• Title/Summary/Keyword: Over discharging

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Investigation of Al-Ni Alloys Deposition during Over-discharge Reaction of Na-NiCl2 Battery

  • Kim, Jeongsoo;Jo, Seung Hwan;Park, Dae-In;Bhavaraju, Sai;Kang, Sang Ook
    • Journal of the Korean Electrochemical Society
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    • v.19 no.3
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    • pp.57-62
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    • 2016
  • The over-discharging phenomena in sodium-nickel chloride batteries were investigated in relation to decomposition of molten salt electrolyte and consequent metal co-deposition. From XRD analysis, the material deposited on graphite cathode current collector was revealed to be by-product of molten salt electrolyte decomposition. In particular, the result showed that the Ni-Al alloys ($Al_3Ni_2$, $Ni_3Al$ and $Al_3Ni$) were electrochemically deposited on graphite current collectors in line with over-discharging behaviors. It is assumed that the $NiCl_2$ solubility in molten salt electrolytes leads to the co-deposition of Ni-Al alloys by increasing metal deposition potential above 1.6 V (vs. $Na/Na^+$). The cell tests have revealed that the composition of molten salt electrolytes modified by various additives makes a decisive influence on the over-discharging behaviors of the cells. It was revealed that NaOCN addition to molten salt electrolytes was advantageous to suppress over-discharge reactions by modifying the characteristics of molten salt electrolytes. NaOCN addition into molten salt electrolytes seems to suppress Ni solubility by maintaining basic melts. The cell using modified molten salt electrolyte with NaOCN (Cell D) showed relatively less cell degradation compared with other cells for long cycles.

Development of High Voltage and High Energy Density Capacitor for Pulsed Power Application (펄스파워용 고전압 고에너지밀도 커패시터 개발)

  • 이병윤;정진교;이우영;박경엽;이수휘;김영광
    • The Transactions of the Korean Institute of Electrical Engineers B
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    • v.52 no.5
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    • pp.203-210
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    • 2003
  • This paper describes high voltage and high energy density capacitor developed for pulsed power applications. The rated voltage of the developed capacitor is DC 22 [kV], the capacitance is 206 [$\mu$F] and the energy density is about 0.7 [kJ/kg]. Polypropylene film and kraft paper were used as the dielectrics. The ratio of the thickness of each dielectric material which consists of the composite dielectric structure, stacking factor and the termination method were determined by the charging and discharging tests on model capacitors. In terms of energy density, the developed capacitor has higher energy density compared with the products of foreign leading companies. In addition, it has been proved that the life expectancy can be more over 2000 shots through the charging and discharging test. The voltage reversal factor was 20%. This capacitor can be used as numerous discharge applications such as military, medical, industrial fields.

Over Discharging Protection system of Leak Acid Battery for Automatic Water Sanitizer Device (소독약 자동 주입장치용 납축전지의 과 방전 방지시스템)

  • Bae, Cherl-O;Park, Young-San
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.18 no.2
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    • pp.161-165
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    • 2012
  • It is one of the most important to protect the battery over charging for stable use and to extend the life of battery which occurs with repeated charging and discharging. Various research have been studied to know the state of health, and in this paper the terminal voltage of battery is measured to calculate the state of charge simply. The circuit used comparator is designed and built not to fall under the specific voltage of battery. The designed circuit board is attached to the automatic water sanitizer device with a solar power system. The system is located in the water tank where there is not water and electric service, and confirmed that the state of working is good.

