• Title/Summary/Keyword: Oxygen Inclusion

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Preparation of YBCO films on Ag substrates by MOCVD process (MOCVD공정에 의한 Ag 기판 위에 YBCO 박막의 증착)

  • 김호진;주진호;전병혁;김찬중
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2003.10a
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    • pp.79-82
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    • 2003
  • We prepared YBCO coated conductor by direct deposition of YBCO on Ag substrate by a MOCVD method. The Ag substrate was only prepared by cold rolling. The XRD data of the as-rolled Ag tape showed the formation of dominant (420) oriented grains. Processing variables were the oxygen partial pressure (Po$_2$) and deposition temperature (T$_{d}$). It was found that the a-axis oriented films were grown at lower T$_{d}$ below 80$0^{\circ}C$, while the c-axis oriented films were grown about 80$0^{\circ}C$. The surface of the films consisted of a second inclusion phase dispersed in the YBCO matrix. The Cu-rich phase regions were observed at the YBCO/Ag interface probably due to the inter-diffusion of Ag and Cu. Cu.

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Sharp-line Electronic Spectroscopy and Ligand Field Analysis of Cr(III) Complexes with Amino Acid Ligands

  • 박성진;최영근;한승석;이규왕
    • Bulletin of the Korean Chemical Society
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    • v.20 no.12
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    • pp.1475-1478
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    • 1999
  • Ligand field calculations have been performed based on the data from the absorption and low temperature sharp-line excitation spectra of fac-Cr(gly)₃, fac-Cr(L-serine)₃ · 2H₂O and fac-Cr(L-leucine)₃·2H₂O. The optimized ligand field parameters for all complexes show that the carboxylate and the amino groups are moderate σ-donor. The values of $e_{{\pi}O}$ are typical of other complexes with carboxylate ligands. However, the π-interaction of carboxylic oxygen to the chromium in serinato complex is much weaker than that of other complexes. The inclusion of π-anisotropy is necessary to adequately explain the large doublet splittings.

Potential of combining natural-derived antioxidants for improving broiler meat shelf-life - A review

  • Andiswa Ntonhle Sithole;Vuyisa Andries Hlatini;Michael Chimonyo
    • Animal Bioscience
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    • v.36 no.9
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    • pp.1305-1313
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    • 2023
  • Synthetic antioxidants have shown adverse effects on consumers. The review, thus, aims to assess the effect of marinating broiler meat with plant leaves-derived antioxidants potential for improving shelf-life and human health. Broiler meat loss and waste due to spoilage is more than three million kg annually, thus, extending shelf-life by reducing initial microbial load and autoxidation is essential. Adding various antioxidants would reduce oxidation of protein and fatty acids improving nutritional shelf-life through synergic interactions. Antioxidant synergetic effects also improves reduction in microbiota proliferation leading to the delayed development of off flavours and deterioration of meat colour. To reduce initial microbial load and autoxidation effects, the inclusion of polyphenols and antioxidants from varying sources by mixing various antioxidants would lead to improved synergic effects.

Enhancement of Nitric Oxide with nonthermal plasma jet and its effect on Escherichia coli inactivation and various type of cancer cell

  • Shaw, Priyanka;Kumar, Naresh;Attri, Pankaj;Choi, Eun Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.230.2-230.2
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    • 2016
  • A new approach for antimicrobial is based on the overproduction of reactive nitrogen species (RNS), especially; nitric oxide (NO) and peroxinitrite ($ONOO^-$-) are important factors to deactivate the bacteria. Recently, non-thermal atmospheric pressure plasma jet (APPJ) has been frequently used in the field of microbial sterilization through the generation of different kinds of RNS/ROS species. However, in previous study we showed APPJ has combine effects ROS/RNS on bacterial sterilization. It is not still clear whether this bacterial killing effect has been done through ROS or RNS. We need to further investigate separate effect of ROS and RNS on bacterial sterilization. Hence, in this work, we have enhanced NO production, especially; by applying a 1% of HNO3 vapour to the N2 based APPJ. In comparison with nitrogen plasma with inclusion of water vapour plasma, it has been shown that nitrogen plasma with inclusion of 1% of HNO3 vapour has higher efficiency in killing the E. coli and different type of cancer cell through the high production of NO. We also investigate the enhancement of NO species both in atmosphere by emission spectrum and inside the solution by ultraviolet absorption spectroscopy. Moreover, qPCR analysis of oxidative stress mRNA shows higher gene expression. It is noted that 1% of HNO3 vapour plasma generates high amount of NO for killing bacteria and cancer cell killing.

