• Title/Summary/Keyword: Oxide superconductors

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Combination of MCA and SHS for Material Synthesis

  • Soh, Dea-Wha;N., Korobova
    • Journal of the Speleological Society of Korea
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    • no.78
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    • pp.1-8
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    • 2007
  • The combination of mechano-chemical activation (MCA)and Self-propagating High-temperature Synthesis (SHS) has widened the technical possibilities for both methods. For YBCO systems the investigation showed that a short-term MCA of initial powders before SHS leads to single-phase and ultra-fine products. A new technique for preparation ultra-fine high-temperature superconductors (HTS) of YBCO composition with a grain size d <1m is developed using combination of MCA and SHS. The specific feature of the technique is formation of the $YBa_2Cu_3O_7-$ crystalline lattice directly from an X-ray amorphous state arising as a result of mechanical activation of the original oxide mixture. The technique allows the stage of formation of any intermediate reaction products to be ruled out. X-ray and magnetic studies of ultra-fine high temperature superconductors are carried out. Dimension effects associated with the microstructure peculiarities are revealed. A considerable enhancement of inter-grain critical currents is found to take place in the ultra-fine samples.

Combination of Mechano-chemical Activation and SHS for HTS Material Synthesis

  • N. Korobova;Deawha Soh
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2004.05a
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    • pp.96-99
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    • 2004
  • The combination of mechano-chemical activation and Self-propagating High-temperature Synthesis (SHS) has widened the possibilities for both methods. For YBCO systems the investigation showed that a short-term mechano-chemical activation of initial powders before SHS leads to single-phase and ultra-fine products. A new technique for preparation ultra-fine high-temperature superconductors of YBCO composition with a grain size d <1 ${\mu}{\textrm}{m}$ is developed. The specific feature of the technique is formation of the YBa$_2$Cu$_3$O$_{7-{\delta}}$ crystalline lattice directly from an X-ray amorphous state arising as a result of mechanical activation of the original oxide mixture. The technique allows the stage of formation of any intermediate reaction products to be ruled out. X-ray and magnetic studies of ultra-fine high temperature superconductors (HTS) are carried out. Dimension effects associated with the microstructure peculiarities are revealed. A considerable enhancement of inter-grain critical currents is found to take place in the ultra-fine samples.fine samples.

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Improvement of bolometric properties of vanadium oxide by addition of tungsten (텅스텐 첨가에 의한 적외선 소자용 바나듐 옥사이드의 특성 향상)

  • Han, Yong-Hui;Choi, In-Hun;Kim, Geun-Tae;Shin, Hyeon-Jun;Chi, En;Moon, Seong-Uk
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.207-207
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    • 2003
  • Uncooled infrared(IR) detectors that use a microbolometer with a large focal-plane array(FPA) have been developed with surface micromachining technology. There are many materials for microbolometers, such as metals, vanadium oxide, semiconductors and superconductors. Among theses, vanadium oxide is a promising material for uncooled microbolometers due to it high temperature coefficient of resistance(TCR) at room temperature. It is, however, is very difficult to deposit vanadium oxide thin films having a high TCR and low resistance because of the process limits in microbolometer fabrication. In general, vanadium oxides have been applied to microbolometer in mixed phases formed by ion beam deposition methods at low temperature with TCR in the range from -1.5 to -2.0%K.

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Use of High-Temperature Gas-Tight Electrochemical

  • Park, Jong-Hee;Beihai Ma;Park, Eun-Tae
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.103-113
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    • 1998
  • By using a gas-tight electrochemical cell, we can perform high-temperature coulometric titration and measure electronic transport properties to determine the elecronic defect structure of metal oxides. This technique reduces the time and expense required for conventional thermogravimetric measurements. The components of the gas-tight coulometric titration cell are an oxygen sensor, Pt/yttria stabilitized zirconia(YSZ)/Pt, and an encapsulated metal oxide sample. Based on cell design, both transport and thermodynamic measurements can be performed over a wide range of oxygen partial pressure ($pO_2=10^{-35}$ to 1 atm). This paper describes the high-temperature gas-tight electrochemical cells used to determine electronic defect structures and transport properties for pure and doped-oxide systems, such as YSZ, doped and pure ceria $(Ca-CeO_2 \;and\; CeO_2)$, copper oxides and copper-oxide-based ceramic superconductors, transition metal oxides, $SrFeCo_{0.5}O_x,\; and \;BaTiO_2$.

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Synthesis of YBa2Cu3O7-y Powder using a Powder Reaction Method and Fabrication of the Bulk Superconductors (분말 반응법에 의한 YBa2Cu3O7-y 합성과 벌크 초전도체의 제조)

  • Jeon, Young Ju;Park, Seung Yeon;You, Byung Youn;Park, Soon-Dong;Kim, Chan-Joong
    • Journal of Powder Materials
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    • v.20 no.2
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    • pp.142-147
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    • 2013
  • $YBa_2Cu_3O_{7-y}$ (Y123) powders for the fabrication of bulk superconductors were synthesized by the powder reaction method using $Y_2O_3$ (99.9% purity), $BaCO_3$ (99.75%) and CuO (99.9%) powders. The raw powders were weighed to the cation ratio of Y:Ba:Cu=1:2:3, mixed and calcined at $880^{\circ}C-930^{\circ}C$ in air with intermediate repeated crushing steps. It was found that the formation of Y123 powder was more sensitive to reaction temperature than reaction time. The calcined Y123 powder and a mixture of (Y123 + 0.25 mole $Y_2O_3$ + 1 wt.% $CeO_2$, $Y_{1.5}Ba_2Cu_3O_x$ (Y1.5)) were used as raw powders for the fabrication of poly-grain or single grain superconductors. The superconducting transition temperature ($T_{c,onset}$) of the sintered Y123 sample was 91 K and the transition width was as large as 11 K, whereas the $T_{c,onset}$ of the melt-grown Y1.5 sample was 90.5 K and the transition width was 3.5 K. The critical current density ($J_c$) at 77 K and 0 T of the sintered Y123 was 700 $A/cm^2$, whereas the $J_c$ of the top-seeded melt growth (TSMG) processed Y1.5 sample was $3.2{\times}10^4\;A/cm^2$. The magnetic flux density (H) at 77 K of the TSMG-processed Y123 and Y1.5 sample showed the 0.53 kG and 2.45 kG, respectively, which are 15% and 71% of the applied magnetic field of 3.5 kG. The high H value of the TSMG-processed Y1.5 sample is attributed to the formation of the larger superconducting grain with fine Y211 dispersion.