Performance Characteristics of Li-ion Battery and Supercapacitor Hybrid Cell for High Power / Low Temperature Discharge (고출력/저온 방전을 위한 리튬전지와 슈퍼캐패시터 하이브리드 셀의 방전 거동 특성 연구)

  • Jang, Woojin;Hong, Seung-Chul;Hong, Jung-Pyo;Hwang, Taeseon;Oh, Joon-Suk;Ko, Sungyeon;Lee, Gaeun;Ahn, Kyunyoung;Kim, Hyunsoo;Suhr, Jonghwan;Nam, Jae-Do
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.6
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    • pp.49-57
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    • 2013
  • In this study, we fabricated a parallelly connected Li-ion battery/supercapacitor hybrid cell to combine the advantageous characteristics of Li-ion battery and supercapacitor, high energy density and high power density, respectively, and investigated its discharging characteristics over a wide temperature range from -40 to $25^{\circ}C$. At the initial state of discharging of the hybrid cell, the power was mostly provided by the supercapacitor and then the portion of the Li-ion battery was gradually increased. By installing a switching system into the hybrid cell, which controls the discharging sequence of Li-ion battery and supercapacitor, the maximum power was improved by 40% compared with non switching system. In addition at low temperatures, the power and discharging time of the hybrid cell were significantly enhanced compared to a battery-alone system. The hybrid cell is expected to be applied in electric vehicles and small domestic appliances that require high power at initial discharging state.

Runoff Characteristics of the Livestock Manure as Fertilizer at Farmland (가축분뇨 비료의 농지 유출 특성)

  • Oa, Seong-Wook
    • Journal of Korean Society on Water Environment
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    • v.26 no.5
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    • pp.775-780
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    • 2010
  • Over 90% of the livestock excretions were treated and utilized by land application in Korea. Excessive application of the livestock manure as fertilizer has been issued as a main pollutant source in groundwater and watersheds. This study was seasonally conducted to identify the discharging characteristics with a certain artificial rainfall intensity (13 mm/hr) in terms of surface runoff, groundwater, and soil residue mass depending on the livestock manure types. A experimental field was constructed with three different sites that pig liquid fertilizer (LF), cattle manure (CM), and standard (S). The pig liquid fertilizer of 1,200 L and cattle manure of 900 kg were sprayed on each site ($50m^2$). The standard area was firmly prevented from any other contaminants. In the LF site, farmland discharging rate (FDR) was computed as 0.006 in CODcr, 0.015 in TN, and 0.029 in TP, resulted from the mass balance among total injection mass, surface runoff and groundwater. In the CM site, 29% of the nitrogen and phosphorus in each were discharged to the surface, and 64% and 58% of them were remained in the farmland. Surface runoff rate of the CM was higher than that of the LF, resulted from the solid form of the CM.

Characteristics of Pollutant Loads and Water Quality in Kwangyang Bay, Korea

  • Lee Dae-In;Park Chung-Kil;Cho Hyeon-Seo
    • Fisheries and Aquatic Sciences
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    • v.6 no.3
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    • pp.149-154
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    • 2003
  • The characteristics of pollutant loads from the various sources and seawater quality in Kwangyang Bay were evaluated. Total flow rate was estimated to be $10,868,066.8 m^3/day$ with a flow rate of R2l (the Seomjin River) as the highest one. Total COD, TN and TP loads of the input rivers and the ditches were about 27,591.8, 25,029.6 and 586.4 kg/day, respectively. Wastewater discharging loads was the greatest contributors to pollutant loads in the inner part of Kwangyang Bay. COD values in the inner part of the bay was over 3.0 mg/L, which exceeded the seawater quality criteria III of Korea. The average values of DIN and DIP were 8.62 ${\mu}gN/L\;and\;1.26\;{\mu}gP/L$, respectively. The limiting factor for algal growth was DIN. In he total discharging loads of the watershed from unit loading estimations, BOD, TN and TP were 9,132.3, 2,727.2 and 304.2 kg/day, respectively. In addition, municipal sewage by the population as pollution sources and the city of Kwangyang as administrative district had the highest loads. For a appropriate water quality recovery of Kwangyang Bay, it is suggested that it is essential to estimate reduction rate of total pollutant loads by water quality modeling.

