• 제목/요약/키워드: Oxide loss

검색결과 481건 처리시간 0.026초

Improved Electrical Properties of Graphene Transparent Conducting Films Via Gold Doping

  • Kim, Yoo-Seok;Song, Woo-Seok;Kim, Sung-Hwan;Jeon, Cheol-Ho;Lee, Seung-Youb;Park, Chong-Yun
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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    • pp.388-388
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    • 2011
  • Graphene, with its unique physical and structural properties, has recently become a proving ground for various physical phenomena, and is a promising candidate for a variety of electronic device and flexible display applications. The physical properties of graphene depend directly on the thickness. These properties lead to the possibility of its application in high-performance transparent conducting films (TCFs). Compared to indium tin oxide (ITO) electrodes, which have a typical sheet resistance of ~60 ${\Omega}/sq$ and ~85% transmittance in the visible range, the chemical vapor deposition (CVD) synthesized graphene electrodes have a higher transmittance in the visible to IR region and are more robust under bending. Nevertheless, the lowest sheet resistance of the currently available CVD graphene electrodes is higher than that of ITO. Here, we report an ingenious strategy, irradiation of MeV electron beam (e-beam) at room temperature under ambient condition,for obtaining size-homogeneous gold nanoparticle decorated on graphene. The nano-particlization promoted by MeV e-beam irradiation was investigated by transmission electron microscopy, electron energy loss spectroscopy elemental mapping, and energy dispersive X-ray spectroscopy. These results clearly revealed that gold nanoparticle with 10~15 nm in mean size were decorated along the surface of the graphene after 1.0 MeV-e-beam irradiation. The fabrication high-performance TCF with optimized doping condition showed a sheet resistance of ~150 ${\Omega}/sq$ at 94% transmittance. A chemical transformation and charge transfer for the metal gold nanoparticle were systematically explored by X-ray photoelectron spectroscopy and Raman spectroscopy. This approach advances the numerous applications of graphene films as transparent conducting electrodes.

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Applications of Smartphone Cameras in Agriculture, Environment, and Food: A review

  • Kwon, Ojun;Park, Tusan
    • Journal of Biosystems Engineering
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    • 제42권4호
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    • pp.330-338
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    • 2017
  • Purpose: The smartphone is actively being used in many research fields, primarily in medical and diagnostic applications. However, there are cases in which smartphone-based systems have been developed for agriculture, environment, and food applications. The purpose of this review is to summarize the research cases using smartphone cameras in agriculture, environment, and food. Methods: This review introduces seventeen research cases which used smartphone cameras in agriculture, food, water, and soil applications. These were classified as systems involving "smartphone-camera-alone" and "smartphone camera with optical accessories". Results: Detecting food-borne pathogens, analyzing the quality of foods, monitoring water quality and safety, gathering information regarding plant growth or damage, identifying weeds, and measuring soil loss after rain were presented for the smartphone-camera-alone system. Measuring food and water quality and safety, phenotyping seeds, and soil classifications were presented for the smartphone camera with optical accessories. Conclusions: Smartphone cameras were applied in various areas for several purposes. The use of smartphone cameras has advantages regarding high-resolution imaging, manual or auto exposure and focus control, ease of use, portability, image storage, and most importantly, programmability. The studies discussed were achieved by sensitivity improvements of CCDs (charge-coupled devices) and CMOS (complementary metal-oxide-semiconductor) on smartphone cameras and improved computing power of the smartphone, respectively. A smartphone camera-based system can be used with ease, low cost, in near-real-time, and on-site. This review article presents the applications and potential of the smartphone and the smartphone camera used for various purposes in agriculture, environment, and food.

