• Title/Summary/Keyword: Oxide Fuel

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Combustion and Emissions Characteristics of a Diesel Engine with the Variation of the HP/LP EGR Proportion (고압/저압 EGR 공급 비율에 따른 디젤 엔진의 연소 및 배기 특성)

  • Park, Youngsoo;Bae, Choongsik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.7
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    • pp.90-97
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    • 2014
  • The effects of high pressure and low pressure exhaust gas recirculation (HP/LP EGR) portion on diesel engine combustion and emissions characteristics were investigated in a 2.2 L passenger-car diesel engine. The po3rtion of HP/LP EGR was varied from 0 to 1 while fixing the mass flow rate of fresh air. The intake manifold temperature was lowered with the increasing of the portion of LP EGR, which led to the retardation of heat release by pilot injection. The lowered intake manifold temperature also resulted in low nitrogen oxide (NOx) emissions due to decreased in-cylinder temperature and prolonged ignition delay, however, the carbon monoxide (CO) emission showed opposite trend to NOx emissions. The brake specific fuel consumption (BSFC) was decreased as the portion of LP EGR increased due to lowered exhaust manifold pressure by wider open of turbocharger vane. Consequently, the trade-off relationship between NOx and BSFC could be improved by increasing the LP EGR portion.

Preparation and Characteristics of $La_{1-x}Sr_xCoO_3$ Cathode material as function of Sr mole fraction in SOFC (SOFC의 Sr 첨가량에 따른 $La_{1-x}Sr_xCoO_3$ Cathode 재료의 제조 및 특성 연구)

  • Park, J.H.;Eom, S.W.;Moon, S.I.;Park, T.G.;Yun, M.S.
    • Proceedings of the KIEE Conference
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    • 1994.11a
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    • pp.202-204
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    • 1994
  • Nowadays Perovskite $La_{1-x}Sr_xCoO_3$ is a preferred cathode material in the construction Solid Oxide Fuel Cell (SOFC). The $La_{1-x}Sr_xCoO_3$ with Sr contents ranging from X=0.0 to X=1.0 were prepared by a citrate method. All samples were examined by X-ray powder diffraction. The samples used for measuring thermal expansion were prepared as pellets by cold pressing and subsequent sintering in air at $1200^{\circ}C$ for 5 hours. To measure the sub-product of $La_{1-x}Sr_xCoO_3$ with YSZ, where coating films were sintered at $1200^{\circ}C$ for 5 hour.

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Characterization of (La,Sr))$MnO_3/Gd_{0.2}Ce_{0.8}O_{1.9}$ Interface with Citric Acid Contents and Sintering Temperature (시트르산의 양과 소결온도에 따른 (La,Sr)$MnO_3/Gd_{0.2}Ce_{0.8}O_{1.9}$ 계면특성)

  • 윤일영;윤희성;김병호
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.1
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    • pp.18-25
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    • 1998
  • G $d_{0.2}$C $e_{0.8}$ $O_{1.9}$(CGO) for electrolyte and L $a_{0.5}$S $r_{0.5}$Mn $O_3$(LSM50) for cathode in Solid Oxide Fuel Cells(SOFC) were synthesized by citrate process. Specimens were prepared with sintering temperatures at 110$0^{\circ}C$, 120$0^{\circ}C$ and 130$0^{\circ}C$, which were fabricated by slurry coating with citric acid contents. Interfacial resistance was measured between cathode and electrolyte using AC-impedance analyzer. With various citric acid content, the degree of agglomeration for the initial particles changed. Also sintering temperature changed the particle size and the degree of densification of cathode. Factors affecting the interfacial resistance were adherent degree of the electrolyte and cathode, distribution of TPB(three phase boundaries, TPB i.e., electrolyte/electrode/gas phase area) and porosity of cathode. By increasing the sintering temperature, particle size and densification of the cathode were increased. And then, TPB area which occurs catalytic reaction was reduced and so interfacial resistance was increased.sed.sed.d.