A Monitoring Unit for Lead Storage Batteries in Stand Alone PV Generation Systems (독립형 태양광 발전소의 연 축전지 모니터링장치 개발)

  • Moon, Chae-Joo;Kim, Tae-Gon;Chang, Young-Hag;Kjm, Eui-Sun;Lim, Jung-Min
    • Journal of the Korean Solar Energy Society
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    • v.29 no.2
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    • pp.1-7
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    • 2009
  • Use of the PV(photovoltaic) generation system is increased in such areas as remote mountain places or islands at which electrical energy is not serviced. The stand alone PV system is required the power storage products such as battery, fly wheel and super capacitor. Several lead storage batteries are connected in series to get high voltages. The life of lead storage battery is shortened when over charge or over discharge takes place. So, it is needed to control batteries not to be overcharged or be discharged deeply. Voltage of each battery was ignored in former control methods in which overall voltage was used to control charge or discharge battery. In this study, the charging and discharging voltage variations of sealed lead storage batteries with l2V/l.2A were investigated step by step experiments. The results of the test show that one should consider and specify the state of each battery to prevent overcharge or deep discharge. With the basis of the experiments, we designed a monitoring unit to monitor battery voltages simultaneously using micro-controller. The unit measures voltage of 20 batteries simultaneously and displays data on the color LCD monitor with curved line graph. It also sends data to PC using the RS232C communication port. The designed unit was adapted to stand alone PV system with 1kW capacity and lead storage batteries are connected to the PV generation system. The number of lead storage batteries was 10 in series and 12V/250Ah each. Resistive load with 3kW was used for discharging.

Steady-State Characteristics of Resonant Switched Capacitor Converters

  • Shoyama Masahito;Deriha Fumitoshi;Ninomiya Tamotsu
    • Journal of Power Electronics
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    • v.5 no.3
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    • pp.206-211
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    • 2005
  • Conventional switched capacitor converters have an inherent drawback that their efficiency decreases as the output current increases. This inherent drawback is due to a periodical forced charging and discharging operation in the internal switched capacitors accompanied by a large capacitor current. Their efficiency can not be increased by decreasing its internal resistance. As a result, conventional switched capacitor converters have been limited to uses with a very small output current. To solve this problem we presented a novel switched capacitor converter topology that uses a resonant operation instead of the forced charging and discharging operation. Its advantage over a conventional switched capacitor converter is higher efficiency even in a high output current region. In this paper, the operation analysis and steady-state characteristics are described in detail for a half buck type switched capacitor converter, and they are confirmed by experimentation.

Control Scheme of Emergency Power Supply for Elevator Emergency Call System (승강기의 비상 통화장치용 비상 전원장치의 충·방전 제어회로)

  • Park, Noh-Sik;Lee, Dong-Hee
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.29 no.8
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    • pp.40-48
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    • 2015
  • In this paper, battery charging and discharging circuit with a single voltage power supply is proposed. The proposed circuit has the separated current path and charging-monitoring sequence control scheme. In the charging sequence, the proposed 2-level comparator combined with control signal of the micro-processor can control the constant charging current to protect the over current of the battery. Furthermore, the proposed circuit uses a periodic main power switch control to detect the discharging characteristics to estimate the approximated battery life-time. In the experiments, the proposed emergency power supply for emergency call system has 89% efficiency with 98% power factor. And the proposed sequence control scheme is well operated in the designed emergency power system.

Test Facility of Battery Simulator for Dynamic Characteristics and Safety Evaluation in Lithium-ion Battery (리튬이온 배터리 동특성 및 안전성 평가를 위한 배터리 시뮬레이터 시험설비)

  • Sungin Jeong;Yongho Yoon
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.24 no.2
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    • pp.133-138
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    • 2024
  • Lithium-ion batteries are used in many fields due to their high energy density, fast charging conditions, and long cycle life. However, overcharging, over-discharging, physical damage, and use of lithium-ion batteries at high temperatures can reduce battery life and cause damage to people due to fire or explosion due to damage to the protection circuit. In order to reduce the risk of these batteries and improve battery performance, the characteristics of the charging and discharging process must be analyzed and understood. Therefore, in this paper, we analyze the charging and discharging characteristics of lithium-ion batteries using a battery charger and discharger and simulator to reduce the risk of loss of life due to overcharge and overdischarge, as well as casualties from fire and explosion due to damage to the protection circuit.