뫼스바우어선원적용을 위한 전기도금과 열처리기법을 이용한 Co가 확산된 Cu기지체 제조 (Synthesis of Co Diffused Cu Matrix by Electroplating and Annealing for Application of Mössbauer Source)

  • 최상무;엄영랑
    • 한국자기학회지
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    • 제24권6호
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    • pp.186-190
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    • 2014
  • 뫼스바우어 선원 $^{57}Co/Cu$의 제조조건을 도출하기 위하여, 금속 분말 코발트(Co)를 황산에 용해시킨 후 $H_3BO_3$, KOH와 NaCl을 첨가하여 Sulfamate 도금용액을 제조 후 Cu plate 기판에 도금하였다. 도금두께는 $4{\mu}m$로 일정하게 유지하였다. 전류밀도를 $2mA/cm^2$$30mA/cm^2$로 유지하면서 pH에 변화를 준 결과 pH가 4 이상으로 증가하면 hcp 결정의 Co 금속 이외의 2차상이 생성되었다. pH가 증가할수록 Co 후막 표면이 거칠어 졌으며 균열된 표면형상을 관찰하였다. pH가 5까지 증가할 경우 평균입도는 54 nmfh 증가함을 확인하였다. 열처리조건을 변화시키면서 Co가 Cu기지 내에 구속되는 온도가 $900^{\circ}C$에서 2 h임을 확인하였다. 열처리는 진공 후 Ar 분위기(1.5 l/min)를 유지하면서 수행하였다.

전사지를 이용 적층한 셀 구조 및 연료극 기능층 형성에 따른 출력 특성 (Power Densities According to Anode Functional Layers on the Manufactured SOFC Unit Cells Using Decalcomania Method)

  • 안용태;지미정;구자빈;최진훈;황해진;최병현
    • 한국재료학회지
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    • 제22권11호
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    • pp.626-630
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    • 2012
  • The properties of SOFC unit cells manufactured using the decalcomania method were investigated. SOFC unit cell manufacturing using the decalcomania method is a very simple process. In order to minimize the ohmic loss of flattened tube type anode supports of solid oxide fuel cells(SOFC), the cells were fabricated by producing an anode function layer, YSZ electrolyte, LSM electrode, etc., on the supports and laminating them. The influence of these materials on the power output characteristics was studied when laminating the components and laminating the anode function layer between the anode and the electrolyte to improve the output characteristics. Regarding the performance of the SOFC unit cell, the output was 246 $mW/cm^2$ at a temperature of $800^{\circ}C$ in the case of not laminating the anode function layer; however, this value was improved by a factor of two to 574 $mW/cm^2$ due to the decrease of the ohmic resistance and polarization resistance of the cell in the case of laminating the anode function layer. The outputs appeared to be as high as 574 and 246 $mW/cm^2$ at a temperature of $800^{\circ}C$ in the case of using decalcomania paper when laminating the electrolyte layer using the in dip-coating method; however, the reason for this is that interfacial adhesion was improved due to the dense structure, which leads to a thin thickness of the electrolyte layer.

An Analog of the Antimicrobial Peptide CopA5 Inhibits Lipopolysaccharide-Induced Macrophage Activation

  • Yoon, I Na;Hong, Ji;Zhang, Peng;Hwang, Jae Sam;Kim, Ho
    • Journal of Microbiology and Biotechnology
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    • 제27권2호
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    • pp.350-356
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    • 2017
  • We previously reported that the CopA3 peptide (LLCIALRKK, ${\small{D}}-form$) originally isolated from the Korean dung beetle has antimicrobial and immunosuppressive effects. However, the high cost of producing the synthetic peptide, especially the ${\small{D}}-form$, has limited the development of CopA3 for therapeutic purposes. Here, we investigated whether the CopA3 deletion derivative, CopA5, which is composed of only five amino acids (LLCIA) and has the ${\small{L}}-form$ structure, could inhibit the lipopolysaccharide (LPS)-induced activation of macrophages. Peritoneal exudate macrophages (PEM) were isolated from mice and exposed to LPS in the presence or absence of CopA5, and biomarkers of macrophage activation were measured. Our results revealed that LPS-induced nitric oxide (NO) production, tumor necrosis factor $(TNF)-{\alpha}$ secretion, and phagocytic activity of PEM were significantly inhibited by CopA5 treatment. Similar to CopA3, the structurally modified CopA5 peptide had no cell toxicity (as assessed by measurement of cell viability loss and apoptosis) in PEM. Moreover, the LPS-induced upregulation of the activating phosphorylation of signal transducer and activator of transcription 1 (STAT1) was markedly inhibited by CopA5 treatment. These results suggest that, similar to CopA3, CopA5 inhibits macrophage activation by inhibiting STAT1 phosphorylation and blocking the release of NO and $TNF-{\alpha}$. CopA5 may therefore prove therapeutically useful in the realm of immune suppression.