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Stable Isotope and Fluid Inclusion Studies of the Manjang Copper Mine, South Korea (만장동광산(萬藏銅鑛山)에 대(對)한 유체포유물(流體包有物) 및 안정동위원소분석(安定同位元素分析) 연구(硏究))

  • Kim, Kyu Han;Shin, Jeung Sook
    • Economic and Environmental Geology
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    • v.20 no.3
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    • pp.169-177
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    • 1987
  • The Manjang copper magnetite-fluorite orebodies are imbedded within the limestone beds of the Hwajonri Formation. The ore deposits are characterized by magnetite-fluorite bearing skarn orebody in the west orebody and copper sulfide veins of the central and main orebodies. This study includes fluid inclusion geothermometry, salinity analysis, stable isotope analysis, and application of phase rule to mineral associations in skarn ore. Ore minerals are closely associated with the skarn silicates such as garnet, wollastonite and epidote. Magnetite and fluorite are remarkable in the west orebody whereas chalcopyrite is dominate in the central and main orebodies where pyrite and pyrrhotite also appear as sulfide gangues. Homogenization temperature and salinity of fluid inclusions are measured ranging between $240^{\circ}C$ and $350^{\circ}C$, 6.3~12.9 wt. percent in quartz and $220^{\circ}C$ and $350^{\circ}C$, 8.5~9.9wt. percent in fluorite, respectively. This indicates that the filling temperature and salinity are higher in quartz than in fluorite with the tendency of both to be linearly decreased suggesting an attribution of meteoric water to the mineralization. $T-fo_2$ diagram in the Ca-Fe-Si system at 1 kb and $Xco_2$=0.02 shows that the mineral assemblages with decreasing temperature are andradite-hedenbergite-calcite, hedenbergite-andradite-quartz, magnetite-andradite-quartz, and magnetite-quartz-calcite, indicating that magnetite crystallizes mostly late skarn stage at lower temperature. According to the carbon and oxygen isotopic values of the host limestone and calcite in ores, the sourec of carbon might be mixture of host limestone and deep seated carbons. Sulfur isotope data imply that ore fluids be relatively homogeneous in sulfur isotopic composition, mainly derived from igneous source.

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Effect of Cardiopulmonary Physiotherapy on Patients With Percutaneous Coronary Intervention - Systematic Review and Meta-Analysis (경피적 관상동맥 중재술을 받은 환자를 대상으로 심장호흡물리치료에 대한 효과 - 체계적 고찰과 메타분석)

  • Kang, Na-yoon;Park, Beom-seok;Kim, Min-hee
    • Journal of the Korean Society of Physical Medicine
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    • v.14 no.1
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    • pp.63-73
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    • 2019
  • PURPOSE: This study examined the effects of cardiopulmonary physiotherapy on the cardiopulmonary function, metabolism, inflammatory markers, and quality of life in patients with coronary artery disease who underwent percutaneous coronary intervention (PCI). METHODS: Electronic bibliographic databases of a regional information sharing system (RISS) and PubMed were searched to identify studies with randomized and non-randomized controlled trials. As the final outcome, 320 publications were identified and 18 studies met the inclusion and exclusion criteria. All studies were assessed for the quality of study using Cochrane's risk of bias. RESULTS: Sixteen studies met the inclusion criteria, in which meta-analysis had been conducted to examine the effectiveness of cardiopulmonary physiotherapy on the cardiopulmonary function, metabolism, inflammatory markers, and quality of life in patients undergoing PCI. Meta-analysis based on a random effect model showed that the cardiopulmonary physiotherapy was beneficial in improving the cardiopulmonary function, metabolism, inflammatory markers, and quality of life. In particular, there was a significant effect on the peak oxygen uptake (effect size 5.30%; 95% confidence interval 3.62~6.97). Cardiopulmonary physiotherapy for a during period of 6 weeks or more was effective in significantly improving the cardiopulmonary function and metabolism function in a subgroup analysis, but cardiopulmonary physiotherapy for less than 6 weeks was not effective. CONCLUSION: Cardiopulmonary physiotherapy has positive effects on the cardiopulmonary function, metabolism, inflammatory markers, and quality of life in patients undergoing PCI.

