• Title/Summary/Keyword: Oxide superconductor

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Magnetic Suspension Effect of Oxide Superconductor (산화물 초전도체의 자기효과)

  • Lee, Sangl-Heon;Lee, Sung-Gap;Lee, Young-Hie
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.04b
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    • pp.199-202
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    • 2004
  • Suspension effect has been studied by using superconductor of BiPbSrCaCuO ceramics containing $Ag_2O$. It has been c1eared that $Ag_2O$ acts as pinning center which plays an important role to the suspension effect. Magnetic repulsive force which affects a superconductor located in magnetic flux from toroidal magnet has been investigated. It has been concluded that the suspension effect arises from the interaction between the pinning effect and the diamagnetic effect.

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Microstructure and Properties of High Tc Superconductor fabricated by Hot Isostatic Pressing (열간정수압소결(HIP) 시킨 고온초전도체의 조직과 특성)

  • Song, Jin-Tae;Akihama, Ryozo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1988.05a
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    • pp.17-19
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    • 1988
  • $YBa_2Cu_3O_{7-x}$ oxide superconductors were fabricated by the hot isostatic pressing (HIP). It was shown that their structures were orthorombic and constited of a single (123) phase. While as-sintered compacts had many pores, they were remarkably reduced by Hiping. The on-set and off set temperature of (123) compound sintered at $950^{\circ}C$ in oxygen and hiping at $880^{\circ}C$ were the highest and it showed 0 resistance at $90^{\circ}K$. The critical current density ($J_c$) of the above superconductor was $27A/cm^2$ and it also showed a number of twin structures, which are typical of high $T_c$ superconductor. It seemed that the low current density may be due to the many pores of starting-sintered compacts.

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The crystal structure transition in YBCO superconductor by Rietveld analysis Method (Rietveld 해석법에의한 YBCO 초전도체의 결정 구조 전이 연구)

  • 채기병;전용우;소대화
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.239-243
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    • 1996
  • In this paper, we have tried to focus on the optimum conditions of crystal structure parameters on YBCO high Tc oxide-superconductor as an excel lent electronic parts. When we verify the characteristic improvement of superconductance and accurate reproduction and so forth, we have made use of RIETAN. We have varied the lattice constant with oxygen content from 6.0 to 7.0 as for transition of orthogonal structure and tetragonal structure for the superconductor. As the result of above, we have preyed that transition from orthogonal structure to tetragonal structure is made at the point of 6.6(oxygen content) by using the simulation.

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Fabrication of Bulk High-Tc Superconductor (벌크형 고온 초전도 합성)

  • Lee, Sang Heon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.34 no.5
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    • pp.333-336
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    • 2021
  • Oxide YBCO bulk superconductors are manufactured using the melt process. Because seed crystal growth method utilizes a slow-spreading layer-by-layer reaction, a long-term heat treatment is required to manufacture a single-crystal specimen of several cm. In this study, the melt process method was applied to compensate for the shortcomings of the seed crystal growth method. The thickness of the upper and lower pellets of the YBCO bulk was molded to 40 mm, and YBCO superconductor was produced by heat treatment. The measurement results of capture magnetism was in line with the literature. This results in a relationship that the higher the growth of Y211 particle in the YBCO, the higher the superconducting properties. We analyzed the YBCO superconductor, focusing on the Y2BaCuO5 particle distribution.

Fabrication and characterization of metal oxide films on textured metal substrates (배향화된 금속기관에서 산화물막의 제조와 분석)

  • Choi, Eun-Chul;Hong, In-Ki;Lee, Chang-Ho;Sung, Tae-Hyun;No, Kwang-Soo
    • 한국초전도학회:학술대회논문집
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    • v.10
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    • pp.111-120
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    • 2000
  • Recently, metal oxide films such as MgO or ZrO$_2$ have been studied as buffer layers to fabricate the superconductor with preferred orientation and as diffusion barriers to prevent the reaction between superconductor and metal substrate. In this research, we focused fabrication and characterization of MgO and ZrO$_2$ films on textured metal substrates. We fabricated MgO and ZrO$_2$ films on the Ni metal sheets by sol-gel dipping method. The microstrcures of the films were investigated by SEM and AES analyses. The films were coated with different cycles and dryed at 400$^{\circ}$C and 500$^{\circ}$C . The final films were heat-treated at 700$^{\circ}$C, 800$^{\circ}$C, and 1000$^{\circ}$C, in air atmosphere. We investigated the alignment of MgO and ZrO$_2$ films on Ni metal sheets by XRD and pole figure. The grain growth of metal oxide films was improved by the increase of the drying temperature and annealing temperature. The grain growth was increased with the annealing temperature. The alignment of metal oxide films depended on the thickness.