Korean red ginseng extract alleviates advanced glycation end product-mediated renal injury

  • Quan, Hai Yan;Kim, Do Yeon;Chung, Sung Hyun
    • Journal of Ginseng Research
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    • 제37권2호
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    • pp.187-193
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    • 2013
  • The effect of Korean red ginseng (KRG) on diabetic renal damage was investigated using streptozotocin (STZ)-induced diabetic rats. The diabetic rats showed loss of body weight gain, and increases in kidney weight and urine volume, whereas the oral administration of KRG at a dose of 100 or 250 mg/kg of body weight per day for 28 d prevented these diabetes-induced physiological abnormalities. Among the kidney function parameters, elevated plasma levels of urea nitrogen and creatinine in diabetic control rats tended to be lowered in KRG-treated rats. In addition, administration of KRG at a dose of 100 mg/kg body weight in the diabetic rats showed significant decreases in serum glucose and tumor necrosis factor-${\alpha}$ (TNF-${\alpha}$), implying that KRG might prevent the pathogenesis of diabetic complications caused by impaired glucose metabolism and oxidative stress. KRG also significantly reduced advanced glycation end product (AGE) formation and secretion from kidney of diabetic rats. Furthermore, KRG decreased the levels of N-(carboxymethyl) lysine and expression of AGE receptor. KRG also reduced the overexpression of cyclooxygenase-2 and inducible nitric oxide synthase in the kidney via deactivation of nuclear factor-kappa B. We also found that KRG prevented STZ-induced destruction of glomerular structure and significantly suppressed high glucose-induced fibronectin production. Taken together, KRG ameliorates abnormalities associated with diabetic nephropathy through suppression of inflammatory pathways activated by TNF-${\alpha}$ and AGEs. These findings indicate that KRG has a beneficial effect on pathological conditions associated with diabetic nephropathy.

자동차 차체 보호를 위한 산화방지 장치의 성능 평가 (Performance Evaluation of Antioxidizing Device for Protection of Car Body)

  • 김해식;윤영진;지종기
    • 대한화학회지
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    • 제46권5호
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    • pp.444-456
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    • 2002
  • 차체의 산화를 방지하기 위하여 희생적 양극을 사용한 산화방지 장치를 개발하였다. 희생적 양극은 철보다 산화 전위가 높은 Mg, Al, Zn으로 만들어 졌고 이것은 차체의 철이나 철합금보다 먼저 산화되어 차체의 부식을 방지한다. 차체 산화방지 장치를 제작하여 철시편을 염산, 질산 및 황산에 대한 방식효과를 시간에 따라 측정하였고 SEM과 XPS를 이용하여 철시편 표면의 방식효과를 분석하였다. 철시편을 산화 방지 장치에 연결하면 산화되어 산성용액 속으로 녹아 들어가는 철의 양이 현저하게 감소하고 철시편 표면의 산화가 방지되며 산화된 철은 $Fe_2O_3$의 산화형태를 가짐을 확인하였다. 따라서 차체 산화방지를 차체에 직접 부착한다면 차체의 부식 및 산화를 효과적으로 방지할 것으로 기대된다.