Texturing of Cu Sheets and Fabrication of Oxide Buffer Layers for YBCO Superconductor Films (YBCO 초전도체막을 위한 Cu 판의 배향화 및 중간 산화층의 제조)

  • Kim, Myeong-Hui;Kim, Eun-Gene;Han, Sang-Chul;Sung, Tae-Hyun;Kim, Sang-Joon;No, Kwang-Soo
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.352-357
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    • 1999
  • The Cu sheets were selected for the substrate of the superconductor films. Pure Cu sheets with the thickness of 50${\mu}$m were fabricated using hot and cold rolling. The Cu sheets were heat treated to induce the biaxial texturing. The z-axis and x-y plane texturing of Cu sheets heat treated at different conditions were analyzed using XRD and a best heat treatment condition for the texturing was selected. ZrO$_2$ film was dip coated on Cu sheets heat treated at the best condition to prevent possible reaction between Cu sheets and YBCO superconductors, to reduce possible cracking due to thermal expansion mismatch and to decrease the lattice mismatch for biaxial texturing. The texturing of the oxide buffer layers were also studied.

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Normal-zone Propagation Properties in Oxide Superconductors (산화물 초전도선재의 상전도전파특성)

  • Kim, Seok-Beom;Ishiyama, Atsushi;Han, Kyung-Hee
    • Proceedings of the KIEE Conference
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    • 1996.07a
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    • pp.41-43
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    • 1996
  • This paper describes on concerning electromagnetical and thermal behaviors during normal transition in Bi-2223/Ag superconducting multifilamentary tapes by conduction cooling. Some experiments were carried with operating temperature, 10-40K, and transport current as parameters in zero magnetic field. Sample tapes are transited normally with heater to intiate a quench. The voltage and temperature properties which accord to normal transition are measured by voltage taps and thermocouples attached to sample tapes, we also calculated longitudinal and transverse directions normal-zone propagation velocities from the voltage traces.

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High $T_c$, Superconductors for Applications

  • Soh, Deawha;Fan, Zhanguo
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2003.05a
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    • pp.366-369
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    • 2003
  • High T$_{c}$ superconducting lines will be applied as key materials in the areas of power transmission line; magnetic levitation of vehicle; magnetic separation; magnetic energy storage and marine propulsion. A combination method of electrophoresis deposition and zone-melting for preparation of YBaCuO tape is proposed. The submicron particle powder of YBaCuO made by sol-gel method is used in the electrophoresis process. A 40~50${\mu}{\textrm}{m}$ thickness of YBaCuO film on Ag plate could be deposited in about three minutes. After deposition the film is rolled and heat treated in order to increase the density and the adhesion of the film to the Ag plate. Silver(Ag) and lead oxide(PbO) were added in the YBaCuO powder in order to reduce its melting point. The YBaCuO coating with controlled Ag and PbO contents was preliminarily zone-melted at about 945$^{\circ}C$.>.

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Evaluation of Mechanical Properties in Bi-2223 Composite Superconducting Tapes (Bi-2223산화물 복합 초전도 테이프의 기계적 특성 평가)

  • 신형섭;최수용
    • Progress in Superconductivity and Cryogenics
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    • v.3 no.2
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    • pp.1-4
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    • 2001
  • For the practical use of a superconducting wire to magnet application, it is important to assess the Young modulus and other mechanical properties of HTS tapes. In order to establish a test method of mechanical properties for oxide composite superconductors. tensile tests of Bi-2223 multi- filamentary tapes were carried out at room temperature, as an activity of the International round robin test proposed by the committee of VAMAS/TWA 16-Subrgroup. The tapes consisting of mutli-filamentary showed a three stage tensile behavior. At the initial stage of the stress-streain curve. The elastic deformation existed in a quite nattrow strain region. But the plastic deformation was observed in a wide strain region due to the platic flow of the Ag alloy matrix. The results of RRT were also reported and discussed.

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Factors Affecting the Superconducting Transition Temperatures of β-Pyrochlore Oxides AOs2O6 (A=K, Rb and Cs)

  • Jung, Dong-Woon
    • Bulletin of the Korean Chemical Society
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    • v.32 no.2
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    • pp.451-454
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    • 2011
  • The traditional BCS superconductors $AOs_2O_6$ (A=K, Rb, and Cs) were investigated to find the relationship between their structures and superconducting transition temperatures. The $T_c$ decreases with increasing the unit cell parameter of $AOs_2O_6$. This is in contrast to the case of conventional BCS superconductivity in a single bond model, where $T_c$ may increase with increasing the the unit cell parameter since the DOS at Fermi level increases as the unit cell parameter increases. Instead, the $T_c$ of a $\beta$-pyrochlore oxide is proportional to the lattice softness of the compound.