Genetic Environment of the Samsung Gold-Silver Deposit, Republic of Korea: Ore Minerals, Fluid Inclusion and Stable Isotope Studies (삼성 금-은광상의 생성환경: 광석광물, 유체포유물 및 안정동위원소 연구)

  • Yoo, Bong-Chul;Lee, Gill-Jae;Koh, Sang-Mo;You, Byoung-Woon
    • Economic and Environmental Geology
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    • v.43 no.5
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    • pp.443-453
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    • 2010
  • The Samsung gold-silver deposit consists of quartz veins that fill along the fault zone within Cretaceous shale and sandstone. Mineralization is occurred within fault-breccia zones and can be divided into two stages. Stage I is main ore mineralization and stage II is barren. Stage I is associated with wall-rock alteration minerals(sericite, pyrite, chlorite, quartz), rutile, base-metal sulfides(pyrrhotite, pyrite, sphalerite, chalcopyrite, galena), and electrum. Stage II occur quartz, calcite and pyrite. Fluid inclusion data indicate that homogenization temperatures and salinities of stage I range from 145 to $309^{\circ}C$ and from 0.4 to 12.4 wt.% NaCl, respectively. It suggests that hydrothermal fluids were cooled and diluted with the mixing of meteoric water. The main deposition of base-metal sulfides and electrum occurred as a result of cooling and dilution at temperature between $200^{\circ}C$ and $300^{\circ}C$. Sulfur(9.3~10.8‰) isotope composition indicates that ore sulfur was mainly derived from a magmatic source as well as the host rocks. The calculated oxygen[-2.3~0.9‰(quartz: 0.3‰, 0.9‰, calcite: -2.3‰)] and hydrogen[-86~-76‰(quartz: -86‰, -82‰, calcite: -76‰)] isotope compositions indicate that hydrothermal fluids may be meteoric origin with some degree of mixing of another meteoric water for paragenetic time.

Ore Minerals, Fluid Inclusion and Stable Isotope Studies of the Buyeong Gold-silver Deposit, Republic of Korea (부영 금-은광상의 광석광물, 유체포유물 및 안정동위원소 연구)

  • Lee, Gill-Jae;Yoo, Bong-Chul;Lee, Jong-Kil;Chi, Se-Jung;Lee, Hyun-Koo
    • Economic and Environmental Geology
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    • v.42 no.6
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    • pp.513-525
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    • 2009
  • The Buyeong gold-silver deposit consists of quartz veins that fill along the NS fault zone within Cretaceous Goseong formation. Mineralization can be divided into hypogene and supergene stages. Hypogene stage is associated with hydrothermal alteration minerals such as sericite, pyrite, chlorite, epidote and sulfides such as pyrite, pyrrhotite, marcasite, sphalerite, chalcopyrite, galena and galenobismutite. Supergene stage is composed of malachite, goethite, chalcocite, and sphalerite oxide. Fluid inclusion data indicate that homogenization temperatures and salinities range from 112 to $340^{\circ}C$ and from 0.2 to 7.9 wt.% NaCl, respectively. Sulfur(3.2~3.9‰) isotope composition indicates that ore sulfur was derived from mainly magmatic source as well as partly host rocks. The calculated oxygen(4.3~6.0‰) and hydrogen(-60~-64‰) isotope compositions indicate that hydrothermal fluids may be meteoric origin with some degree of mixing of another meteoric water for paragenetic time.