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Joining Characteristics of Plasma Sprayed BSCCO Superconducting Coatings (플라즈마 용사 BSCCO(Bismuth Strontium Calcium Copper Oxide) 초전도 피막의 접합 특성)

  • Park, Jung-Sik;Cho, Chang-Eun;Ko, Young-Bong;Park, Kwang-Soon;Park, Kyeung-Chae
    • Journal of Surface Science and Engineering
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    • v.46 no.5
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    • pp.181-186
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    • 2013
  • We performed plasma spraying for 2001 (Bi:Cu = 2:1), 0212 (Sr:Ca:Cu = 2:1:2) oxide powders. $Bi_2Sr_2CaCu_2Ox$ (2212) superconductor has been prepared by PMP-AT (partial melting process-annealing treatment). The 2212 phase is synthesized between Sr-Ca-Cu oxide coating layer (0212) and Bi-Cu oxide coating layer (2001) by movement of partial melted Bi on 2001 layer and the diffusion reaction (Cu, Sr, Ca) after PMP-AT. There are two different coating layers on joining process. The one is ABAB coating layers and the other is BAAB coating layers by arrangement of 2001 (A), 0212 (B) layers. We performed heat treatment these two different coating layers processes under same PMP-AT conditions. We obtained Bi-2212 superconducting layers at each experimental condition, and the result of MPMS, the critical temperature was showed about 78 K. But the microstructure images and result of EDS as each experimental variable were showed about the qualitatively different Bi-2212 superconducting phases. We also deduced the generation mechanism of Bi-2212 superconducting layer as a result of these experimental data, microstruc ture images, EDS data and phase diagram.

Texturing of Cu Sheets and Fabrication of Oxide Buffer Layers for YBCO Superconductor Films (YBCO 초전도체막을 위한 Cu 판의 배향화 및 중간 산화층의 제조)

  • Kim, Myeong-Hui;Kim, Eun-Gene;Han, Sang-Chul;Sung, Tae-Hyun;Kim, Sang-Joon;No, Kwang-Soo
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.352-357
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    • 1999
  • The Cu sheets were selected for the substrate of the superconductor films. Pure Cu sheets with the thickness of 50${\mu}$m were fabricated using hot and cold rolling. The Cu sheets were heat treated to induce the biaxial texturing. The z-axis and x-y plane texturing of Cu sheets heat treated at different conditions were analyzed using XRD and a best heat treatment condition for the texturing was selected. ZrO$_2$ film was dip coated on Cu sheets heat treated at the best condition to prevent possible reaction between Cu sheets and YBCO superconductors, to reduce possible cracking due to thermal expansion mismatch and to decrease the lattice mismatch for biaxial texturing. The texturing of the oxide buffer layers were also studied.

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Technique development of Bi-2212/2223 superconductor thick film manufacturing by plasma spraying and heat treatment (플라즈마 용사 및 열처리 공정을 통한 Bi-2212/2223 초전도체 thick film 제조의 기술 개발)

  • Lee, Seon-Hong;Cho, Sang-Hum;Ko, Young-Bong;Park, Kyeung-Chae
    • Proceedings of the KWS Conference
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    • 2005.11a
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    • pp.262-264
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    • 2005
  • $Bi_{2}Sr_{2}CaCu_{2}O_{x}$(Bi-2212) and $Bi_{2}Sr_{2}Ca_{2}Cu_{3}O_{y}$(Bi-2223) high-$T_{c}$ superconductor(HTS) coating have been prepared by plasma spraying and heaat treatment. The Bi-2212 HTS coating later is synthesized through the peritectic reaction between Sr-Ca-Cu oxide coating layer and Bi-Cu oxide coating later, and $Bi_{2}Sr_{2}CaCu_{2}O_{y}$(Bi-2212) superconducting phase grow by partial melting process. The superconducting characteristic depends strongly on the conditions of the partial melting process. the Bi-2212 HTS layer consists of the whiskers grown in the diffusion direction. Above the 2212 layer, Bi-2223 phase and secondary phase was observed. The secondary phase is distributed uniformly over the whole surface. This is caused to the microcrack on the coatings surface. Despite everything, the film shows superconducting with an onset $T_{c}$ of about 115K. There are two changes steps. One changes (1step) at 115K is due to the diamagnetism of the Bi-2223 phase and the other changes (2step) at 78K is due to the diamagnetism of the Bi-2212 phase.

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