공기-분말 연마와 구연산의 적용시간에 따른 임프란트 표면 거칠기의 변화에 관한 주사탐침현미경적 연구 (The SPM Study on the Change of Titanium Surface Roughness following Airpowder Abrasive and Application Time of Citric Acid)

  • 박민서;정진형;임성빈
    • Journal of Periodontal and Implant Science
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    • 제30권4호
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    • pp.821-836
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    • 2000
  • The Peri-implantitis causes inflammation of periodontal tissue and bone loss. It contaminates surface of implants. Therefore, guided bone regeneration has been used for the treatment of this disease. For the reosseointegration of the exposed surface, various mechanical and chemical methods have been used for cleaning and detoxication of implant surface. Among these methods, air-powder abrasive and oversaturated citrate are known to be most effective. However, these treatments may deform implant surface. In this research, changes of surface roughness they were examined. 10 experimental machined titanium cylinder models were fabricated to be used for control groups. Each of them was air powder abraded for 1 minute and they were named group 1. And then, group 1 were burnished with cotton pellets soaked with citrate for 30 seconds(Group 2), 1 minute(Group 3), 3 minutes(Group 4), and 5 minutes(Group 5) burnishing were applied for grouping respectively. Each group were examined with SPM, and their surface roughness were measured and analyzed. 1. Surface roughness of titanium decreased when it was air-powder abraded for 1 minute. It was statistically significant. 2. When Air-powder abraded titanium were treated with citrate for 3 minutes, Their surface roughness was the lowest. Titanium treated for 1 minute was the second lowest and 30 seconds was the third and titanium burnished for 5 minutes was the highest. 3. Surface roughness of titanium which was treated with citrate was decreased till 3 minutes, which was statistically significant. There was no statistical significance from 30 seconds to 1 minute and from 1 minute to 3 minutes, and there was statistical significance from 30 seconds to 3 minutes. 4. Oxide layer was formed when titanium is exposed to air, and it was removed when air-powder abraded. It was made when treated with citrate. It is thought that citrate treatment is necessary after the air-powder abrasion, and 1 minute is clinically and qualitatively adequate for burnishing time of citrate.

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중.저온헝 SOFC를 위한 Ni-YSZ 연료극 지지체형 단전지 미세구조와 전기적 특성 (Microstructure and Electrical Properties of Single Cells Based on a Ni-YSZ Cermet Anode for IT-SOFCs)

  • 박재근;양수용;이태희;오제명;유영성;박진우
    • 한국세라믹학회지
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    • 제43권12호
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    • pp.823-828
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    • 2006
  • One of the main issues of Solid Oxide Fuel Cells (SOFCs) is to reduce the operating temperature to $750^{\circ}C$ or less. It has advantages of improving the life of component parts and the long-term stability of a system, so the production cost could be decreased. In order to achieve that, the ohmic and polarization loss of a single cell should be minimized first. This paper presents.to fabricate anode-supported single cells with controlling microstructure as a function of particle size and volume of graphite and NiO-YSZ weight ratio. By means of optimizing the manufactural condition through microstructure analysis and performance evaluation, the single cell which had NiO-YSZ=6:4, graphite volume of 24% and graphite size of $75{\mu}m$ as the anode composition showed a distinguished power density of $510mW/cm^2$ at $650^{\circ}C$ and $810mW/cm^2$ at $700^{\circ}C$, respectively.

2 모듈 스택을 이용한 5kW급 SOFC 시스템 운전결과 (Operation Results of a 5kW-Class SOFC System Composed of 2 Sub-Module Stacks)

  • 이태희;최미화;유영성
    • 한국수소및신에너지학회논문집
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    • 제22권5호
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    • pp.609-615
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    • 2011
  • A 5 kW class SOFC system for cogeneration power units was consisted of a hot box part and cold BOPs. High temperature components such as a stack, a fuel reformer, a catalytic combustor, and heat exchanges are arranged in the bot box considering their operating temperatures for the system efficiency. The hot box was made of ceramic boards for the thermal insulation. A 5 kW class SOFC stack was composed of 2 sub-modules and each module had 64 cells with $15{\times}15cm^2$ area and stainless steel interconnects. The 5 kW class SOFC system was operated with a hydrogen and a city gas. With a hydrogen, the total power of the stacks was about 7.1 kWDC and electrical efficiency was about 49.3% at 80 A. With a city gas, the total power of the stacks was about 5.7 $kW_{DC}$ and electrical efficiency was about 38.8% at 60 A. Under self-sustained operating condition, the system efficiency including a power conditioning loss and a consumed power by BOPs was about 30.2%.