• Title/Summary/Keyword: Oxygen Flow Rate

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Low Temperature Thermal Oxidation using ECR Oxygen Plasma (ECR 산소 플라즈마를 이용한 저온 열산화)

  • 이정열;강석원;이진우;한철희;김충기
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.32A no.3
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    • pp.68-77
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    • 1995
  • Characteristics of electron cyclotron resonance (ECR) plasma thermal oxide grown at low-temperature have been investigated. The effects of several process parameters such as substrate temperature, microwave power, gas flow rate, and process pressure on the growth rate of the oxide have been also investigated. It was found that the plasma density, reactive ion species, is strongly related to the growth rate of ECR plasma oxied. It was also found that the plasma density increases with microwave power while it decreases with decreasing O2 flow rate. The oxidation time dependence of the oxide thichness showed parabolic characteristics. Considering ECR plasma thermal oxidation at low-temperature, the linear as well as parabolic rate constants calculated from fitting data by using the Deal-Grove model was very large in comparison with conventional thermal oxidation. The ECR plasma oxide grown on (100) crystalline-Si wafer exhibited good electrical characteristics which are comparable to those of thermal oxide: fixed oxide charge(N$_{ff}$)= 7${\times}10^{10}cm^{-2}$, interface state density(N$_{it}$)=4${\times}10^[10}cm^{-2}eV^{-1}$, and breakdown field > 8MV/cm.

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Effect of Geometrical Parameters on Discharge Coefficients of a Shear Coaxial Injector (전단동축형 분사기의 유량계수에 대한 형상학적 변수들의 영향)

  • Ahn, Jonghyeon;Lee, Keunseok;Ahn, Kyubok
    • Journal of ILASS-Korea
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    • v.25 no.3
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    • pp.95-102
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    • 2020
  • Six shear coaxial injectors for a 3 tonf-class liquid rocket engine using oxygen and methane as propellants were designed and manufactured by considering geometric design parameters such as a recess length and a taper angle. Cold-flow tests on the injectors were performed using water and air as simulants. By changing the water mass flow rate and air mass flow rate, the injection pressure drop under single-injection and bi-injection was measured. The discharge coefficients through the injector oxidizer-side and fuel-side were calculated and the discharge coefficient ratio between bi-injection and single-injection was obtained. Under single-injection, the recess served to reduce the injection pressure drop on the injector fuel-side. For the injectors without recess, the discharge coefficients under bi-injection were almost the same as those under single-injection. However, for the injectors with recess, the taper angle and bi-injection had a significant effect on the discharge coefficient.

Assessment of flow-accelerated corrosion-induced wall thinning in SA106 pipes with elbow sections

  • Seongin Moon;Jong Yeon Lee;Kyung-Mo Kim;Soon-Woo Han;Gyeong-Geun Lee;Wan-Young Maeng;Sebeom Oh;Dong-Jin Kim
    • Nuclear Engineering and Technology
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    • v.56 no.4
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    • pp.1244-1249
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    • 2024
  • A combination of flow-accelerated corrosion (FAC) tests and corresponding computational fluid dynamics (CFD) tests were performed to determine the hydrodynamic parameters that could help predict the highly susceptible location to FAC in the elbow section. The accelerated FAC tests were performed on a specimen containing elbow sections fabricated using commercial 2-inch carbon steel pipe. The tests were conducted at flow rates of 9 m/s under the following conditions: water temperature of 150 ℃, dissolved oxygen <5 ppb, and pH 7. Thickness reduction of the specimen pipe due to FAC was measured using ultrasonic testing. CFD was conducted on the FAC test specimen, and the turbulence intensity, and shear stress were analyzed. Notably, the location of the maximum hydrodynamic parameters, that is, the wall shear stress and turbulent intensity, is also the same location with maximum FAC rate. Therefore, the shear stress and turbulence intensity can be used as hydrodynamic parameters that help predict the FAC-induced wall-thinning rate. The results provide a method to identify locations susceptible to FAC and can be useful for determining inspection priority in piping systems.