Hydrothermal Gold mineralization of the trabong district, vietnam : Mineralogical and geochemical study (베트남 짜봉(Trabong) 지역의 열수 금 광화작용 : 광물 및 지화학적 연구)

  • 한진경
    • Economic and Environmental Geology
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    • v.32 no.2
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    • pp.129-139
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    • 1999
  • Hydrothermal gold deposits of the Trabong district in Vietnam occur as single-stage quartz $\pm$ calcite veins (0.3-1.2 m thick) which fill fault fractures in graphite-bearing gneiss and schist of the Chulai Complex and Kham Duc Formation of the Proterozoic age. Ore grades are 1.3 to 92.4 g/ton Au. Ore mineralogy is very simple, consisting mainly of pyrite with minor amounts of base-metal sulfides and electrum. Gold grains occur in two assemblages as follows: (1) early, Fe-rich (7.2-10.4 mole % FeS) sphalerite + electrum (50.4-64.3 atom % Au) assemblage occurring as inclusions in pyrite; (2) late, Fe-poor «4.7 mole % FeS) sphalerite + galena + electrum (47.6-81.7 atom % Au) assemblage occurring along fractures of pyrites. Based on fluid inclusion data and thermochemical considerations of ore mineral assemblages, ore minerals were formed at high temperatures (about $230^{\circ}C$ to $420^{\circ}C$) from $H_{2}O-CO_{2}(-CH_{4})$-NaCI fluids with the sulfur fugacity of about $10^{-6}$ to $10^{-10}$ atm. Fluid inclusion data also indicate that ore mineralization occurred mainly as a result of fluid unmixing accompanying $CO_2$ effervescence. Calculated oxygen and measured hydrogen isotope compositions of mineralizing waters (${\delta}^{18}O_{V-SMOW}$ values = 5.3 to 8.6$\textperthousand$, ${\delta}D_{V-SMOW}$ values = - 60 to - 52$\textperthousand$), along with the sulfur isotope compositions of vein sulfides (${\delta}^{34}S_{CDR}$ values = - 1.2 to 2.8$\textperthousand$) and carbon isotope compositions of inclusion $CO_2$ (${\delta}^{13}C_{PDB}$ values = - 4.7 to - 2.0$\textperthousand$) indicate that the high temperature (mesohypothermal) gold mineralization formed from a magmatic fluid.

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Ore Minerals, Fluid Inclusion and Stable Isotope Studies of the Bongsang Gold-silver Deposit, Republic of Korea (봉상 금-은광상의 광석광물, 유체포유물 및 안정동위원소 연구)

  • Yoo, Bong-Chul;Lee, Jong-Kil;Lee, Gil-Jae;Lee, Hyun-Koo
    • Economic and Environmental Geology
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    • v.41 no.1
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    • pp.1-14
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    • 2008
  • The Bongsang gold-silver deposit consists of quartz veins that fill along the fault Bone within Cretaceous andesitic lapilli tuff. Mineralization is occurred within fault-breccia zones and can be divided into two stages. Stage I which can be subdivided into early and late depositional stages is main ore mineralization and stage II is barren. Stage I began with deposition of wall-rock alteration minerals and base-metal sulfides, and was deposited by later native silver, Ag-bearing tetrahedrite, polybasite and base-metal sulfides such like pyrite, sphalerite, chalcopyrite and galena. Fluid inclusion data indicate that homogenization temperatures and salinities of stage I range from 137 to $336^{\circ}C$ and from 0.0 to 10.6 wt.% NaCl, respectively. It suggests that ore forming fluids were cooled and diluted with the mixing of meteoric water. Also, temperature and sulfur fugacity deduced mineral assemblages of late stage I are $<210^{\circ}C\;and\;<10^{-15.4}$ atm, respectively. Sulfur(3.4%o) isotope composition indicates that ore sulfur was mainly derived from a magmatic source as well as the host rocks. The calculated oxygen{2.9%o, 10.3%o(quartz: 7.9%o, 8.9%o, calcite: 2.9%o, 10.3%o)}, hydrogen(-75%o) and carbon(-7.0%o, -5.9%o) isotope compositions indicate that hydrothermal fluids may be meteoric origin with some degree of mixing of another meteoric water for paragenetic time.