• Transactions of the Korean Society of Automotive Engineers
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• v.8 no.2
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• pp.33-40
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• 2000

In order to investigate the exhaust structure and secondary oxidation of unburned hydrocarbon (HC) in the exhaust port, a numerical simulation was performed with 3-dimensional flow model and oxidation mechanism optimized for port oxidation. To predict the exhaust and oxidation process with consideration of flow, mixing, and temperature, 3-dimensional flow model and HC oxidation model were used with a commercial computational program, STAR-CD. The flow model were with moving grid for valve motion, which could predict the change of flow field with respect to valve lift. Optimization was performed to predict the HC oxidation with temperature range of 1200~1500K, low HC and oxygen concentration, existence of intermediate species, as typical in port oxidation. The constructed model could predict the port oxidation process with oxidation degree of 14~48% according to the engine operation conditions.

• Journal of Life Science
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• v.5 no.2
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• pp.70-75
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• 1995

The effect of lipoxygenase (LOX) on the oxidation and co-oxidation of lipid fraction was studied in the model system of rainbow trout. For the reaction in model system 1 g of lipid fraction and 50mL of enzyme extract(LOX, 140 unit in 50mL phosphate buffer solution at pH 7, 4)), which were obtained from rainbow trout, were homoginized in the presence of Tween 20 and kept at 23$\circ$C for 3 days. The activity of LOX was decreased to 43% of initial level during the reaction in the model system. The initial composition of rainbow trout lipid was showed to be consisted of trigliceride(TG;82%) and free fatty acid(FFA;0.1%), while this converted to 59% of TG and 20% of FIFA, respectively after reaction in model system. Change of fatty acid composition was also observed and the content of linoleic acid, one of the major fatte acids, was decreased to 13% from 54% in the content of total fatty acids after reaction. The carotenoids in rainbow trout were composed of 0.4% $\alpha$-carotene, 1.6% $\beta$ -carotene, 80% canthaxanthin, 7% lutein and 11% zeaxanthin, thus the canthaxanthin was the major component. This canthaxanthin was the most degraded carotenoid by lipoxygenase catalyzed co-oxidation during the reaction. On the other hand the tocopherol isomers found in the rainbow trout were $\alpha$ and $\beta$ -tocopherol, and $\alpha$-tocopherol had a higher degradation rate by the lipoxygenase catalyzed co-oxidation than of $\beta$-tocopherol in the reaction of model system.

• Journal of environmental and Sanitary engineering
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• v.16 no.1
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• pp.66-71
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• 2001

The objective of this study was to depict the kinetic behavior of the platinum catalyst for the deep oxidation of aromatic solvents and their binary mixtures. The oxidation kinetics of aromatic solvents, which were benzene, toluene and m-xylene, was studied on a 0.5% $Pt/{\gamma}-Al_2O_3$ catalyst. Deep oxidation of binary mixtures, which were 1:1 in volume, was carried out and the inlet concentration was controlled in the range of 133 and 333ppmv. An approach based on the two-stage redox model was used to analysis the results. The deep oxidation conversion of aromatic solvents was inversely proportional to inlet concentration in plug flow reactor. This trend is due to the zeroth-order kinetics with respect to inlet concentration. The kinetic parameters of multicomponent model were independently evaluated from the single compound oxidation experiments. A simple multicomponent model based on two-stage redox rate model made reasonably good predictions of conversion over the range of parameters studied.