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Determination of Chemical Compositions and Oxidation States for Corrosion Products in LiCl Molten Salts

  • Park, Yong-Joon;Pyo, Hyung-Ryul;Kim, Do-Yang;Jee, Kwang-Yong;Kim, Won-Ho
    • Nuclear Engineering and Technology
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    • v.32 no.5
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    • pp.514-520
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    • 2000
  • The mechanism of corrosion behavior has to be understood clearly to select an optimum material for handling molten salts to be used in the oxide reduction process of PWR spent fuel. In this study, the oxidation states of corrosion products on the surface of Inconel 600 and 800H as well as their chemical compositions and structural informations were determined by using XPS, ICP-AES, AAS, EPMA and XRD after the corrosion experiment with lithium molten salts at 75$0^{\circ}C$ for 25 hours. Nickel and oxygen were detected from the corrosion products on the surface of Inconel plates and chromium was found to be dissolved out into lithium molten salts leaving cracks on the surface. The corrosion products were identified as metal oxides such as Fe$_2$O$_3$, Cr$_2$O$_3$, NiO, NiFe$_2$O$_4$and MnO by using XPS and XRD.

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An Experimental Study on Heat Transfer Characteristics of Synthetic Gas($H_2/CO$)Air Premixed Flames in an Impinging Jet Burner - Part 1 : Stretched Lift-off Flames (충돌제트 버너에서 합성가스($H_2/CO$) 공기 예혼합 화염의 열전달 특성에 관한 실험적 연구 - Part 1 : 스트레치된 부상 화염)

  • Kang, Ki-Joong;Jo, Joon-Ik;Lee, Kee-Man
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.04a
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    • pp.453-456
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    • 2011
  • An experimental investigation of the heat transfer characteristics of stretched premixed flames using Synthetic gas has been performed. Hydrogen and carbon mon-oxide which could be extracted from coal gasification process are the main fuel of synthetic-gas. Heat flux at the stagnation point was increased as global strainrate was increased, then the heat flux was decreased when a global strainrate reached a sudden point. Heat flux at the stagnation point is also affected by nozzle to impingement distance. Heat flux was increased as nozzle to impingement place distance was increased. This study is a foundation study of practical use of secondary gases from coals.

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Performance of cyclone separator for syngas production in downdraft gasifier

  • Kumara, Sunil;Shukla, S.K.
    • Advances in Energy Research
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    • v.4 no.3
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    • pp.223-237
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    • 2016
  • The excess use of conventional sources of energy by the industries and power sector result in acute shortage of energy produced by fossil fuel. To overcome this energy crisis, biomass feedstock is used to produce syngas or producer gas. For cleaning the dust particle present in the producer gas cyclone separators are largely used. In this paper we investigate the performance parameters of cyclone separator mainly efficiency and pressure drop for different feedstock. Cyclone performance has been evaluated based on experimentation and empirical approach using Leith and Licht model. The same has also been calculated by using turbulent RSM in Ansys Fluent for Wood and Coconut shell feedstock. Experimental results show that using feed stock with 10 % Calcium oxide (CaO) by weight, the efficiency of cyclone got reduced from 71.87% to 70.75% for wood feed stock, whereas in case of coconut shell, the cyclone efficiency got reduced from 78% to 73.44%. It is also seen that Leith and Licht model and Reynolds stress model (RMS) predicts very close to the particle collection efficiency evaluated by using experimental data.

Effect of Vanes on Flow Distribution in a Diffuser Type Recuperator Header (디퓨저 타입 레큐퍼레이터 헤더에서 유동분배에 미치는 베인의 영향)

  • Jeong Young-Jun;Kim Seo-Young;Kim Kwang-Ho;Kwak Jae-Su;Kang Byung-Ha
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.18 no.10
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    • pp.819-825
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    • 2006
  • In a SOFC/GT (solid oxide fuel cell/gas turbine) hybrid power generation system, the recuperator is an indispensible component to enhance system performance. Since the expansion ratio to the recuperator core is very large, generally, the effective header design to distribute the flow uniformly before entering the core is crucial to guarantee the required performance. In the present study, we focus on the design of a diffuser type recuperator header with a 90 degree turn inlet port. To reduce the flow separation and recirculation flows, multiple horizontal vanes are used. The number of horizontal vanes is varied from 0 to 24. The air flow velocity is measured at 40 points just behind the core outlet by using a hot wire anemometer. Then, the flow non-uniformity is evaluated from the measured flow velocity. The experimental results showed that inlet air velocity did not effect on relative flow non-uniformity. According to increasing the number of horizontal vanes, flow non-uniformity reduced about $40{\sim}50%$ than without using horizontal vanes.

