suggest that the topographic features of a seamount influence the circulation of bottom current and its effects play a significant role in determining the behavior of water column environmental parameters.

Distribution and Species Composition of Phytoplankton in the Southern Waters of Korea and their Relation to the Character of Water Masses (한국남해의 식물플랑크톤의 분포와 수괴특성)

  • PARK Joo-Suck;LEE Sam-Geun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.23 no.3
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    • pp.208-214
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    • 1990
  • Phytoplankton samples for this study were collected by Van Dorn Sampler at 28 oceanographic stations in the southern waters of Korea in February, April and August, 1988 to characterize the distribution and species composition of phytoplankton and their relation to the movement of water masses. During the study periods, phytoplankton standing crops in the southern waters were maximum in April and minimum in February. When the geographical distribution and abundance of the phytoplankton were considered, the highest standing crops were found near the front zone formed between Cheju Island and Tsushima Island. Therefore, their abundance depends ell the location of the front zone. On the other hand, there were relatively low standing crops in the open sea off the coastal area from the front zone in February and August. The cause of the unusal low standing crops found in August at the station 205/01, the central part of the coastal area of the southern waters where the largest standing crops occurred in February and April, seems to be due to the intrusion of Tsushima warm waters. This is because the waters at the station have high temperature and salinity, poor dissolved oxygen and nutrient salts, which are identical to the characteristics of proper Tsushima warm waters. It seems that these warm waters may affect the poor productivity in this area. Seventy-two species in thirty-three genera of the phytoplankton were indentified from the samples. Among them, 61 species in 27 genera belong to diatoms and 12 species in 7 genera to dinoflagellates. The largest number of phytoplankton species occurred in August while the largest number of the tells in April. Predominant species were Eucampia zodiacus in February, Skeletonema costatum and Chaetoceros curvisetus in April and Chaetoceros affinis in August. Eucampia zodiacus which was dominant in February and April seems to be a indicator of the southern coastal waters of Korea and mixed waters west of Cheju Island.

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Preparation and characterization of PVDF/alkali-treated-PVDF blend membranes

  • Liu, Q.F.;Li, F.Z.;Guo, Y.Q.;Dong, Y.L.;Liu, J.Y.;Shao, H.B.;Fu, Z.M.
    • Membrane and Water Treatment
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    • v.7 no.5
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    • pp.417-431
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    • 2016
  • Poly(vinylidene fluoride) (PVDF) powder was treated with aqueous sodium hydroxide to obtain partially defluorinated fluoropolymers with expected properties such as improving hydrophilicity and fouling resistance. Raman spectrum and FT-IR results confirmed the existence of conjugated carbon double bonds after alkaline treatment. As the concentration increased, the degree of defluorination increased. The morphology and structure of membranes were examined. The permeation performance was investigated. The results showed that membrane's hydrophilicity increased with increase of the percentage of alkaline treated PVDF powder. Moreover, in terms of the water contact angle, it decreased from $92^{\circ}$ to a minimum of $68^{\circ}$; while water up take increased from 128 to 138%. Fluxof pure water and the cleaning efficiency increased with the increase of alkaline treated PVDF powder. The fouling potential also decreased with the increase of the percentage of alkaline treated PVDF powder. The reason that makes blending PVDF show different characteristics because of partial defluorination, which led the formation of conjugated C = C bonds and the inclusion of oxygen functionalities. The polyene structure followed by hydroxide attack to yield hydroxyl and carbonyl groups. Therefore, the hydrophilicity of blending membrane was improved. The SEM and porosity measurements showed that no obvious variations of the pore dimensions and structures for blend membranes were observed. Mechanical tests suggest that the high content of the alkaline treated PVDF result in membranes with less tolerance of tensile stress and higher brittleness. TGA results exhibited that the blend of alkaline treated PVDF did not change membrane thermal stability.

Variation of Calcium Carbonate Content and Dansgaard-Oeschger Events in the Continental Slope of the Central Bering Sea during the Last 65 Kyr (베링해 중부 대륙사면 지역의 지난 65,000년 동안 탄산염 함량 변화와 Dansgaard-Oeschger 사건들)

  • Kim, Sung-Han;Khim, Boo-Keun;Itaki, Takuya;Shin, Hye-Sun
    • Ocean and Polar Research
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    • v.30 no.3
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    • pp.215-224
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    • 2008
  • A piston core (MR06-04 PC23A) collected from the northern continental slope in the central Bering Sea has recorded the high-resolution millennial-scale variation of calcium carbonate ($CaCO3$) content during the last 65 kyr. An estimation of the age of the core sediments was carried out by using the lithologic correlation of the deglacial laminated layers with a neighboring core (HLY02023JPC), complementing the last appearance datum of both Lychnocanoma nipponica sakaii (54 kyr) and Amphimelissa setosa (85 kyr). The probable age of core MR06-04 PC23A was approximately younger than 65 kyr. Two distinct events of a significant increase of $CaCO3$ in the deglacial laminated sediments clearly correspond to MWP1A and MWP1B in the Bering Sea (Gorbarenko et al. 2005) and to T1ANP and T1BNP in the North Pacific (Gorbarenko 1996). These pronounced peaks of $CaCO3$ contents result from the elevated carbonate production in the surface water and the subsequent weakened dilution due to terrestrial input, along with an enhanced oxygen minimum zone. The $CaCO3$ contents are low (${\sim}2%$) during the last glacial period mainly because of a low carbonate production caused by an expanded sea-ice cover and an increased dilution by terrigenous particles due to their closer distance to the continent during the sea-level low stand. The occurrence of seven distinct $CaCO3$ peaks in core MR06-04 PC23A is remarkable during MIS 3 and MIS 4, and they most likely correlate to the short-term millennial Dansgaard-Oeschger events.

Characteristics and Risk Assessment of Flame Spreading Over Metal Dust Layers (퇴적금속 분진층을 전파하는 화염의 연소특성과 위험성 평가)

  • Han, Ou-Sup
    • Korean Chemical Engineering Research
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    • v.43 no.1
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    • pp.47-52
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    • 2005
  • The wide use of metal dusts have been found in industrial field and many dust explosion accidents occur by fire spread of dust layer. In this study, we developed a new experimental device to examine fire and explosion characteristics of the dust layer. Aspects of the burning zone over metals(Mg, Zr, Ta, Ti, etc) and PMMA(Polymethyl methacrylate) dust layers have been investigated experimentally to clarify behaviors (Spread rate and quenching distance) and effects of $N_2$ surrounding gas on the fire spread over metal dust layers. From the experimental result, it was found that the spread rate of metal dusts is larger than PMMA, the dependability of spread rate over the thickness of dust layer is small, and the minimum oxygen concentration of spread flame over Mg dust layer is 3.6-3.7 vol%. Since high correlation between the spread rate and the reciprocal of quenching distance was seen, relative risk prediction in those inflammable parameters can be predicted.