• Journal of Microbiology and Biotechnology
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• v.18 no.7
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• pp.1298-1307
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• 2008

In this study, we investigated the inhibition effects of single and mixed heavy metal ions ($Zn^{2+},\;Ni^{2+},\;Cu^{2+},\;and\;Cd^{2+}$) on iron oxidation by Acidithiobacillus ferrooxidans. Effects of metals on the iron oxidation activity of A. ferrooxidans are categorized into four types of patterns according to its oxidation behavior. The results indicated that the inhibition effects of the metals on the iron oxidation activity were noncompetitive inhibitions. We proposed a reduced inhibition model, along with the reduced inhibition constant ($\alpha_i$), which was derived from the inhibition constant ($K_I$) of individual metals and represented the tolerance of a given inhibitor relative to that of a reference inhibitor. This model was used to evaluate the toxicity effect (inhibition effect) of metals on the iron oxidation activity of A. ferrooxidans. The model revealed that the iron oxidation behavior of the metals, regardless of metal systems (single, binary, ternary, or quaternary), is closely matched to that of any reference inhibitor at the same reduced inhibition concentration, $[I]_{reduced}$, which defines the ratio of the inhibitor concentration to the reduced inhibition constant. The model demonstrated that single metal systems and mixed metal systems with the same reduced inhibitor concentrations have similar toxic effects on microbial activity.

• Journal of Mechanical Science and Technology
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• v.17 no.6
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• pp.888-895
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• 2003

Combustion chamber crevices in SI engines are identified as the largest contributors to the engine-out hydrocarbon emissions. The largest crevice is the piston ring-pack crevice. A numerical simulation method was developed, which would allow to predict and understand the oxidation process of piston crevice hydrocarbons. A computational mesh with a moving grid to represent the piston motion was built and a 4-step oxidation model involving seven species was used. The sixteen coefficients in the rate expressions of 4-step oxidation model are optimized based on the results from a study on the detailed chemical kinetic mechanism of oxidation in the engine combustion chamber. Propane was used as the fuel in order to eliminate oil layer absorption and the liquid fuel effect. Initial conditions of the burned gas temperature and in-cylinder pressure were obtained from the 2-zone cycle simulation model. And the simulation was carried out from the end of combustion to the exhaust valve opening for various engine speeds, loads, equivalence ratios and crevice volumes. The total hydrocarbon (THC) oxidation in the crevice during the expansion stroke was 54.9% at 1500 rpm and 0.4 bar (warmed-up condition). The oxidation rate increased at high loads, high swirl ratios, and near stoichiometric conditions. As the crevice volume increased, the amount of unburned HC left at EVO (Exhaust Valve Opening) increased slightly.

• Transactions of the Korean Society of Automotive Engineers
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• v.4 no.4
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• pp.58-71
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• 1996

A model which calculates the hydrocarbon emissions from spark ignition engines is presented The model contains the formation of HC emissions due to both crevices around piston ring top land and oil films on the cylinder wall. The model also considers in-cylinder oxidation and exhaust port oxidation of desorbed HC from crevices and oil films after combustion process. The HC emissions model utilizes the results of SI engine cycle simulation. The model predicts well the trends of HC emissions from the engines when varying engine parameters.

• Journal of the Korean Society of Food Science and Nutrition
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• v.24 no.6
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• pp.1005-1009
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• 1995

This study was carried out to investigate the antioxidative effect of kimchi on the lipid oxidation of cooked meat in model systems. Four model systems of cooked ground meat(CGM). CGM-water(W), CGM-brine(B) and CGM-kimchi(K) were prepared and their oxidation behaviours were evaluated during the storage at 4$^{\circ}C$ for 5 weeks. Thiobarbituric acid values and peroxide values of the systems of CGM, CGM-B and CGM-W increased significantly with the storage time, however, those values of CGM-K were hardly changed during the time of 5 weeks storage. Antioxidative effect of CGM-K increased with the addition level of kimchi in system. And also in the model systems which were prepared with cooked ground meat and kimchi whose fermentation period is different, the antioxidative effect of well ripened and properly fermented kimchi was higher than that of unripened kimchi during the lipid oxidation process of model systems. These results suggested that kimchi especially the properly femented kimchi in the systems plays an important roles as an antioxidative activity on the lipid oxidation of cooked ground meat.