Enhancement of OH Radical Generation of Dielectric Barrier Discharge Plasma Gas Using Air-automizing Nozzle (이류체 노즐을 이용한 유전체장벽방전 플라즈마 가스의 OH 라디칼 생성 향상)

  • Park, Young-Seek
    • Journal of Environmental Science International
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    • v.27 no.8
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    • pp.621-629
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    • 2018
  • Many chemically active species such as ${\cdot}H$, ${\cdot}OH$, $O_3$, $H_2O_2$, hydrated $e^-$, as well as ultraviolet rays, are produced by Dielectric Barrier Discharge (DBD) plasma in water and are widely use to remove non-biodegradable materials and deactivate microorganisms. As the plasma gas containing chemically active species that is generated from the plasma reaction has a short lifetime and low solubility in water, increasing the dissolution rate of this gas is an important challenge. To this end, the plasma gas and water within reactor were mixed using the air-automizing nozzle, and then, water-gas mixture was injected into water. The dissolving effect of plasma gas was indirectly confirmed by measuring the RNO (N-Dimethyl-4-nitrosoaniline, indicator of the formation of OH radical) solution. The plasma system consisted of an oxygen generator, a high-voltage power supply, a plasma generator and a liquid-gas mixing reactor. Experiments were conducted to examine the effects of location of air-automizing nozzle, flow rate of plasma gas, water circulation rate, and high-voltage on RNO degradation. The experimental results showed that the RNO removal efficiency of the air-automizing nozzle is 29.8% higher than the conventional diffuser. The nozzle position from water surface was not considered to be a major factor in the design and operation of the plasma reactor. The plasma gas flow rate and water circulation rate with the highest RNO removal rate were 3.5 L/min and 1.5 L/min, respectively. The ratio of the plasma gas flow rate to the water circulation rate for obtaining an RNO removal rate of over 95% was 1.67 ~ 4.00.

Effect of Air Flow Rate on the Performance of Planar Solid Oxide Fuel Cell using CFD (평판형 고체산화물 연료전지의 CFD 성능해석에서 공기유량변화의 영향)

  • Kim, Danbi;Han, Kyoungho;Yoon, Do-Young
    • Journal of the Korean Electrochemical Society
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    • v.18 no.4
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    • pp.172-181
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    • 2015
  • Solid Oxide Fuel Cells (SOFC) continue to be among the most promising alternative energy devices. This paper addresses i-V characteristics of SOFC with a focus on air flow rate along the planar anode electrodes. To address this, detailed Butler-Volmer kinetics are implemented in a general-purpose CFD code FLUENT. The numerical results were validated against experimental data from the literature showing excellent match with i-V polarization data ranging 1V-0.4V. Numerical calculations of fuel cell operation under different flow rare conditions were performed in three-dimensional geometries. Results are presented in terms of concentration distribution of hydrogen, oxygen, and water. The simulations and results indicate that advanced CFD with UDF(User-Defined Function) of Butler-Volmer kinetics can be used to identify the conditions leading to air flow rate and specific surface area and guide development of operating conditions and improve the fuel cell system performance.

Maximum Efficiency Point Tracking Algorithm Using Oxygen Access Ratio Control for Fuel Cell Systems

  • Jang, Min-Ho;Lee, Jae-Moon;Kim, Jong-Hoon;Park, Jong-Hu;Cho, Bo-Hyung
    • Journal of Power Electronics
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    • v.11 no.2
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    • pp.194-201
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    • 2011
  • The air flow supplied to a fuel cell system is one of the most significant factors in determining fuel efficiency. The conventional method of controlling the air flow is to fix the oxygen supply at an estimated constant rate for optimal efficiency. However, the actual optimal point can deviated from the pre-set value due to temperature, load conditions and so on. In this paper, the maximum efficiency point tracking (MEPT) algorithm is proposed for finding the optimal air supply rate in real time to maximize the net-power generation of fuel cell systems. The fixed step MEPT algorithm has slow dynamics, thus it affects the overall efficiency. As a result, the variable step MEPT algorithm is proposed to compensate for this problem instead of a fixed one. The complete small signal model of a PEM Fuel cell system is developed to perform a stability analysis and to present a design guideline. For a design example, a 1kW PEM fuel cell system with a DSP 56F807 (Motorola Inc) was built and tested using the proposed MEPT algorithm. This control algorithm is very effective for a soft current change load like a grid connected system or a hybrid electric vehicle system with a secondary energy source.

Proposed Guidelines for Selection of Methods for Erosion-corrosion testing in Flowing Liquids