Recycling of Li2ZrO3 as LiCl and ZrO2 via a Chlorination Technique

  • Jeon, Min Ku;Kim, Sung-Wook;Lee, Keun-Young;Choi, Eun-Young
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.2
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    • pp.271-278
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    • 2021
  • In this study, a chlorination technique for recycling Li2ZrO3, a reaction product of ZrO2-assisted rinsing process, was investigated to minimize the generation of secondary radioactive pyroprocessing waste. It was found that the reaction temperature was a key parameter that determined the reaction rate and maximum conversion ratio. In the temperature range of 400-600℃, an increase in the reaction temperature resulted in a profound increase in the reaction rate. Hence, according to the experimental results, a reaction temperature of at least 450℃ was proposed to ensure a Li2ZrO3 conversion ratio that exceeded 80% within 8 h of the reaction time. The activation energy was found to be 102 ± 2 kJ·mol-1·K-1 between 450 and 500℃. The formation of LiCl and ZrO2 as reaction products was confirmed by X-ray diffraction analysis. The experimental results obtained at various total flow rates revealed that the overall reaction rate depends on the Cl2 mass transfer rate in the experimental condition. The results of this study prove that the chlorination technique provides a solution to minimize the amount of radioactive waste generated during the ZrO2-assisted rinsing process.

Corrosion Behavior of Carbon Steel in Diluted Sulfuric Acid based on Seawater

  • Kim, Mun Su;Jeong, Jin-A
    • Corrosion Science and Technology
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    • v.18 no.3
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    • pp.78-85
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    • 2019
  • The International Maritime Organization (IMO) will administer a new 0.5% global sulfur cap on fuel content from 1 January 2020, lowering from the present 3.5% limit. Seawater $SO_x$ (sulfur oxide) scrubbing is especially spray scrubbing and a promising alternative to complying with the IMO regulation. However, the ionization of $SO_2$ (sulfur dioxide) and the $H_2SO_4$ (sulfuric acid) formed from $SO_3$ (sulfur trioxide) is proposed to accelerate corrosion of the internal seawater pipe. Apparently, the corrosion of the scrubber seawater piping system occurs in a severe and frequent manner. Hence, in this study, electrochemical measurement and weight loss of carbon steel (used as seawater pipe in most of the ships) in diluted sulfuric acid solution were investigated to determine corrosion rate, corrosion current density, corrosion potential, electrochemical behavior, and impressed-current density. Accordingly, the corrosion rate of carbon steel sheet in various diluted sulfuric acid solutions was observed to be greater than that in natural seawater, thus suggesting the fundamental data to deal with corrosion problems in scrubber seawater pipe.

Study of Aluminum Agglomeration Model During Solid Propellant Combustion (고체추진제 연소 중 알루미늄 응집 모델 연구)

  • Yoon, Jisang;Lee, Kookjin;Kim, Daeyu;Park, Namho;Ko, Seungwon;Yoon, Woongsup
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.2
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    • pp.78-86
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    • 2019
  • Aluminum, which is a metal fuel contained in the composite solid propellant, is not ignited and burned on the combustion surface by the oxide film, and it partially melts and coalesces with surrounding aluminum particles. For the evaluation and design of the propellant performance, modeling was performed to predict the size and distribution of agglomerated particles, and the size and distribution of agglomerates were compared and verified through experiment. The predicted values showed the tendency to decrease with pressure as in the experiment, but the error increased as the pressure increased. The agglomerated particle distribution graph showed a difference in the volume fraction although the diameter at the peak was the same.