• Journal of Life Science
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• v.5 no.2
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• pp.14-14
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• 1995

The effect of lipoxygenase (LOX) on the oxidation and co-oxidation of lipid fraction was studied in the model system of rainbow trout. For the reaction in model system 1 g of lipid fraction and 50mL of enzyme extract(LOX, 140 unit in 50mL phosphate buffer solution at pH 7,4)), which were obtained from rainbow trout, were homoginized in the presence of Tween 20 and kept at 23$\circ$C for 3 days. The activity of LOX was decreased to 43% of initial level during the reaction in the model system. The initial composition of rainbow trout lipid was showed to be consisted of trigliceride(TG;82%) and free fatty acid(FFA;0.1%), while this converted to 59% of TG and 20% of FIFA, respectively after reaction in model system. Change of fatty acid composition was also observed and the content of linoleic acid, one of the major fatte acids, was decreased to 13% from 54% in the content of total fatty acids after reaction. The carotenoids in rainbow trout were composed of 0.4% $\alpha$-carotene, 1.6% $\beta$ -carotene, 80% canthaxanthin, 7% lutein and 11% zeaxanthin, thus the canthaxanthin was the major component. This canthaxanthin was the most degraded carotenoid by lipoxygenase catalyzed co-oxidation during the reaction. On the other hand the tocopherol isomers found in the rainbow trout were $\alpha$ and $\beta$ -tocopherol, and $\alpha$-tocopherol had a higher degradation rate by the lipoxygenase catalyzed co-oxidation than of $\beta$-tocopherol in the reaction of model system.

• Journal of the Korean Chemical Society
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• v.61 no.4
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• pp.204-210
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• 2017

In this study, we analyzed the descriptions of the electron movement model and the oxidation number change model presented in the 2009 revised curriculum and textbooks. We also investigated chemistry education major teachers' conceptions of limitations of each model. The electron movement model and oxidation number change model were presented in the curriculum and the textbooks. However, hybrid model was also presented which fail to grasp the limitation of each model. The hybrid model explains redox reactions of covalent bond compounds by electron movement model or even if it explains redox reactions by oxidation number change model, this explanations have the problem of confusing the virtual electron movement with the actual electron movement. A questionnaire and interviews were conducted to investigate chemistry education major teachers' perceptions of redox reactions. As results, many teachers did not recognize the limitations of each model and had difficulties to distinguish redox reactions from acid-base reactions because of the hybrid model.

• Nuclear Engineering and Technology
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• v.55 no.7
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• pp.2504-2515
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• 2023

In past years the Paul Scherrer Institute (PSI, Switzerland) and the Karlsruhe Institue of Technology (KIT, Germany)) collaborated to develop a model to account for the active role of nitrogen in the air oxidation of a Zircalloy cladding. The "PSI-KIT Nitriding Model for Zirconium based Fuel Cladding" model was implemented at PSI into PSI-MELCOR 1.8.6. In order to make a preliminary evaluation of the effect of the new model on the evolution of full-scale spent fuel pool accidents, one spent fuel pool event was analyzed using the PSI research version of PSI-MELCOR 1.8.6, which includes the nitriding model. To adapt an existing input deck for the calculations, a sensitivity study was conducted to find an optimal nodalization for the analyses. The nitriding model results were compared to those calculated with the MELCOR 1.8.6-PSI without the new nitriding model. The results demonstrate the effect of the nitriding reactions in spent fuel pool accident progression. Moreover, they confirm the impact of ZrN formation during cladding oxidation in air when the oxidation reactions lead to oxygen starvation inside the fuel assemblies. The nitriding reaction led to higher chemical heat generation during the accident and to an earlier failure of the cladding than when the effect of nitrogen reactions was not considered. It should be noted that the nitriding model, as implemented in the PSI version of MELCOR 1.8.6 has not yet been conclusively validated. Thereby the results presented in this paper should be treated as a preliminary demonstration of the capabilities of the model.