  • Matsumura, Masanobu
    • Corrosion Science and Technology
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    • v.6 no.6
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    • pp.291-296
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    • 2007
  • The corrosion of metals and alloys in flowing liquids can be classified into uniform corrosion and localized corrosion which may be categorized as follows. (1) Localized corrosion of the erosion-corrosion type: the protective oxide layer is assumed to be removed from the metal surface by shear stress or turbulence of the fluid flow. A macro-cell may be defined as a situation in which the bare surface is the macro-anode and the other surface covered with the oxide layer is the macro-cathode. (2) Localized corrosion of the differential flow-velocity corrosion type: at a location of lower fluid velocity, a thin and coarse oxide layer with poor protective qualities may be produced because of an insufficient supply of oxygen. A macro-cell may be defined as a situation in which this surface is the macro-anode and the other surface covered with a dense and stable oxide layer is the macro-cathode. (3) Localized corrosion of the active/passive-cell type: on a metal surface a macro-cell may be defined as a situation in which a part of it is in a passivation state and another in an active dissolution state. This situation may arise from differences in temperature as well as in the supply of the dissolved oxygen. Compared to uniform corrosion, localized corrosion tends to involve a higher wall thinning rate (corrosion rate) due to the macro-cell current as well as to the ratio of the surface area of the macro-anode to that of the macro-cathode, which may be rationalized using potential vs. current density diagrams. The three types of localized corrosion described above can be reproduced in a Jet-in-slit test by changing the flow direction of the test liquid and arranging environmental conditions in an appropriate manner.

Measurement of mass Transfer Coefficients for Adsorptive Bulk Gas Separation with Velocity Variations (기체속도가 변하는 벌크기체의 흡착공정에서 물질전달계수의 측정)

  • Min, Jun-Ho;Choi, Min-Ho;Suh, Sung-Sup
    • Applied Chemistry for Engineering
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    • v.10 no.2
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    • pp.310-318
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    • 1999
  • The concentration breakthrough curves were examined to predict mass transfer coefficients of nitrogen and oxygen in adsorption column for design data of PSA process. Experimental breakthrough curves for bulk gas flow were compared with theoretical simulation results. For quantitative analysis of the adsorption, coupled Langmuir isotherm was considered and LDF model was used to describe the mass transfer effect. In the experimental and theoretical results, it was found that mass transfer coefficient was not affected by flow rate but strongly affected by pressure. As a result of this tendency, mass transfer resistance in this system was proved to belong to the macropore diffusion controlling region and the mass transfer coefficients could be expressed by exponential functions of pressure change. The mass transfer coefficients for one component, nitrogen or oxygen, were successfully applied to breakthrough curves for bulk mixed gases. The experimental curves were reasonably in consistent with the theoretical curves and the error time was less than 5 percent.

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Calculation and Comparison of Liquid Oxygen Filling System between the KSLV-I Flight Test Data and the Modeling of the KSLV-II Launch Complex (한국형발사체 발사대시스템 산화제공급계 충전 운용 설계의 검증을 위한 나로호 비행시험 실증 자료 분석)

  • Seo, Mansu;Lee, Jae Jun;Hong, Ilgu;Kang, Sunil
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.5
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    • pp.107-114
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    • 2018
  • Korea Space Launch Vehicle (KSLV)-I flight test data and the modified 1-dimensional steady state modeling data from the critical design results of the KSLV-II liquid oxygen filling system operation are compared to validate the reliability of critical design modeling. A comparison of major flow rates and pressure values between test data and calculation results are conducted. The relative errors relative to maximum total flow rate for each cooling, filling, and replenishment mode are determined within 6.7%. Calculated pressure values at the outlet of the pump and the inlet of flow control valves are within 5.1%. The pressure at the inlet of the launch vehicle for each operation mode are within the measured pressure range.

A Study on the Reduction Process of VOCs Emission from Paint Booth - A Hybrid Process of Biotrickling Filter and Activated Sludge Reactor

  • Lim Gye-Gyu
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.E2
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    • pp.41-48
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    • 2005
  • A novel hybrid system composed of a biotrickling filter and an activated sludge reactor was investigated under the conditions of four different SRTs (sludge retention times). The performance of the hybrid reactor was found to be directly comparable among the four different sludge ages. Discernible differences in the removal performance were observed among four different SRTs of 2, 4, 6, and 8 days. High removal efficiency was achieved by continuous circulation of activated sludge over the immobilized mixture culture, which allowed on pH control, addition of nutrients, and removal of paint VOCs (volatile organic compounds). The results also showed that the removal efficiency for a given pollutant depends on the activity of microorganisms based on the SRT. As the SRT increased gradually from 2 to 8 days, the average removal performance decreased. The highest removal rate was achieved at the SRT of 2 days at which the highest OUR (oxygen uptake rate), $6.1mg-O_2/liter-min$ was measured. Biological activity in the recycle microbes decreased to a much lower level, $3.6mg-O_2/liter-min$ at a SRT of 8 days. It is thus believed that young microorganisms were more active and more efficient for the VOCs removal of low concentrations and high flow rates. The apparent correlation of $R^2=0.996$ between the average removal efficiency and the average OUR at each SRTs suggests that VOCs degradation by young cells significantly affected the overall removal efficiency for the tested SRTs.